Journal ArticleDOI
Catalytic activities of Schiff base transition metal complexes
K.C. Gupta,Alekha Kumar Sutar +1 more
TLDR
A review of the catalytic activity of metal complexes of binaphthyl compounds and their combinations with salen Schiff base is presented in this paper, where the pyridyl bis (imide) and pyridine bis(imine) complexes of cobalt(II), iron(II) ions have been used as catalysts in the polymerization of ethylene and propylene.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2008-07-01. It has received 1237 citations till now. The article focuses on the topics: Schiff base & Imine.read more
Citations
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Journal ArticleDOI
New stable aryl-substituted acyclic imino-N-heterocyclic carbene: synthesis, characterisation and coordination to early transition metals
TL;DR: The absence of acidic protons adjacent to the iminic carbon allowed for the first isolation of an imino-N-heterocyclic carbene of this ligand class.
Journal ArticleDOI
Nanomolar-level selective dual channel sensing of Cu2+ and CN- from an aqueous medium by an opto-electronic chemoreceptor.
S. N. Paul,S. N. Paul,Pritam Ghosh,Samuzal Bhuyan,Subhra Kanti Mukhopadhyay,Priyabrata Banerjee,Priyabrata Banerjee +6 more
TL;DR: In vitro fluorescence imaging in male microspores of seed plants and Monilia Albicans with TyM and Cu2+ confirmed the permeability of the chemoreceptor TyM at the cellular level as well as its ability to investigate transition metals, such as Cu2+, in biological samples.
Journal ArticleDOI
Synthesis and characterization of rare-earth metal complexes supported by a new pentadentate Schiff base and their application in heteroselective polymerization of rac-lactide
TL;DR: A series of neutral rare-earth metal aryloxides and amides supported by a new pentadentate (N2O3) salen ligand were synthesized, and their catalytic behaviors for the ring-opening polymerization of rac-lactide (rac-LA) were explored as mentioned in this paper.
Journal ArticleDOI
Synthesis, structural characterization and catalytic activity study of Mn(II), Fe(III), Ni(II), Cu(II) and Zn(II) complexes of quinoxaline-2-carboxalidine-2-amino-5-methylphenol: Crystal structure of the nickel(II) complex
Manju Sebastian,V. Arun,P.P. Robinson,Annu Anna Varghese,Rani Abraham,Eringathodi Suresh,K. K. Mohammed Yusuff +6 more
TL;DR: In this article, a tridentate Schiff base ligand was used to synthesize transition metal complexes for catalytic phenol hydroxylation reaction and the results showed that the complexes were active catalysts.
Journal ArticleDOI
Two- and Three-Electron Oxidation of Single-Site Vanadium Centers at Surfaces by Ligand Design.
Daniel Skomski,Christopher D. Tempas,Brian J. Cook,Alexander V. Polezhaev,Kevin A. Smith,Kenneth G. Caulton,Steven L. Tait +6 more
TL;DR: The ability to control metal oxidation states in surface coordination architectures by altering the redox properties of organic ligands is shown, offering new opportunities in controlling the oxidation state of single-site transition metal atoms at a surface for new advances in heterogeneous catalysts.
References
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Journal ArticleDOI
The heck reaction as a sharpening stone of palladium catalysis.
TL;DR: s, or keywords if they used Heck-type chemistry in their syntheses, because it became one of basic tools of organic preparations, a natural way to make organic preparations.
Journal ArticleDOI
The Development of L2X2RuCHR Olefin Metathesis Catalysts: An Organometallic Success Story
Tina M. Trnka,Robert H. Grubbs +1 more
TL;DR: The discussion includes an analysis of trends in catalyst activity, a description of catalysts coordinated with N-heterocyclic carbene ligands, and an overview of ongoing work to improve the activity, stability, and selectivity of this family of L2X2Ru=CHR complexes.
Journal ArticleDOI
Late-metal catalysts for ethylene homo- and copolymerization.
Book
Catalytic Asymmetric Synthesis
TL;DR: Asymmetric Hydrogenation (T. Ohkuma, et al. as discussed by the authors ), asymmetric carbon-Carbon Bond-Forming Reactions (K. Nozaki & I. Negishi). Asymmetric Addition and Insertion Reactions of Catalytically-Generated Metal Carbenes (M. O'Donnell), and asymptotic phase-transfer Reactions.