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3D carbon based nanostructures for advanced supercapacitors

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TLDR
In this article, a review of 3D carbon-based nanostructures for advanced supercapacitor applications is presented, which includes CNTs-based networks, graphene-based architectures, hierarchical porous carbon-bimodal structures, and other even more complex 3D configurations.
Abstract
Supercapacitors have attracted intense attention due to their great potential to meet the demand of both high energy density and power density in many advanced technologies. Various carbon-based nanocomposites are currently pursued as supercapacitor electrodes because of the synergistic effect between carbon (high power density) and pseudo-capacitive nanomaterials (high energy density). This feature article aims to review most recent progress on 3D (3D) carbon based nanostructures for advanced supercapacitor applications in view of their structural intertwinement which not only create the desired hierarchical porous channels, but also possess higher electrical conductivity and better structural mechanical stability. The carbon nanostructures comprise of CNTs-based networks, graphene-based architectures, hierarchical porous carbon-based nanostructures and other even more complex carbon-based 3D configurations. Their advantages and disadvantages are compared and summarized based on the results published in the literature. In addition, we also discuss and view the ongoing trends in materials development for advanced supercapacitors.

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Citations
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Journal ArticleDOI

Design and Mechanisms of Asymmetric Supercapacitors.

TL;DR: This review looks at the essential energy-storage mechanisms and performance evaluation criteria for asymmetric supercapacitors to understand the wide-ranging research conducted in this area and highlights several key scientific challenges.
Journal ArticleDOI

Hierarchically porous carbon derived from polymers and biomass: effect of interconnected pores on energy applications

TL;DR: In this article, a review focusing on the out-of-the-box synthetic techniques capable of deriving hierarchical porous carbons (HPCs) with superior application profiles is presented.
Journal ArticleDOI

Synthesis of functionalized 3D hierarchical porous carbon for high-performance supercapacitors

TL;DR: In this paper, a functionalized three-dimensional hierarchical porous carbon (THPC) is prepared via a facile modified chemical activation route with polypyrrole microsheets as precursor and KOH as activating agent.
Journal ArticleDOI

Asymmetric Supercapacitor Electrodes and Devices.

TL;DR: Asymmetric supercapacitors assembled using two dissimilar electrode materials offer a distinct advantage of wide operational voltage window, and thereby significantly enhance the energy density, with the main focus on an extensive survey of the materials developed for ASC electrodes.
References
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Journal ArticleDOI

Highly dispersed ruthenium oxide nanoparticles on carboxylated carbon nanotubes for supercapacitor electrode materials

TL;DR: In this paper, highly dispersed RuO2 nanoparticles were obtained on carboxylated carbon nanotubes by preventing agglomeration among RuO 2 nanoparticles by bond formation.
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Hierarchical porous nanostructures assembled from ultrathin MnO2 nanoflakes with enhanced supercapacitive performances

TL;DR: In this paper, three kinds of hierarchical porous nanostructures assembled from ultrathin MnO2 nanoflakes with different sizes and crystallinities, have been synthesized by a very simple and scalable strategy.
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Nanoarchitectured current collector for high rate capability of polyaniline based supercapacitor electrode

TL;DR: In this article, a hybrid heterostructure design of polyaniline and ITO coaxial nanowires was proposed to improve the specific capacitance, rate capability, and cycling stability of the supercapacitor electrode.
Journal ArticleDOI

Preparation and electrochemical capacitance of hierarchical graphene/polypyrrole/carbon nanotube ternary composites

TL;DR: In this paper, a ternary composites of graphene/polypyrrole/carbon nanotube (GN/PPy/CNT) has been fabricated via in situ polymerization method.
Journal ArticleDOI

PPO15-PEO22-PPO15block copolymer assisted synthesis of monolithic macro- and microporous carbon aerogels exhibiting high conductivity and remarkable capacitance

TL;DR: In this article, a PPO-PEO-PPO block copolymer assisted route was used to construct monolithic carbon aerogels exhibiting a three-dimensional continuous micro-and macroporous structure.
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