Journal ArticleDOI
The nitrate radical: Physics, chemistry, and the atmosphere
Richard P. Wayne,Ian Barnes,P. Biggs,John P. Burrows,Carlos E. Canosa-Mas,Jens Hjorth,G. Le Bras,Geert K. Moortgat,Dieter Perner,G. Poulet,G Restelli,Howard Sidebottom +11 more
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A review of the state of the art in the field of chemistry of the NO 3 radical is presented in this paper, with a focus on the relationship between the laboratory and the atmospheric studies.About:
This article is published in Atmospheric Environment. Part A. General Topics.The article was published on 1991-01-01. It has received 694 citations till now. The article focuses on the topics: Radical & Chemical reaction.read more
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Protocol for the development of the Master Chemical Mechanism, MCM v3 (Part A): tropospheric degradation of non-aromatic volatile organic compounds
TL;DR: In this paper, an update to the previous protocol is presented, which has been used to define degradation schemes for 107 non-aromatic VOC as part of version 3 of the Master Chemical Mechanism (MCM v3).
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A new mechanism for regional atmospheric chemistry modeling
TL;DR: The Regional Atmospheric Chemistry Mechanism (RACM) as discussed by the authors is a gas-phase chemical mechanism for the modeling of regional atmospheric chemistry, the mechanism is intended to be valid for remote to polluted conditions and from the Earth's surface through the upper troposphere.
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The tropospheric degradation of volatile organic compounds: a protocol for mechanism development
TL;DR: In this paper, a series of rules for the construction of detailed degradation schemes for use in numerical models of the boundary layer over Europe is presented. But, as a major disadvantage of explicit chemical mechanisms is the very large number of reactions potentially generated, if the rules are rigorously applied.
Journal ArticleDOI
Formation of Organic Aerosols from the Oxidation of Biogenic Hydrocarbons
Thorsten Hoffmann,Jay R. Odum,Frank M. Bowman,Don R. Collins,Dieter Klockow,Richard C. Flagan,John H. Seinfeld +6 more
TL;DR: In this article, a gas/particle absorption model was used to simulate the evolution of aerosol formation during photooxidation of α-pinene and other cyclic monoterpenes.
Journal ArticleDOI
Atmospheric composition change – global and regional air quality
Paul S. Monks,Claire Granier,Claire Granier,Claire Granier,Sandro Fuzzi,Andreas Stohl,Martin L. Williams,Hajime Akimoto,Markus Amann,Alexander Baklanov,Urs Baltensperger,Isabelle Bey,Nicola J. Blake,Robert S. Blake,Kenneth S. Carslaw,Owen R. Cooper,Owen R. Cooper,F. J. Dentener,David Fowler,E. Fragkou,Gregory J. Frost,Gregory J. Frost,S. Generoso,Paul Ginoux,Volker Grewe,Alex Guenther,Hans-Christen Hansson,Stephan Henne,Jens Hjorth,Andreas Hofzumahaus,Heidi Huntrieser,Ivar S. A. Isaksen,Michael E. Jenkin,Jan Kaiser,Maria Kanakidou,Zbigniew Klimont,Markku Kulmala,Paolo Laj,Paolo Laj,Mark Lawrence,James D. Lee,Catherine Liousse,Michela Maione,Gordon McFiggans,A. Metzger,Aude Mieville,Nicolas Moussiopoulos,John J. Orlando,Colin D. O'Dowd,Paul I. Palmer,D. D. Parrish,Andreas Petzold,Ulrich Platt,Ulrich Pöschl,André S. H. Prévôt,Claire E. Reeves,Stefan Reimann,Yinon Rudich,Karine Sellegri,Rainer Steinbrecher,David Simpson,David Simpson,H.M. ten Brink,J. Theloke,G. R. van der Werf,Robert Vautard,Vigdis Vestreng,Ch. Vlachokostas,R. von Glasow +68 more
TL;DR: A review of the state of scientific understanding in relation to global and regional air quality is outlined in this article, in terms of emissions, processing and transport of trace gases and aerosols.
References
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Rate Constants for Reactions of Inorganic Radicals in Aqueous Solution
TL;DR: In this article, rate constants have been compiled for reactions of various inorganic radicals produced by radiolysis or photolysis, as well as by other chemical means in aqueous solutions.
Journal ArticleDOI
Relationship between Absorption Intensity and Fluorescence Lifetime of Molecules
S. J. Strickler,Robert A. Berg +1 more
TL;DR: In this paper, the authors derived a modified 1/τ0=2.880×10−9n2/n2-1(gl/gu) ∫ edlnν, which should be valid for broad molecular bands when the transition is strongly allowed.
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Hydrocarbon Bond Dissociation Energies
TL;DR: The best available values for homolytic bond dissociation energies (BDEs) of various classes of neutral compounds are considered in a review as mentioned in this paper, focusing on prototypical radicals whose heats of formation, formerly thought to be well in hand, have recently been called into serious question.
Journal ArticleDOI
Tropospheric chemistry: A global perspective
TL;DR: A model for the photochemistry of the global troposphere constrained by observed concentrations of H2O, O3, CO, CH4, NO, NO2, and HNO3 is presented in this paper.
Journal ArticleDOI
The influence of nitrogen oxides on the atmospheric ozone content
TL;DR: In this paper, the probable importance of NO and NO2 in controlling the ozone concentrations and production rates in the stratosphere is pointed out and some processes which may lead to production of nitric acid are discussed.