Journal ArticleDOI
Catalytic activities of Schiff base transition metal complexes
K.C. Gupta,Alekha Kumar Sutar +1 more
TLDR
A review of the catalytic activity of metal complexes of binaphthyl compounds and their combinations with salen Schiff base is presented in this paper, where the pyridyl bis (imide) and pyridine bis(imine) complexes of cobalt(II), iron(II) ions have been used as catalysts in the polymerization of ethylene and propylene.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2008-07-01. It has received 1237 citations till now. The article focuses on the topics: Schiff base & Imine.read more
Citations
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Supramolecular coordination: self-assembly of finite two- and three-dimensional ensembles.
TL;DR: In the early 1960s, the discovery of crown ethers and spherands by Pedersen, Lehn, and Cram3 led to the realization that small, complementary molecules can be made to recognize each other through non-covalent interactions such as hydrogen-bonding, charge-charge, donor-acceptor, π-π, van der Waals, hydrophilic and hydrophobic interactions to achieve these highly complex and often symmetrical architectures as mentioned in this paper.
Journal ArticleDOI
Zr-based metal-organic frameworks: design, synthesis, structure, and applications.
TL;DR: Advances in Zr-MOFs since 2008 are summarized and reviewed from three aspects: design and synthesis, structure, and applications to provide guidance for the in-depth investigation of MOFs towards practical applications.
Journal ArticleDOI
Synthesis of cyclic carbonates from epoxides and CO2
TL;DR: In this article, the synthesis of cyclic carbonates by the 100% atom economical reaction between epoxides and CO2 is reviewed in the context of reducing global emissions of waste CO 2 and converting waste CO2 into industrially useful chemical feedstocks.
Journal ArticleDOI
First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands.
TL;DR: This review aims at providing a comprehensive picture of the utilization of functional pincer ligands in first-row transition metal hydrogenation and dehydrogenation catalysis and related synthetic concepts relying on these such as the hydrogen borrowing methodology.
Journal ArticleDOI
A review on versatile applications of transition metal complexes incorporating Schiff bases
TL;DR: This review compiles examples of the most promising applied Schiff bases and their complexes in different areas and explains how to understand the properties of both ligands and metal can lead to the synthesis of highly active compounds.
References
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Recent advances in enantioselective hydroformylation
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Catalysts for the Asymmetric Transfer Hydrogenation of Ketones Derived from l-Prolinamide and (p-CymeneRuCl2)2 or (Cp*RhCl2)2
TL;DR: In this paper, the combination of l-prolinamide with (p-CymeneRuCl2)2 or (Cp*RhCl2), in the presence of KOH/2-propanol, has been found to generate catalysts in situ that are capable of enantioselectively reducing aryl ketones to the respective (R)-alcohols.
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Extremely High Enantioselective Redox Reaction of Ketones and Alcohols Catalyzed by RuCl2(PPh3)(oxazolinylferrocenylphosphine)
TL;DR: The ruthenium complex RuCl2(PPh3) has been found to be a quite effective catalyst for asymmetric transfer hydrogenation of not only alkyl aryl ketones but also alkyls methyl ketones with iPrOH.
Journal ArticleDOI
Catalysis in the preparation of fragrances and flavours
Christian Chapuis,Denis Jacoby +1 more
TL;DR: A review of recent progress in industrial catalysis can be found in this article, where applications in classical reactions, such as hydrogenations, isomerisations, hydride reductions, oxidations, hydroformylations, metathesis, aldol and Friedel-Crafts condensations in achiral, racemic and asymmetric fashion are discussed.
Journal ArticleDOI
Palladium-catalyzed allylic alkylation of tert-butyl(diphenylmethylene)-glycinate with simple allyl esters under chiral phase transfer conditions
Guoshu Chen,Yijian Deng,Liu-Zhu Gong,Aiqiao Mi,Xin Cui,Yaozhong Jiang,Michael C. K. Choi,Albert S. C. Chan +7 more
TL;DR: The first example of palladium-catalyzed allylic alkylation of an imino ester with simple allyl esters in the presence of a chiral quaternary ammonium salt is reported in this article.