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3D carbon based nanostructures for advanced supercapacitors

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TLDR
In this article, a review of 3D carbon-based nanostructures for advanced supercapacitor applications is presented, which includes CNTs-based networks, graphene-based architectures, hierarchical porous carbon-bimodal structures, and other even more complex 3D configurations.
Abstract
Supercapacitors have attracted intense attention due to their great potential to meet the demand of both high energy density and power density in many advanced technologies. Various carbon-based nanocomposites are currently pursued as supercapacitor electrodes because of the synergistic effect between carbon (high power density) and pseudo-capacitive nanomaterials (high energy density). This feature article aims to review most recent progress on 3D (3D) carbon based nanostructures for advanced supercapacitor applications in view of their structural intertwinement which not only create the desired hierarchical porous channels, but also possess higher electrical conductivity and better structural mechanical stability. The carbon nanostructures comprise of CNTs-based networks, graphene-based architectures, hierarchical porous carbon-based nanostructures and other even more complex carbon-based 3D configurations. Their advantages and disadvantages are compared and summarized based on the results published in the literature. In addition, we also discuss and view the ongoing trends in materials development for advanced supercapacitors.

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Citations
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A melt route for the synthesis of activated carbon derived from carton box for high performance symmetric supercapacitor applications

TL;DR: In this paper, a facile strategy is proposed for generating porosity in porous carbons by using carton box as the precursor and eutectic NaOH-KOH melt as the activating agent.
Journal ArticleDOI

Controllable Synthesis of Functional Hollow Carbon Nanostructures with Dopamine As Precursor for Supercapacitors.

TL;DR: A facile one-step synthesis of discrete and highly dispersible N-HCSs with dopamine as a carbon precursor and TEOS as a structure-assistant agent in a mixture containing water, ethanol, and ammonia is reported.
Journal ArticleDOI

Core–shell reduced graphene oxide/MnOx@carbon hollow nanospheres for high performance supercapacitor electrodes

TL;DR: In this article, the reduced graphene oxide (RGO)/MnO x @carbon hollow nanospheres (HCNs) nanohybrids were fabricated for high performance supercapacitor application.
Journal ArticleDOI

Three-dimensional porous graphene/polyaniline composites for high-rate electrochemical capacitors

TL;DR: In this article, an electrochemical co-deposition method was used to prepare three-dimensional (3D) porous composites of reduced graphene oxide (rGO) and polyaniline (PANI) with pores vertically oriented on the surfaces of current collectors and used as an electrode material for electrochemical capacitors.
Journal ArticleDOI

Three dimensional architectures: design, assembly and application in electrochemical capacitors

TL;DR: In this paper, the current progress of different synthetic processes with respect to the preparation of 3D supercapacitors electrodes and focuses on both template-assisted and non-template strategies.
References
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The rise of graphene

TL;DR: Owing to its unusual electronic spectrum, graphene has led to the emergence of a new paradigm of 'relativistic' condensed-matter physics, where quantum relativistic phenomena can now be mimicked and tested in table-top experiments.
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Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene

TL;DR: Graphene is established as the strongest material ever measured, and atomically perfect nanoscale materials can be mechanically tested to deformations well beyond the linear regime.
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Issues and challenges facing rechargeable lithium batteries

TL;DR: A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
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Materials for electrochemical capacitors

TL;DR: This work has shown that combination of pseudo-capacitive nanomaterials, including oxides, nitrides and polymers, with the latest generation of nanostructured lithium electrodes has brought the energy density of electrochemical capacitors closer to that of batteries.
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Superior Thermal Conductivity of Single-Layer Graphene

TL;DR: The extremely high value of the thermal conductivity suggests that graphene can outperform carbon nanotubes in heat conduction and establishes graphene as an excellent material for thermal management.
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