Journal ArticleDOI
Catalytic activities of Schiff base transition metal complexes
K.C. Gupta,Alekha Kumar Sutar +1 more
TLDR
A review of the catalytic activity of metal complexes of binaphthyl compounds and their combinations with salen Schiff base is presented in this paper, where the pyridyl bis (imide) and pyridine bis(imine) complexes of cobalt(II), iron(II) ions have been used as catalysts in the polymerization of ethylene and propylene.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2008-07-01. It has received 1237 citations till now. The article focuses on the topics: Schiff base & Imine.read more
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Imines in the Titanium Coordination Sphere: η1-Imine Complexes as Sources of Azavinylidenes and Four-Membered Imine–Amido-N,N′ Chelates
TL;DR: In this paper, the potential of imines to coordinate through the lone pair of electrons of the nitrogen atom by a dative bond to the titanium center is studied, and the formation of bis-η1 complexes by the reaction of Schiff bases with titanium(IV) chloride was observed.
Journal ArticleDOI
Tetranuclear Cu(II) complex with [2+4] Cu4O4 cubane based core framework derived from 2-[{2-(1-hydroxy-ethyl)-phenylimino}-methyl]-6-methoxy-phenol: Quantifying conventional and unconventional interactions and QTAIM analysis
TL;DR: A cubane based tetranuclear copper(II) complex prepared using 2-[{2-(1-hydroxy-ethyl)-phenylimino}-methyl]-6-methoxy-phenol and copper (II) acetate has been characterized by spectral techniques and single-crystal X-ray diffraction studies as discussed by the authors .
Journal ArticleDOI
Some novel nanostructure Schiff base compounds: Antimicrobial and thermal behaviors
Journal ArticleDOI
Synthesis of novel polycarbonyl Schiff bases by ring-opening reaction of ethyl 5-acyl-4-pyrone-2-carboxylates with primary mono- and diamines
TL;DR: An approach for the introduction of tricarbonyl moiety into aromatic, heterocyclic, and aliphatic amines with the use of acylpyrones has been developed for the synthesis and the design of novel polycarbonyl Schiff base ligands, including salphen structures as discussed by the authors.
Journal ArticleDOI
Synthesis and structure characterization of homoleptic lanthanide complexes stabilized by Schiff-base ligands and their application in the polymerization of ε-caprolactone
TL;DR: A series of homoleptic lanthanide complexes supported by Schiff-base ligands were synthesized by the amine elimination reactions of monophenol ligands as discussed by the authors, and the catalytic properties of these complexes were studied and found that all complexes were efficient initiators for this ring-opening polymerization reaction that afforded polycaprolactone with high molecular weights and moderate molecular-weight distributions.
References
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The heck reaction as a sharpening stone of palladium catalysis.
TL;DR: s, or keywords if they used Heck-type chemistry in their syntheses, because it became one of basic tools of organic preparations, a natural way to make organic preparations.
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The Development of L2X2RuCHR Olefin Metathesis Catalysts: An Organometallic Success Story
Tina M. Trnka,Robert H. Grubbs +1 more
TL;DR: The discussion includes an analysis of trends in catalyst activity, a description of catalysts coordinated with N-heterocyclic carbene ligands, and an overview of ongoing work to improve the activity, stability, and selectivity of this family of L2X2Ru=CHR complexes.
Journal ArticleDOI
Late-metal catalysts for ethylene homo- and copolymerization.
Book
Catalytic Asymmetric Synthesis
TL;DR: Asymmetric Hydrogenation (T. Ohkuma, et al. as discussed by the authors ), asymmetric carbon-Carbon Bond-Forming Reactions (K. Nozaki & I. Negishi). Asymmetric Addition and Insertion Reactions of Catalytically-Generated Metal Carbenes (M. O'Donnell), and asymptotic phase-transfer Reactions.