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3D carbon based nanostructures for advanced supercapacitors

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TLDR
In this article, a review of 3D carbon-based nanostructures for advanced supercapacitor applications is presented, which includes CNTs-based networks, graphene-based architectures, hierarchical porous carbon-bimodal structures, and other even more complex 3D configurations.
Abstract
Supercapacitors have attracted intense attention due to their great potential to meet the demand of both high energy density and power density in many advanced technologies. Various carbon-based nanocomposites are currently pursued as supercapacitor electrodes because of the synergistic effect between carbon (high power density) and pseudo-capacitive nanomaterials (high energy density). This feature article aims to review most recent progress on 3D (3D) carbon based nanostructures for advanced supercapacitor applications in view of their structural intertwinement which not only create the desired hierarchical porous channels, but also possess higher electrical conductivity and better structural mechanical stability. The carbon nanostructures comprise of CNTs-based networks, graphene-based architectures, hierarchical porous carbon-based nanostructures and other even more complex carbon-based 3D configurations. Their advantages and disadvantages are compared and summarized based on the results published in the literature. In addition, we also discuss and view the ongoing trends in materials development for advanced supercapacitors.

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Citations
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Easy fabrication and high electrochemical capacitive performance of hierarchical porous carbon by a method combining liquid-liquid phase separation and pyrolysis process

TL;DR: A hierarchical porous carbon membrane was designed and prepared through a method combining liquid-liquid phase separation and then pyrolysis process using polyacrylonitrile (PAN) as precursor as discussed by the authors.
Journal ArticleDOI

Interfacial Engineering of Hierarchical Transition Metal Oxide Heterostructures for Highly Sensitive Sensing of Hydrogen Peroxide.

TL;DR: The synergistic effects for enhanced H2 O2 adsorption in integrated CuO-CoO nanostructures and performance of the sensor suggest a potential for exploring pathological and physiological roles of reactive oxygen species like H2O2 in biological systems.
Journal ArticleDOI

ZnO-assisted synthesis of lignin-based ultra-fine microporous carbon nanofibers for supercapacitors.

TL;DR: In this work, ultra-fine porous carbon nanofibers prepared by electrospinning using lignin/ polyvinylpyrrolidone as carbon precursor and zinc nitrate hexahydrate as an additive show exceptional cycling stability in symmetrical supercapacitors, manifesting a promising application prospect in the next generation of superCapacitors.
Journal ArticleDOI

Facile preparation of graphene/polyaniline composite hydrogel film by electrodeposition for binder-free all-solid-state supercapacitor

TL;DR: In this paper, the free-standing reduced graphene oxide (rGO) hydrogel film is hydrothermally synthesized from a GO solution layer, which is used for subsequent electropolymerization of PANI.
Journal ArticleDOI

Integration of VS2 nanosheets into carbon for high energy density micro-supercapacitor

TL;DR: In this paper, a pyrolyzed carbon/vanadium disulfide nanosheets (C/VS2) microelectrode based MSC was fabricated by modern micromachining photolithography.
References
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The rise of graphene

TL;DR: Owing to its unusual electronic spectrum, graphene has led to the emergence of a new paradigm of 'relativistic' condensed-matter physics, where quantum relativistic phenomena can now be mimicked and tested in table-top experiments.
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Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene

TL;DR: Graphene is established as the strongest material ever measured, and atomically perfect nanoscale materials can be mechanically tested to deformations well beyond the linear regime.
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Issues and challenges facing rechargeable lithium batteries

TL;DR: A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
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Materials for electrochemical capacitors

TL;DR: This work has shown that combination of pseudo-capacitive nanomaterials, including oxides, nitrides and polymers, with the latest generation of nanostructured lithium electrodes has brought the energy density of electrochemical capacitors closer to that of batteries.
Journal ArticleDOI

Superior Thermal Conductivity of Single-Layer Graphene

TL;DR: The extremely high value of the thermal conductivity suggests that graphene can outperform carbon nanotubes in heat conduction and establishes graphene as an excellent material for thermal management.
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