Showing papers in "Nature Photonics in 2017"

Fano resonances in photonics

Abstract: The importance of the Fano resonance concept is recognized across multiple fields of physics. In this Review, Fano resonance is explored in the context of optics, with particular emphasis on dielectric nanostructures and metasurfaces. Rapid progress in photonics and nanotechnology brings many examples of resonant optical phenomena associated with the physics of Fano resonances, with applications in optical switching and sensing. For successful design of photonic devices, it is important to gain deep insight into different resonant phenomena and understand their connection. Here, we review a broad range of resonant electromagnetic effects by using two effective coupled oscillators, including the Fano resonance, electromagnetically induced transparency, Kerker and Borrmann effects, and parity–time symmetry breaking. We discuss how to introduce the Fano parameter for describing a transition between two seemingly different spectroscopic signatures associated with asymmetric Fano and symmetric Lorentzian shapes. We also review the recent results on Fano resonances in dielectric nanostructures and metasurfaces.

Efficient perovskite light-emitting diodes featuring nanometre-sized crystallites

Abstract: Organic–inorganic hybrid perovskite materials are emerging as highly attractive semiconductors for use in optoelectronics. In addition to their use in photovoltaics, perovskites are promising for realizing light-emitting diodes (LEDs) due to their high colour purity, low non-radiative recombination rates and tunable bandgap. Here, we report highly efficient perovskite LEDs enabled through the formation of self-assembled, nanometre-sized crystallites. Large-group ammonium halides added to the perovskite precursor solution act as a surfactant that dramatically constrains the growth of 3D perovskite grains during film forming, producing crystallites with dimensions as small as 10 nm and film roughness of less than 1 nm. Coating these nanometre-sized perovskite grains with longer-chain organic cations yields highly efficient emitters, resulting in LEDs that operate with external quantum efficiencies of 10.4% for the methylammonium lead iodide system and 9.3% for the methylammonium lead bromide system, with significantly improved shelf and operational stability. Perovskite nanocrystal LEDs featuring long-chain ammonium cations offer improved stability and efficiency.

Non-Hermitian photonics based on parity-time symmetry

Abstract: Nearly one century after the birth of quantum mechanics, parity–time symmetry is revolutionizing and extending quantum theories to include a unique family of non-Hermitian Hamiltonians. While conceptually striking, experimental demonstration of parity–time symmetry remains unexplored in quantum electronic systems. The flexibility of photonics allows for creating and superposing non-Hermitian eigenstates with ease using optical gain and loss, which makes it an ideal platform to explore various non-Hermitian quantum symmetry paradigms for novel device functionalities. Such explorations that employ classical photonic platforms not only deepen our understanding of fundamental quantum physics but also facilitate technological breakthroughs for photonic applications. Research into non-Hermitian photonics therefore advances and benefits both fields simultaneously. General concepts and recent developments of parity–time symmetry in classical photonics are reviewed.

Phase-change materials for non-volatile photonic applications

Abstract: Materials whose optical properties can be reconfigured are crucial for photonic applications such as optical memories. Phase-change materials offer such utility and here recent progress is reviewed. Phase-change materials (PCMs) provide a unique combination of properties. On transformation from the amorphous to crystalline state, their optical properties change drastically. Short optical or electrical pulses can be utilized to switch between these states, making PCMs attractive for photonic applications. We review recent developments in PCMs and evaluate the potential for all-photonic memories. Towards this goal, the progress and existing challenges to realize waveguides with stepwise adjustable transmission are presented. Colour-rendering and nanopixel displays form another interesting application. Finally, nanophotonic applications based on plasmonic nanostructures are introduced. They provide reconfigurable, non-volatile functionality enabling manipulation and control of light. Requirements and perspectives to successfully implement PCMs in emerging areas of photonics are discussed.

Cs 2 AgBiBr 6 single-crystal X-ray detectors with a low detection limit

Abstract: Sensitive X-ray detection is crucial for medical diagnosis, industrial inspection and scientific research. The recently described hybrid lead halide perovskites have demonstrated low-cost fabrication and outstanding performance for direct X-ray detection, but they all contain toxic Pb in a soluble form. Here, we report sensitive X-ray detectors using solution-processed double perovskite Cs2AgBiBr6 single crystals. Through thermal annealing and surface treatment, we largely eliminate Ag+/Bi3+ disordering and improve the crystal resistivity, resulting in a detector with a minimum detectable dose rate as low as 59.7 nGyair s−1, comparable to the latest record of 0.036 μGyair s−1 using CH3NH3PbBr3 single crystals. Suppressed ion migration in Cs2AgBiBr6 permits relatively large external bias, guaranteeing efficient charge collection without a substantial increase in noise current and thus enabling the low detection limit. Double perovskite Cs2AgBiBr6 single crystals are used to make a sensitive X-ray detector. The device exhibits a high sensitivity of 105 µC Gyair −1 cm−2 and a low detection limit of 59.7 nGyairs−1, and demonstrates long-term operational stability.

Dye-sensitized solar cells for efficient power generation under ambient lighting

Abstract: Solar cells that operate efficiently under indoor lighting are of great practical interest as they can serve as electric power sources for portable electronics and devices for wireless sensor networks or the Internet of Things. Here, we demonstrate a dye-sensitized solar cell (DSC) that achieves very high power-conversion efficiencies (PCEs) under ambient light conditions. Our photosystem combines two judiciously designed sensitizers, coded D35 and XY1, with the copper complex Cu(II/I)(tmby) as a redox shuttle (tmby, 4,4′,6,6′-tetramethyl-2,2′-bipyridine), and features a high open-circuit photovoltage of 1.1 V. The DSC achieves an external quantum efficiency for photocurrent generation that exceeds 90% across the whole visible domain from 400 to 650 nm, and achieves power outputs of 15.6 and 88.5 μW cm–2 at 200 and 1,000 lux, respectively, under illumination from a model Osram 930 warm-white fluorescent light tube. This translates into a PCE of 28.9%. A dye-sensitized solar cell that has been designed for efficient operation under indoor lighting could offer a convenient means for powering the Internet of Things.

Two-dimensional topological photonics

Abstract: Originating from the studies of two-dimensional condensed-matter states, the concept of topological order has recently been expanded to other fields of physics and engineering, particularly optics and photonics. Topological photonic structures have already overturned some of the traditional views on wave propagation and manipulation. The application of topological concepts to guided wave propagation has enabled novel photonic devices, such as reflection-free sharply bent waveguides, robust delay lines, spin-polarized switches and non-reciprocal devices. Discrete degrees of freedom, widely used in condensed-matter physics, such as spin and valley, are now entering the realm of photonics. In this Review, we summarize the latest advances in this highly dynamic field, with special emphasis on the experimental work on two-dimensional photonic topological structures. Topological photonic structures offer unique features such as reflection-free and non-reciprocal devices. This Review highlights the experimental progress in the relatively new field of photonic topology.

Lasing in topological edge states of a one-dimensional lattice

Abstract: Topology describes properties that remain unaffected by smooth distortions. Its main hallmark is the emergence of edge states localized at the boundary between regions characterized by distinct topological invariants. Because their properties are inherited from the topology of the bulk, these edge states present a strong immunity to distortions of the underlying architecture. This feature offers new opportunities for robust trapping of light in nano- and micrometre-scale systems subject to fabrication imperfections and environmentally induced deformations. Here, we report lasing in such topological edge states of a one-dimensional lattice of polariton micropillars that implements an orbital version of the Su–Schrieffer–Heeger Hamiltonian. We further demonstrate that lasing in these states persists under local deformations of the lattice. These results open the way to the implementation of chiral lasers in systems with broken time-reversal symmetry and, when combined with polariton interactions, to the study of nonlinear phenomena in topological photonics. Topologically protected lasing is reported in a lattice of polariton micropillars.

Non-reciprocal photonics based on time modulation

Abstract: Reciprocity is a fundamental principle in optics, requiring that the response of a transmission channel is symmetric when source and observation points are interchanged. It is of major significance because it poses fundamental constraints on the way we process optical signals. Non-reciprocal devices, which break this symmetry, have become fundamental in photonic systems. Today they require magnetic materials that are bulky, costly and cannot be integrated. This is in stark contrast with most photonic devices, including sources, modulators, switches, waveguides, interconnects and antennas, which may be realized at the nanoscale. Here, we review recent progress and opportunities offered by temporal modulation to break reciprocity, revealing its potential for compact, low-energy, integrated non-reciprocal devices, and discuss the future of this exciting research field. The progress on non-reciprocal photonic devices enabled by temporal modulation is reviewed.

Metamaterial-inspired silicon nanophotonics

Abstract: Applying metamaterial concepts to dielectric systems offers low losses compared with metallic structures. Here, silicon-based metamaterial and nanophotonic advances are reviewed. The prospect of creating metamaterials with optical properties greatly exceeding the parameter space accessible with natural materials has been inspiring intense research efforts in nanophotonics for more than a decade. Following an era of plasmonic metamaterials, low-loss dielectric nanostructures have recently moved into the focus of metamaterial-related research. This development was mainly triggered by the experimental observation of electric and magnetic multipolar Mie-type resonances in high-refractive-index dielectric nanoparticles. Silicon in particular has emerged as a popular material choice, due to not only its high refractive index and very low absorption losses in the telecom spectral range, but also its paramount technological relevance. This Review overviews recent progress on metamaterial-inspired silicon nanostructures, including Mie-resonant and off-resonant regimes.

Near-zero refractive index photonics

Abstract: The underlying principles and unique optical applications of structures exhibiting near-zero dielectric permittivity and/or magnetic permeability are reviewed. The timely relevance to nonlinear, non-reciprocal and non-local effects is highlighted. Structures with near-zero parameters (for example, media with near-zero relative permittivity and/or relative permeability, and thus a near-zero refractive index) exhibit a number of unique features, such as the decoupling of spatial and temporal field variations, which enable the exploration of qualitatively different wave dynamics. This Review summarizes the underlying principles and salient features, physical realizations and technological potential of these structures. In doing so, we revisit their distinctive impact on multiple optical processes, including scattering, guiding, trapping and emission of light. Their role in emphasizing secondary responses of matter such as nonlinear, non-reciprocal and non-local effects is also discussed.

Solution-processed organic tandem solar cells with power conversion efficiencies >12%

Abstract: Careful selection of small-molecule materials provides solution-processed tandem organic solar cells with a boost in efficiency. An effective way to improve the power conversion efficiency of organic solar cells is to use a tandem architecture consisting of two subcells, so that a broader part of the solar spectrum can be used and the thermalization loss of photon energy can be minimized1. For a tandem cell to work well, it is important for the subcells to have complementary absorption characteristics and generate high and balanced (matched) currents. This requires a rather challenging effort to design and select suitable active materials for use in the subcells. Here, we report a high-performance solution-processed, tandem solar cell based on the small molecules DR3TSBDT and DPPEZnP-TBO, which offer efficient, complementary absorption when used as electron donor materials in the front and rear subcells, respectively. Optimized devices achieve a power conversion efficiency of 12.50% (verified 12.70%), which represents a new level of capability for solution-processed, organic solar cells.

Monolithic integration of hybrid perovskite single crystals with heterogenous substrate for highly sensitive X-ray imaging

Abstract: Hybrid perovskite crystals are integrated onto silicon wafers enabling fabrication of an X-ray linear detector array. High sensitivity may reduce patient dose in medical imaging applications.

Broadband image sensor array based on graphene–CMOS integration

Abstract: Integrated circuits based on complementary metal-oxide–semiconductors (CMOS) are at the heart of the technological revolution of the past 40 years, enabling compact and low-cost microelectronic circuits and imaging systems However, the diversification of this platform into applications other than microcircuits and visible-light cameras has been impeded by the difficulty to combine semiconductors other than silicon with CMOS Here, we report the monolithic integration of a CMOS integrated circuit with graphene, operating as a high-mobility phototransistor We demonstrate a high-resolution, broadband image sensor and operate it as a digital camera that is sensitive to ultraviolet, visible and infrared light (300–2,000 nm) The demonstrated graphene–CMOS integration is pivotal for incorporating 2D materials into the next-generation microelectronics, sensor arrays, low-power integrated photonics and CMOS imaging systems covering visible, infrared and terahertz frequencies Graphene–quantum dots on CMOS sensor offers broadband imaging

Near-infrared organic light-emitting diodes with very high external quantum efficiency and radiance

Abstract: New design of Pt(II) phosphors yield near-infrared organic light-emitting diodes with high efficiency and brightness.

High-efficiency multiphoton boson sampling

Abstract: This work was supported by the National Natural Science Foundation of China, the Chinese Academy of Sciences, the National Fundamental Research Program, and the State of Bavaria.

Spatial beam self-cleaning in multimode fibres

Abstract: The Kerr effect in graded-index multimode fibres drives a spatial beam self-cleaning phenomenon that withstands fibre bending and does not necessitate dissipative processes such as stimulated scattering. Multimode optical fibres are enjoying renewed attention, boosted by the urgent need to overcome the current capacity crunch of single-mode fibre (SMF) systems and by recent advances in multimode complex nonlinear optics1,2,3,4,5,6,7,8,9,10,11,12,13. In this work, we demonstrate that standard multimode fibres (MMFs) can be used as ultrafast all-optical tools for the transverse beam manipulation of high-power laser pulses. Our experimental data show that the Kerr effect in a graded-index (GRIN) MMF is the driving mechanism that overcomes speckle distortions, and leads to a counterintuitive effect that results in a spatially clean output beam robust against fibre bending. Our observations demonstrate that nonlinear beam reshaping into the fundamental mode of a MMF can be achieved even in the absence of a dissipative process such as stimulated scattering (Raman or Brillouin)14,15.

Quantum transport simulations in a programmable nanophotonic processor

Abstract: Environmental noise and disorder play critical roles in quantum particle and wave transport in complex media, including solid-state and biological systems. While separately both effects are known to reduce transport, recent work predicts that in a limited region of parameter space, noise-induced dephasing can counteract localization effects, leading to enhanced quantum transport. Photonic integrated circuits are promising platforms for studying such effects, with a central goal of developing large systems providing low-loss, high-fidelity control over all parameters of the transport problem. Here, we fully map the role of disorder in quantum transport using a nanophotonic processor: a mesh of 88 generalized beamsplitters programmable on microsecond timescales. Over 64,400 experiments we observe distinct transport regimes, including environment-assisted quantum transport and the ‘quantum Goldilocks’ regime in statically disordered discrete-time systems. Low-loss and high-fidelity programmable transformations make this nanophotonic processor a promising platform for many-boson quantum simulation experiments. A large-scale, low-loss and phase-stable programmable nanophotonic processor is fabricated to explore quantum transport phenomena. The signature of environment-assisted quantum transport in discrete-time systems is observed for the first time.

Hard X-ray free-electron laser with femtosecond-scale timing jitter

Abstract: The hard X-ray free-electron laser at the Pohang Accelerator Laboratory (PAL-XFEL) in the Republic of Korea achieved saturation of a 0.144 nm free-electron laser beam on 27 November 2016, making it the third hard X-ray free-electron laser in the world, following the demonstrations of the Linac Coherent Light Source (LCLS) and the SPring-8 Angstrom Compact Free Electron Laser (SACLA). The use of electron-beam-based alignment incorporating undulator radiation spectrum analysis has allowed reliable operation of PAL-XFEL with unprecedented temporal stability and dispersion-free orbits. In particular, a timing jitter of just 20 fs for the free-electron laser photon beam is consistently achieved due to the use of a state-of-the-art design of the electron linear accelerator and electron-beam-based alignment. The low timing jitter of the electron beam makes it possible to observe Bi(111) phonon dynamics without the need for timing-jitter correction, indicating that PAL-XFEL will be an extremely useful tool for hard X-ray time-resolved experiments. The Pohang Accelerator Laboratory X-ray Free Electron Laser (PAL-XFEL) in South Korea has now entered operation with a timing jitter of just 20 fs.

Planar metasurface retroreflector

Abstract: Metasurfaces are two-dimensional arrangements of subwavelength scatterers that control the propagation of optical waves. Here, we show that cascaded metasurfaces, each performing a predefined mathematical transformation, provide a new optical design framework that enables new functionalities not yet demonstrated with single metasurfaces. Specifically, we demonstrate that retroreflection can be achieved with two vertically stacked planar metasurfaces, the first performing a spatial Fourier transform and its inverse, and the second imparting a spatially varying momentum to the Fourier transform of the incident light. Using this concept, we fabricate and test a planar monolithic near-infrared retroreflector composed of two layers of silicon nanoposts, which reflects light along its incident direction with a normal incidence efficiency of 78% and a large half-power field of view of 60°. The metasurface retroreflector demonstrates the potential of cascaded metasurfaces for implementing novel high-performance components, and enables low-power and low-weight passive optical transmitters.

High-performance direct conversion X-ray detectors based on sintered hybrid lead triiodide perovskite wafers

Abstract: Methyl ammonium lead triiodide perovskite wafers for application in direct conversion X-ray detectors are fabricated by a room-temperature sintering process. A conversion efficiency of 2,527 mC Gyaircm–2 under 70 kVp X-ray exposure is obtained.

Continuous-wave lasing in an organic–inorganic lead halide perovskite semiconductor

Abstract: Hybrid organic–inorganic perovskites have emerged as promising gain media for tunable, solution-processed semiconductor lasers. However, continuous-wave operation has not been achieved so far 1–3 . Here, we demonstrate that optically pumped continuous-wave lasing can be sustained above threshold excitation intensities of ~17 kW cm–2 for over an hour in methylammonium lead iodide (MAPbI3) distributed feedback lasers that are maintained below the MAPbI3 tetragonal-to-orthorhombic phase transition temperature of T ≈ 160 K. In contrast with the lasing death phenomenon that occurs for pure tetragonal-phase MAPbI3 at T > 160 K (ref. 4 ), we find that continuous-wave gain becomes possible at T ≈ 100 K from tetragonal-phase inclusions that are photogenerated by the pump within the normally existing, larger-bandgap orthorhombic host matrix. In this mixed-phase system, the tetragonal inclusions function as carrier recombination sinks that reduce the transparency threshold, in loose analogy to inorganic semiconductor quantum wells, and may serve as a model for engineering improved perovskite gain media. Optically pumped continuous-wave lasing is achieved in methylammonium lead iodide (MAPbI3) distributed feedback lasers that are maintained below the MAPbI3 tetragonal-to-orthorhombic phase transition temperature of 160 K.

Ultrastable optical clock with two cold-atom ensembles

Abstract: Optical clocks with a record low zero-dead-time instability of 6 × 10–17 at 1 second are demonstrated in two cold-ytterbium systems. The two systems are interrogated by a shared optical local oscillator to nearly eliminate the Dick effect. Atomic clocks based on optical transitions are the most stable, and therefore precise, timekeepers available. These clocks operate by alternating intervals of atomic interrogation with the ‘dead’ time required for quantum state preparation and readout. This non-continuous interrogation of the atom system results in the Dick effect, an aliasing of frequency noise from the laser interrogating the atomic transition1,2. Despite recent advances in optical clock stability that have been achieved by improving laser coherence, the Dick effect has continually limited the performance of optical clocks. Here we implement a robust solution to overcome this limitation: a zero-dead-time optical clock that is based on the interleaved interrogation of two cold-atom ensembles3. This clock exhibits vanishingly small Dick noise, thereby achieving an unprecedented fractional frequency instability assessed to be for an averaging time τ in seconds. We also consider alternate dual-atom-ensemble schemes to extend laser coherence and reduce the standard quantum limit of clock stability, achieving a spectroscopy line quality factor of Q > 4 × 1015.

Soliton crystals in Kerr resonators

Abstract: Self-organized solitons confined to an optical resonator would offer unique capabilities for experiments in communication, computation and sensing with light. Here, we report the observation of soliton crystals in monolithic Kerr microresonators—spontaneously and collectively ordered ensembles of co-propagating solitons whose interactions discretize their allowed temporal separations. We unambiguously identify and characterize soliton crystals through analysis of their ‘fingerprint’ optical spectra, which arise from spectral interference between the solitons. We identify a rich space of soliton crystals exhibiting crystallographic defects and we perform time-domain measurements to directly confirm our inference of their crystal structure. Soliton crystallization is explained by long-range soliton interactions mediated by resonator mode degeneracies, and we probe the qualitative difference between soliton crystals and the disorganized soliton liquid that would form in the absence of these interactions. Our work explores the physics of monolithic Kerr resonators in a regime of dense soliton occupation and offers a way to increase the efficiency of Kerr combs. Furthermore, the extreme degeneracy of the configuration space of soliton crystals suggests an implementation for an on-chip optical buffer. The observation of soliton crystals in monolithic Kerr microresonators is reported. The physics of such resonators is explored in a regime of dense soliton occupation, offering a way to increase the efficiency of Kerr combs.

Long-distance free-space quantum key distribution in daylight towards inter-satellite communication

Abstract: In the past, long-distance free-space quantum communication experiments could only be implemented at night. During the daytime, the bright background sunlight prohibits quantum communication in transmission under conditions of high channel loss over long distances. Here, by choosing a working wavelength of 1,550 nm and developing free-space single-mode fibre-coupling technology and ultralow-noise upconversion single-photon detectors, we have overcome the noise due to sunlight and demonstrate free-space quantum key distribution over 53 km during the day. The total channel loss is ∼48 dB, which is greater than the 40 dB channel loss between the satellite and ground and between low-Earth-orbit satellites. Our system thus demonstrates the feasibility of satellite-based quantum communication in daylight. Moreover, given that our working wavelength is located in the optical telecom band, our system is naturally compatible with ground fibre networks and thus represents an essential step towards a satellite-constellation-based global quantum network. The feasibility of satellite-assisted quantum communication is demonstrated by a field test on the ground. To supress noise due to sunlight the wavelength of 1,550 nm is chosen, and spectrum and spatial filtering technology developed.

Extreme terahertz science

Abstract: In the future, sources of intense terahertz radiation will open up an era of extreme terahertz science featuring nonlinear light–matter interactions and applications in spectroscopy and imaging.

Time stretch and its applications

Abstract: Photonic time-stretch techniques and their applications are reviewed. The approach enables the observation of signals that are otherwise too short or rapid for conventional measurement. Observing non-repetitive and statistically rare signals that occur on short timescales requires fast real-time measurements that exceed the speed, precision and record length of conventional digitizers. Photonic time stretch is a data acquisition method that overcomes the speed limitations of electronic digitizers and enables continuous ultrafast single-shot spectroscopy, imaging, reflectometry, terahertz and other measurements at refresh rates reaching billions of frames per second with non-stop recording spanning trillions of consecutive frames. The technology has opened a new frontier in measurement science unveiling transient phenomena in nonlinear dynamics such as optical rogue waves and soliton molecules, and in relativistic electron bunching. It has also created a new class of instruments that have been integrated with artificial intelligence for sensing and biomedical diagnostics. We review the fundamental principles and applications of this emerging field for continuous phase and amplitude characterization at extremely high repetition rates via time-stretch spectral interferometry.

Highly efficient luminescent solar concentrators based on earth-abundant indirect-bandgap silicon quantum dots

Abstract: Building-integrated photovoltaics is gaining consensus as a renewable energy technology for producing electricity at the point of use. Luminescent solar concentrators (LSCs) could extend architectural integration to the urban environment by realizing electrode-less photovoltaic windows. Crucial for large-area LSCs is the suppression of reabsorption losses, which requires emitters with negligible overlap between their absorption and emission spectra. Here, we demonstrate the use of indirect-bandgap semiconductor nanostructures such as highly emissive silicon quantum dots. Silicon is non-toxic, low-cost and ultra-earth-abundant, which avoids the limitations to the industrial scaling of quantum dots composed of low-abundance elements. Suppressed reabsorption and scattering losses lead to nearly ideal LSCs with an optical efficiency of η = 2.85%, matching state-of-the-art semi-transparent LSCs. Monte Carlo simulations indicate that optimized silicon quantum dot LSCs have a clear path to η > 5% for 1 m2 devices. We are finally able to realize flexible LSCs with performances comparable to those of flat concentrators, which opens the way to a new design freedom for building-integrated photovoltaics elements. Reabsorption losses in luminescent solar concentrators can be avoided by the use of indirect-bandgap semiconductor nanostructures. The technology has been used to demonstrate flexible luminescent solar concentrators with performance comparable to flat concentrators.

Three-dimensional all-dielectric photonic topological insulator

Abstract: The theoretical study of a 3D photonic topological metacrystal based on an all-dielectric metamaterial platform shows robust propagation of surface states along 2D domain walls, making it a promising solution for photonics applications. The proposed metacrystal design might also open the way for the observation of elusive fundamental physical phenomena.

Single-qubit quantum memory exceeding ten-minute coherence time

Abstract: A long-time quantum memory capable of storing and measuring quantum information at the single-qubit level is an essential ingredient for practical quantum computation and communication 1,2 . Currently, the coherence time of a single qubit is limited to less than 1 min, as demonstrated in trapped ion systems 3–5 , although much longer coherence times have been reported in ensembles of trapped ions 6,7 and nuclear spins of ionized donors 8,9 . Here, we report the observation of a coherence time of over 10 min for a single qubit in a 171Yb+ ion sympathetically cooled by a 138Ba+ ion in the same Paul trap, which eliminates the problem of qubit-detection inefficiency from heating of the qubit ion 10,11 . We also apply a few thousand dynamical decoupling pulses to suppress ambient noise from magnetic-field fluctuation s and phase noise from the local os cillator 8,9,12–16 . The long-time quantum memory of the single trapped ion qubit would be the essential component of scalable quantum computers 1,17,18 , quantum networks 2,19,20 and quantum money 21,22 . The longest coherence time of a single qubit of more than ten minutes is observed in a 171Yb+ ion. After sympathetically cooling the 171Yb+ ion qubit with a 138Ba+ ion, noise from magnetic-field fluctuations and the local oscillator is suppressed by a dynamic decoupling scheme.