Journal ArticleDOI
Catalytic activities of Schiff base transition metal complexes
K.C. Gupta,Alekha Kumar Sutar +1 more
TLDR
A review of the catalytic activity of metal complexes of binaphthyl compounds and their combinations with salen Schiff base is presented in this paper, where the pyridyl bis (imide) and pyridine bis(imine) complexes of cobalt(II), iron(II) ions have been used as catalysts in the polymerization of ethylene and propylene.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2008-07-01. It has received 1237 citations till now. The article focuses on the topics: Schiff base & Imine.read more
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Book ChapterDOI
Assemblies Based on Schiff Base Chemistry
TL;DR: In this article, the development of design strategies and self-assembly pathways of metal-based systems incorporating Schiff base ligands is discussed, and the metal-directed selfassembly of Schiff bases has also experienced considerable attention in offering a route toward fabrication of multinuclear assemblies.
Journal ArticleDOI
Crystal structures of ten enanti-opure Schiff bases bearing a naphthyl group.
G. Hernández-Téllez,Gloria E. Moreno,Sylvain Bernès,Angel Mendoza,Oscar Portillo,Pankaj Sharma,René Gutiérrez +6 more
TL;DR: Enantiopure imines synthesized starting from 2-naphthaldehyde and chiral liquid amines were characterized by X-ray diffraction.
Journal ArticleDOI
Azobenzene based Zn(II)/Ru(II) coordination-organometallic hybrid complexes: Influence of π-conjugation, donor/acceptor substituent's and coligands on electrochemical, luminescence and NLO properties
TL;DR: In this article, a series of azobenzene based heterobinuclear coordination-organometallic hybrid complexes of the type [Zn(phen)(R C6H4HC N(O)C6H3N NC6H 4C CRu(dppe)2Cl)]X (1a-6a) and [ Zn(bipy)(R 6H4H 4H 4N NC 6H 4E 2Cl]X(1b-6b) have been prepared and characterized.
Journal ArticleDOI
Two new supramolecular compounds based on Ni(II)-Schiff-base and Keggin-type [PMo12O40]3−
TL;DR: In this article, two polyoxometalate-templated nickel-Schiff-base compounds, {Ni(L)2]2[PMo12O40][Cl] · DMSO · CH3OH · 0.5H2O} n (2), were synthesized in situ from Ni2+ and L in H 2O/DMF/CH3OH or H2O/DMSO/Ch3OH at room temperature.
Journal ArticleDOI
New enamine ligands derived from ethyl 2-ethoxymethylidene-3-oxo-3-polyfluoroalkylpropionates and o -phenylenediamine
TL;DR: The use of equimolar ratios of the starting reactants affords ethyl 2]-(2-aminophenyl)aminomethylidene]-3-oxo-3-polyfluoroalkylpropionates from which nonsymmetric biscondensation products were synthesized by the reaction with related reactants containing different polyfluoro-alkyl substituent The copper(II), nickel(II, and cobalt(II) complexes were obtained on the basis of new ligands.
References
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Journal ArticleDOI
The heck reaction as a sharpening stone of palladium catalysis.
TL;DR: s, or keywords if they used Heck-type chemistry in their syntheses, because it became one of basic tools of organic preparations, a natural way to make organic preparations.
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The Development of L2X2RuCHR Olefin Metathesis Catalysts: An Organometallic Success Story
Tina M. Trnka,Robert H. Grubbs +1 more
TL;DR: The discussion includes an analysis of trends in catalyst activity, a description of catalysts coordinated with N-heterocyclic carbene ligands, and an overview of ongoing work to improve the activity, stability, and selectivity of this family of L2X2Ru=CHR complexes.
Journal ArticleDOI
Late-metal catalysts for ethylene homo- and copolymerization.
Book
Catalytic Asymmetric Synthesis
TL;DR: Asymmetric Hydrogenation (T. Ohkuma, et al. as discussed by the authors ), asymmetric carbon-Carbon Bond-Forming Reactions (K. Nozaki & I. Negishi). Asymmetric Addition and Insertion Reactions of Catalytically-Generated Metal Carbenes (M. O'Donnell), and asymptotic phase-transfer Reactions.