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Journal ArticleDOI

3D carbon based nanostructures for advanced supercapacitors

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TLDR
In this article, a review of 3D carbon-based nanostructures for advanced supercapacitor applications is presented, which includes CNTs-based networks, graphene-based architectures, hierarchical porous carbon-bimodal structures, and other even more complex 3D configurations.
Abstract
Supercapacitors have attracted intense attention due to their great potential to meet the demand of both high energy density and power density in many advanced technologies. Various carbon-based nanocomposites are currently pursued as supercapacitor electrodes because of the synergistic effect between carbon (high power density) and pseudo-capacitive nanomaterials (high energy density). This feature article aims to review most recent progress on 3D (3D) carbon based nanostructures for advanced supercapacitor applications in view of their structural intertwinement which not only create the desired hierarchical porous channels, but also possess higher electrical conductivity and better structural mechanical stability. The carbon nanostructures comprise of CNTs-based networks, graphene-based architectures, hierarchical porous carbon-based nanostructures and other even more complex carbon-based 3D configurations. Their advantages and disadvantages are compared and summarized based on the results published in the literature. In addition, we also discuss and view the ongoing trends in materials development for advanced supercapacitors.

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Citations
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Journal ArticleDOI

Molecular Insights into the Complex Relationship between Capacitance and Pore Morphology in Nanoporous Carbon-based Supercapacitors.

TL;DR: This paper presents the concept of ion reorganization kinetics during charge/discharge cycles, especially within highly confining subnanometer pores, which necessarily dictates the capacitance and proposes that a new structural descriptor, coined as the pore shape factor, can provide a new avenue for materials optimization.
Journal ArticleDOI

One-step construction of 3D N/P-codoped hierarchically porous carbon framework in-situ armored Mn3O4 nanoparticles for high-performance flexible supercapacitors

TL;DR: In this paper, a 3D N/P-codoped hierarchically porous carbon framework in-situ armored Mn3O4 nanoparticles (NPCM/Mn 3O4) was proposed to improve the conductivity and prevent the aggregation of nanoparticles.
Journal ArticleDOI

Density functional theory study of Li binding to graphene

TL;DR: In this paper, the authors studied the interaction between Li and graphene by considering two kinds of models, which are related to the configurations of Li adsorption and the concentration of Li on graphene.
Journal ArticleDOI

Preparation of Porous Carbons Using NaOH, K <sub>2</sub> CO <sub>3</sub> , Na <sub>2</sub> CO <sub>3</sub> and Na <sub>2</sub> S <sub>2</sub> O <sub>3</sub> Activating Agents and Their Supercapacitor Application: A Comparative Study

TL;DR: In this article , an alternative preparation method for porous carbons using NaOH, K2CO3, Na2 CO3 and Na2S2O3 as activating agents was reported.
Book ChapterDOI

Nanotechnology in energy storage: the supercapacitors

TL;DR: Supercapacitors (SCs) as mentioned in this paper are the two main parameters of an energy storage device system, energy and power densities, which are two main parameter of an EH device system.
References
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Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene

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Journal ArticleDOI

Issues and challenges facing rechargeable lithium batteries

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Journal ArticleDOI

Materials for electrochemical capacitors

TL;DR: This work has shown that combination of pseudo-capacitive nanomaterials, including oxides, nitrides and polymers, with the latest generation of nanostructured lithium electrodes has brought the energy density of electrochemical capacitors closer to that of batteries.
Journal ArticleDOI

Superior Thermal Conductivity of Single-Layer Graphene

TL;DR: The extremely high value of the thermal conductivity suggests that graphene can outperform carbon nanotubes in heat conduction and establishes graphene as an excellent material for thermal management.
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