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Lignocellulosic biomass: a sustainable platform for the production of bio-based chemicals and polymers

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TLDR
In this paper, the potential of lignocellulosic biomass as an alternative platform to fossil resources has been analyzed and a critical review provides insights into the potential for LBS.
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This article is published in Polymer Chemistry.The article was published on 2015-06-16 and is currently open access. It has received 1763 citations till now. The article focuses on the topics: Lignocellulosic biomass & Biomass.

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Citations
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Clean Production of Levulinic Acid from Fructose and Glucose in Salt Water by Heterogeneous Catalytic Dehydration.

TL;DR: The combination of high sugar concentration and heterogeneous catalysis in an aqueous system under relatively mild conditions could provide a high-yielding and sustainable process for bio-based LA production.
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Sustainable Synthetic Approaches for the Preparation of Plant Oil-Based Thermosets

TL;DR: In this paper, a review of the sustainability of plant oil-based thermoset materials is presented, including epoxy resins, polyurethane networks, polybenzoxazines and unsaturated polyesters.
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Valorization of Rice Straw for Ethanol Production and Lignin Recovery Using Combined Acid-Alkali Pre-treatment

TL;DR: In this paper, rice straw was sequentially pre-treated with sulphuric acid (3% v/v) and sodium hydroxide (4% w/v), which resulted in the removal of ~90% hemicelluloses and ~55% lignin, respectively.
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Life cycle assessments of bio-based sustainable polylimonene carbonate production processes

TL;DR: In this article, the authors investigated the environmental impacts associated with the production of the newly proposed biopolymer polylimonene carbonate, and concluded that future process designs should combine polymer production with the co-generation of energy from waste biomass.
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Enhanced production of phenolics and aromatics from raw bio-oil using HZSM-5 zeolite additives for PtPd/C and NiW/C catalysts

TL;DR: In this article, the performance of a Pt-Pd and a Ni-W catalyst supported on a phosphorus-containing activated carbon (ACP) in the hydrodeoxygenation (HDO) of raw bio-oil, as well as the enhancement of phenolic and aromatic product yields produced by incorporating physically mixed HZSM-5 zeolites of different Si/Al ratio in the catalytic bed.
References
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Journal ArticleDOI

Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering.

TL;DR: Hydrogen Production by Water−Gas Shift Reaction 4056 4.1.
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Features of promising technologies for pretreatment of lignocellulosic biomass.

TL;DR: This paper reviews process parameters and their fundamental modes of action for promising pretreatment methods and concludes that pretreatment processing conditions must be tailored to the specific chemical and structural composition of the various, and variable, sources of lignocellulosic biomass.
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Cellulose: Fascinating Biopolymer and Sustainable Raw Material

TL;DR: The current knowledge in the structure and chemistry of cellulose, and in the development of innovative cellulose esters and ethers for coatings, films, membranes, building materials, drilling techniques, pharmaceuticals, and foodstuffs are assembled.
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Hydrolysis of lignocellulosic materials for ethanol production: a review.

TL;DR: Simultaneous saccharification and fermentation effectively removes glucose, which is an inhibitor to cellulase activity, thus increasing the yield and rate of cellulose hydrolysis, thereby increasing the cost of ethanol production from lignocellulosic materials.
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The path forward for biofuels and biomaterials

TL;DR: The integration of agroenergy crops and biorefinery manufacturing technologies offers the potential for the development of sustainable biopower and biomaterials that will lead to a new manufacturing paradigm.
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