Journal ArticleDOI
Catalytic activities of Schiff base transition metal complexes
K.C. Gupta,Alekha Kumar Sutar +1 more
TLDR
A review of the catalytic activity of metal complexes of binaphthyl compounds and their combinations with salen Schiff base is presented in this paper, where the pyridyl bis (imide) and pyridine bis(imine) complexes of cobalt(II), iron(II) ions have been used as catalysts in the polymerization of ethylene and propylene.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2008-07-01. It has received 1237 citations till now. The article focuses on the topics: Schiff base & Imine.read more
Citations
More filters
Journal ArticleDOI
Supramolecular coordination: self-assembly of finite two- and three-dimensional ensembles.
TL;DR: In the early 1960s, the discovery of crown ethers and spherands by Pedersen, Lehn, and Cram3 led to the realization that small, complementary molecules can be made to recognize each other through non-covalent interactions such as hydrogen-bonding, charge-charge, donor-acceptor, π-π, van der Waals, hydrophilic and hydrophobic interactions to achieve these highly complex and often symmetrical architectures as mentioned in this paper.
Journal ArticleDOI
Zr-based metal-organic frameworks: design, synthesis, structure, and applications.
TL;DR: Advances in Zr-MOFs since 2008 are summarized and reviewed from three aspects: design and synthesis, structure, and applications to provide guidance for the in-depth investigation of MOFs towards practical applications.
Journal ArticleDOI
Synthesis of cyclic carbonates from epoxides and CO2
TL;DR: In this article, the synthesis of cyclic carbonates by the 100% atom economical reaction between epoxides and CO2 is reviewed in the context of reducing global emissions of waste CO 2 and converting waste CO2 into industrially useful chemical feedstocks.
Journal ArticleDOI
First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands.
TL;DR: This review aims at providing a comprehensive picture of the utilization of functional pincer ligands in first-row transition metal hydrogenation and dehydrogenation catalysis and related synthetic concepts relying on these such as the hydrogen borrowing methodology.
Journal ArticleDOI
A review on versatile applications of transition metal complexes incorporating Schiff bases
TL;DR: This review compiles examples of the most promising applied Schiff bases and their complexes in different areas and explains how to understand the properties of both ligands and metal can lead to the synthesis of highly active compounds.
References
More filters
Journal ArticleDOI
Regioselective synthesis of ibuprofen via the palladium complex catalyzed hydrocarboxylation of 1-(4-isobutylphenyl) ethanol
TL;DR: In this article, the synthesis of 2-(4-isobutylphenyl) propionic acid (ibuprofen) by the hydrocarboxylation of 1-(4isobuthphenyl)-ethyl ethanol with carbon monoxide and water has been studied in the presence of PdCl 2 -PPh 3 -HCl catalyst system.
Journal ArticleDOI
Preparation and reactivities of chiral manganese(III) and copper(II) complexes of binaphthyl Schiff bases
TL;DR: In this article, a series of chiral Schiff bases, 2,2′-bis(3-R1-5-R2-2-hydroxybenzylideneamino)-1,1′-binaphthyl H2L (R2= Cl, R1= Cl or NO2; R2= Me, R 1= But; R 2= NO2, R2 = H, H, Me, Et, Pri, But or Cl), and their complexes [CuL1]1 and [Mn2L12
Journal ArticleDOI
Catalytic and physico-chemical properties of new Schiff base complexes in zeolites
TL;DR: In this article, a relation between the appearance of low-field features in the Mn(II) EPR spectra and a high activity in hydrocarbon oxidation was proposed, based on adsorption of the pyridine derived pyren and pyrpn ligands on MnIINaY zeolites.
Journal ArticleDOI
New mono- and di-nuclear complexes of PdII, PtII and NiII of PNNP ligands with a 2,2′-biaryl bridging unit
Alette G.J. Ligtenbarg,Esther K. van den Beuken,Auke Meetsma,Nora Veldman,Wilberth J. J. Smeets,Anthony L. Spek,Bernard Feringa +6 more
TL;DR: In this paper, the Schiff bases 2,2′-bis{N-[(2-diphenylphosphino)phenyl]formimidoyl}biphensyl (L1) and 2, 2′-is{[(2diphexylphphoenino)benzylidene]amino}binhenyl (l2) were synthesized from the appropriate amine and aldehyde.
Journal ArticleDOI
The oxyfunctionalization of cyclohexane catalyzed by Mn(II) complexes included in zeolite Y
TL;DR: In this article, the authors showed that the transition metal complex immobilized on zeolite Y represent a good cytochrome P-450 type oxidation system with ligands of 2,2′-bipyridine, ethylenediamine, tetramethylethylenedienine, and tetramethyl 1,8-naphtalenediamines included in zeolinite Y.