Journal ArticleDOI
Catalytic activities of Schiff base transition metal complexes
K.C. Gupta,Alekha Kumar Sutar +1 more
TLDR
A review of the catalytic activity of metal complexes of binaphthyl compounds and their combinations with salen Schiff base is presented in this paper, where the pyridyl bis (imide) and pyridine bis(imine) complexes of cobalt(II), iron(II) ions have been used as catalysts in the polymerization of ethylene and propylene.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2008-07-01. It has received 1237 citations till now. The article focuses on the topics: Schiff base & Imine.read more
Citations
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Supramolecular coordination: self-assembly of finite two- and three-dimensional ensembles.
TL;DR: In the early 1960s, the discovery of crown ethers and spherands by Pedersen, Lehn, and Cram3 led to the realization that small, complementary molecules can be made to recognize each other through non-covalent interactions such as hydrogen-bonding, charge-charge, donor-acceptor, π-π, van der Waals, hydrophilic and hydrophobic interactions to achieve these highly complex and often symmetrical architectures as mentioned in this paper.
Journal ArticleDOI
Zr-based metal-organic frameworks: design, synthesis, structure, and applications.
TL;DR: Advances in Zr-MOFs since 2008 are summarized and reviewed from three aspects: design and synthesis, structure, and applications to provide guidance for the in-depth investigation of MOFs towards practical applications.
Journal ArticleDOI
Synthesis of cyclic carbonates from epoxides and CO2
TL;DR: In this article, the synthesis of cyclic carbonates by the 100% atom economical reaction between epoxides and CO2 is reviewed in the context of reducing global emissions of waste CO 2 and converting waste CO2 into industrially useful chemical feedstocks.
Journal ArticleDOI
First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands.
TL;DR: This review aims at providing a comprehensive picture of the utilization of functional pincer ligands in first-row transition metal hydrogenation and dehydrogenation catalysis and related synthetic concepts relying on these such as the hydrogen borrowing methodology.
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A review on versatile applications of transition metal complexes incorporating Schiff bases
TL;DR: This review compiles examples of the most promising applied Schiff bases and their complexes in different areas and explains how to understand the properties of both ligands and metal can lead to the synthesis of highly active compounds.
References
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Journal ArticleDOI
Synthesis and Characterization of a Polymer-Supported Salen Ligand for Enantioselective Epoxidation
TL;DR: In this paper, a covalently linked salen complex was constructed on the surface of a 98 vol % styrene/2 vol % divinylbenzene polymeric support.
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Amination of aromatic olefins with anilines: a new domino synthesis of quinolines.
TL;DR: Mechanistic investigations strongly support the regioselective oxidative amination of styrene as the key reaction step.
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Autoxidation of substituted phenols catalyzed by cobalt Schiff base complexes in supercritical carbon dioxide
TL;DR: This first study of O(2) oxidation (autoxidation) of substituted phenols catalyzed by a dioxygen carrier in supercritical carbon dioxide (scCO(2)) provides additional insights into the established mechanism of reactions that have been much studied in conventional solvents.
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Rhodium versus ruthenium: contrasting behaviour in the asymmetric transfer hydrogenation of α-substituted acetophenones
TL;DR: In this paper, the reduction of α-substituted acetophenones has been achieved using both ruthenium(II)- and rhodium(III)-based asymmetric transfer hydrogenation catalysts employing formic acid as the hydrogen donor.
Journal ArticleDOI
Regioselectivity of the ring-opening polymerization of monofunctional alkyl-substituted aromatic amine-based benzoxazines
Hatsuo Ishida,Daniel P. Sanders +1 more
TL;DR: The reaction site of ring-opening polymerization in monofunctional aromatic amine-based benzoxazines has been investigated through systematic manipulation of the monomer chemistry as discussed by the authors.