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3D carbon based nanostructures for advanced supercapacitors

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TLDR
In this article, a review of 3D carbon-based nanostructures for advanced supercapacitor applications is presented, which includes CNTs-based networks, graphene-based architectures, hierarchical porous carbon-bimodal structures, and other even more complex 3D configurations.
Abstract
Supercapacitors have attracted intense attention due to their great potential to meet the demand of both high energy density and power density in many advanced technologies. Various carbon-based nanocomposites are currently pursued as supercapacitor electrodes because of the synergistic effect between carbon (high power density) and pseudo-capacitive nanomaterials (high energy density). This feature article aims to review most recent progress on 3D (3D) carbon based nanostructures for advanced supercapacitor applications in view of their structural intertwinement which not only create the desired hierarchical porous channels, but also possess higher electrical conductivity and better structural mechanical stability. The carbon nanostructures comprise of CNTs-based networks, graphene-based architectures, hierarchical porous carbon-based nanostructures and other even more complex carbon-based 3D configurations. Their advantages and disadvantages are compared and summarized based on the results published in the literature. In addition, we also discuss and view the ongoing trends in materials development for advanced supercapacitors.

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Journal ArticleDOI

Zinc tartrate oriented hydrothermal synthesis of microporous carbons for high performance supercapacitor electrodes

TL;DR: In this article, a zinc tartrate oriented hydrothermal synthesis of microporous carbons was reported, which achieved high surface area (up to 1255m 2 /g) and large mean pore size (1.99nm).
Journal ArticleDOI

Bioinspired Sea-sponge Nanostructure Design of Ni/Ni(HCO3)2-on-C for Supercapacitor with Superior Anti-fading Capacity

TL;DR: In this paper, a bioinspired sea-sponge nanostructure of Ni/Ni(HCO3)2-on-C, synthesized through modifying triangle nanoflakes of Ni (HCO 3)2 with partially in situ reduced Ni generated on sea sponge-like porous carbon spheres (S-PCSs), was proposed to tackle capacity fading issues of battery-type electrode materials for supercapacitors.
Journal ArticleDOI

Zinc removal from aqueous solution using a deionization pseudocapacitor with a high-performance nanostructured birnessite electrode

TL;DR: In this paper, a facile method for the rapid synthesis of nanostructured birnessite and highly efficient removal of Zn2+ from aqueous solution was proposed.
Journal ArticleDOI

Density functional theory study on the adsorption of alkali metal ions with pristine and defected graphene sheet

TL;DR: In this article, the authors have investigated the structural properties of the graphite-based materials along with the adsorption of alkali metal ions for energy conversion and storage applications.
References
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Journal ArticleDOI

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Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene

TL;DR: Graphene is established as the strongest material ever measured, and atomically perfect nanoscale materials can be mechanically tested to deformations well beyond the linear regime.
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Issues and challenges facing rechargeable lithium batteries

TL;DR: A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
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Materials for electrochemical capacitors

TL;DR: This work has shown that combination of pseudo-capacitive nanomaterials, including oxides, nitrides and polymers, with the latest generation of nanostructured lithium electrodes has brought the energy density of electrochemical capacitors closer to that of batteries.
Journal ArticleDOI

Superior Thermal Conductivity of Single-Layer Graphene

TL;DR: The extremely high value of the thermal conductivity suggests that graphene can outperform carbon nanotubes in heat conduction and establishes graphene as an excellent material for thermal management.
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