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Journal ArticleDOI

Schottky barrier heights of tantalum oxide, barium strontium titanate, lead titanate, and strontium bismuth tantalate

John Robertson, +1 more
- 18 Feb 1999 - 
- Vol. 74, Iss: 8, pp 1168-1170
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TLDR
In this article, the Schottky barrier heights of various metals on the high permitivity oxides tantalum pentoxide, barium strontium titanate, lead zirconate titanate (LZT), and strontia bismuth tantalate have been calculated as a function of the metal work function.
Abstract
The Schottky barrier heights of various metals on the high permitivity oxides tantalum pentoxide, barium strontium titanate, lead zirconate titanate, and strontium bismuth tantalate have been calculated as a function of the metal work function. It is found that these oxides have a dimensionless Schottky barrier pinning factor S of 0.28–0.4 and not close to 1 because S is controlled by Ti–O-type bonds not Sr–O-type bonds, as assumed in earlier work. The band offsets on silicon are asymmetric with a much smaller offset at the conduction band, so that Ta2O5 and barium strontium titanate are relatively poor barriers to electrons on Si.

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Citations
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References
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Book

Metal-semiconductor contacts

TL;DR: In this article, a review of the present knowledge of metal-semiconductor contacts is given, including the factors that determine the height of the Schottky barrier, its current/voltage characteristics, and its capacitance.
Journal ArticleDOI

Fatigue-free ferroelectric capacitors with platinum electrodes

TL;DR: In this article, the authors describe the preparation and characterization of thin-film capacitors using ferroelectric materials from a large family of layered perovskite oxides, exemplified by SrBi2Ta2O9, SRBi2NbTaO9 and SrBi4Ta4O15.
Journal ArticleDOI

Surface States and Barrier Height of Metal‐Semiconductor Systems

TL;DR: In this paper, the dependence of the barrier height of metal-semiconductor systems upon the metal work function is derived based on the following assumptions: (1) the contact between the metal and the semiconductor has an interfacial layer of the order of atomic dimensions; it is further assumed that this layer is transparent to electrons with energy greater than the potential barrier but can withstand potential across it.
Journal ArticleDOI

Theory of semiconductor heterojunctions: The role of quantum dipoles

TL;DR: In this paper, a simple criterion for zero-dipole band lineups is proposed, which gives excellent agreement with experimental band lineup, and the close connection between heterojunction band line up and Schottky barrier formation is emphasized.
Journal ArticleDOI

First-principles investigation of ferroelectricity in perovskite compounds

TL;DR: A first-principles ultra-soft-pseudopotential method in conjunction with an efficient preconditioned conjugate-gradient scheme is used to investigate the properties of a series of eight cubic perovskite compounds to predict the symmetry of the ground-state structures of all compounds whose observed low-temperature structure retains a primitive five-atom unit cell.
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