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3D carbon based nanostructures for advanced supercapacitors

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TLDR
In this article, a review of 3D carbon-based nanostructures for advanced supercapacitor applications is presented, which includes CNTs-based networks, graphene-based architectures, hierarchical porous carbon-bimodal structures, and other even more complex 3D configurations.
Abstract
Supercapacitors have attracted intense attention due to their great potential to meet the demand of both high energy density and power density in many advanced technologies. Various carbon-based nanocomposites are currently pursued as supercapacitor electrodes because of the synergistic effect between carbon (high power density) and pseudo-capacitive nanomaterials (high energy density). This feature article aims to review most recent progress on 3D (3D) carbon based nanostructures for advanced supercapacitor applications in view of their structural intertwinement which not only create the desired hierarchical porous channels, but also possess higher electrical conductivity and better structural mechanical stability. The carbon nanostructures comprise of CNTs-based networks, graphene-based architectures, hierarchical porous carbon-based nanostructures and other even more complex carbon-based 3D configurations. Their advantages and disadvantages are compared and summarized based on the results published in the literature. In addition, we also discuss and view the ongoing trends in materials development for advanced supercapacitors.

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Citations
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Journal ArticleDOI

Hierarchical mesoporous CoS2 microspheres: Morphology-controlled synthesis and their superior pseudocapacitive properties

TL;DR: In this article, a simple and novel strategy has been developed for the morphology-controlled synthesis of hierarchical CoS2 microspheres for supercapacitors and other electrochemical applications.
Journal ArticleDOI

Printable multi-walled carbon nanotubes thin film for high performance all solid state flexible supercapacitors

TL;DR: In this paper, an all-solid-state flexible supercapacitor is assembled using multi-walled carbon nanotubes (MWCNT) and ionic liquid 1-ethyl-3methylimidazolium tetrafluoroborate [EMIM][BF4] based gel polymer electrolyte.
Journal ArticleDOI

Synthesis of Cobalt Sulfide/Sulfur Doped Carbon Nanocomposites with Efficient Catalytic Activity in the Oxygen Evolution Reaction

TL;DR: Electrochemical data showed that Co9 S8 /S-C had a good activity and long-term stability in catalyzing oxygen evolution reaction in alkaline electrolyte, even better than the traditional RuO2 electrocatalyst.
Journal ArticleDOI

Investigation of cyclic voltammetry of graphene oxide/polyaniline/polyvinylidene fluoride nanofibers prepared via electrospinning

TL;DR: In this paper, the morphology of obtained nanofibers was characterized by scanning electron microscope and the specific capacitance of 170.63 F/g was obtained for GO/PANI/PVDF nanofibrers, which evidently shows a new pathway for the development of these nanofiberers for futuristic supercapacitor applications.
Journal ArticleDOI

A simple CaCO3-assisted template carbonization method for producing nitrogen doped porous carbons as electrode materials for supercapacitors

TL;DR: A series of nitrogen doped porous carbons are prepared using a simple and economic template carbonization method, in which nano-CaCO3 and ethylenediamine (EDA) and carbon tetrachloride (CTC) serve as a template and nitrogen-containing carbon precursors, respectively as discussed by the authors.
References
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The rise of graphene

TL;DR: Owing to its unusual electronic spectrum, graphene has led to the emergence of a new paradigm of 'relativistic' condensed-matter physics, where quantum relativistic phenomena can now be mimicked and tested in table-top experiments.
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Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene

TL;DR: Graphene is established as the strongest material ever measured, and atomically perfect nanoscale materials can be mechanically tested to deformations well beyond the linear regime.
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Issues and challenges facing rechargeable lithium batteries

TL;DR: A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
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Materials for electrochemical capacitors

TL;DR: This work has shown that combination of pseudo-capacitive nanomaterials, including oxides, nitrides and polymers, with the latest generation of nanostructured lithium electrodes has brought the energy density of electrochemical capacitors closer to that of batteries.
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Superior Thermal Conductivity of Single-Layer Graphene

TL;DR: The extremely high value of the thermal conductivity suggests that graphene can outperform carbon nanotubes in heat conduction and establishes graphene as an excellent material for thermal management.
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