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Journal ArticleDOI

Catalytic activities of Schiff base transition metal complexes

K.C. Gupta, +1 more
- 01 Jul 2008 - 
- Vol. 252, Iss: 252, pp 1420-1450
TLDR
A review of the catalytic activity of metal complexes of binaphthyl compounds and their combinations with salen Schiff base is presented in this paper, where the pyridyl bis (imide) and pyridine bis(imine) complexes of cobalt(II), iron(II) ions have been used as catalysts in the polymerization of ethylene and propylene.
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This article is published in Coordination Chemistry Reviews.The article was published on 2008-07-01. It has received 1237 citations till now. The article focuses on the topics: Schiff base & Imine.

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Palladium(II) complex with a potential N4-type Schiff-base ligand as highly efficient catalyst for Suzuki–Miyaura reactions in aqueous media

TL;DR: In this article, two new air-stable palladium(II) complexes containing a N 4 -Schiff base ligand have been synthesized and investigated as catalysts for additive-free Suzuki-Miyaura reactions of bromides in neat water at room temperature and aryl chlorides in aqueous-glycerol at 80°C.
Journal ArticleDOI

Highly selective olefin epoxidation with the bicarbonate activation of hydrogen peroxide in the presence of manganese(III) meso-tetraphenylporphyrin complex: Optimization of effective parameters using the Taguchi method

TL;DR: In this paper, a MnIII-porphyrin-based catalytic system was explored for olefin epoxidations under mild reaction conditions using sodium bicarbonate-hydrogen peroxide as an oxidant.
Journal ArticleDOI

Molecular docking and DFT studies on some nano-meter binuclear complexes derived from hydrazine-carbothioamide ligand, synthesis, thermal, kinetic and spectral characterization

TL;DR: In this article, a Schiff base ligand was used to verify the structural and molecular formula of the organic ligand and its isolated complexes using IR, 1HNMR and mass spectra.
Journal ArticleDOI

Synthesis and structures of two cobalt(III) complexes with N4 donor ligands: Isolation of a unique bis-hemiaminal ether ligand as the metal complex

TL;DR: Two cobalt(III) complexes, [CoL1(N3)2]ClO4·H2O (1) and [ CoL2(N 3]NO3 (2), have been prepared and characterized by elemental analysis, IR and UVVis spectroscopy, cyclic voltammetry and single crystal X-ray diffraction studies as mentioned in this paper.
Journal ArticleDOI

Hydrogenation and Redox Isomerization of Allylic Alcohols Catalyzed by a New Water-Soluble Pd–tetrahydrosalen Complex

TL;DR: In this paper, sulfonated tetrahydrosalen (sulfosalan, HSS) was synthesized by sulfonation of tetrasalen in fuming sulfuric acid and showed outstanding activity in hydrogenation and redox isomerization of allylic alcohols.
References
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Journal ArticleDOI

Comprehensive Organometallic Chemistry

Dietmar Seyferth
- 01 Jul 1984 - 
Journal ArticleDOI

The heck reaction as a sharpening stone of palladium catalysis.

TL;DR: s, or keywords if they used Heck-type chemistry in their syntheses, because it became one of basic tools of organic preparations, a natural way to make organic preparations.
Journal ArticleDOI

The Development of L2X2RuCHR Olefin Metathesis Catalysts: An Organometallic Success Story

TL;DR: The discussion includes an analysis of trends in catalyst activity, a description of catalysts coordinated with N-heterocyclic carbene ligands, and an overview of ongoing work to improve the activity, stability, and selectivity of this family of L2X2Ru=CHR complexes.
Book

Catalytic Asymmetric Synthesis

Iwao Ojima
TL;DR: Asymmetric Hydrogenation (T. Ohkuma, et al. as discussed by the authors ), asymmetric carbon-Carbon Bond-Forming Reactions (K. Nozaki & I. Negishi). Asymmetric Addition and Insertion Reactions of Catalytically-Generated Metal Carbenes (M. O'Donnell), and asymptotic phase-transfer Reactions.
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