Journal ArticleDOI
Catalytic activities of Schiff base transition metal complexes
K.C. Gupta,Alekha Kumar Sutar +1 more
TLDR
A review of the catalytic activity of metal complexes of binaphthyl compounds and their combinations with salen Schiff base is presented in this paper, where the pyridyl bis (imide) and pyridine bis(imine) complexes of cobalt(II), iron(II) ions have been used as catalysts in the polymerization of ethylene and propylene.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2008-07-01. It has received 1237 citations till now. The article focuses on the topics: Schiff base & Imine.read more
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Supramolecular coordination: self-assembly of finite two- and three-dimensional ensembles.
TL;DR: In the early 1960s, the discovery of crown ethers and spherands by Pedersen, Lehn, and Cram3 led to the realization that small, complementary molecules can be made to recognize each other through non-covalent interactions such as hydrogen-bonding, charge-charge, donor-acceptor, π-π, van der Waals, hydrophilic and hydrophobic interactions to achieve these highly complex and often symmetrical architectures as mentioned in this paper.
Journal ArticleDOI
Zr-based metal-organic frameworks: design, synthesis, structure, and applications.
TL;DR: Advances in Zr-MOFs since 2008 are summarized and reviewed from three aspects: design and synthesis, structure, and applications to provide guidance for the in-depth investigation of MOFs towards practical applications.
Journal ArticleDOI
Synthesis of cyclic carbonates from epoxides and CO2
TL;DR: In this article, the synthesis of cyclic carbonates by the 100% atom economical reaction between epoxides and CO2 is reviewed in the context of reducing global emissions of waste CO 2 and converting waste CO2 into industrially useful chemical feedstocks.
Journal ArticleDOI
First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands.
TL;DR: This review aims at providing a comprehensive picture of the utilization of functional pincer ligands in first-row transition metal hydrogenation and dehydrogenation catalysis and related synthetic concepts relying on these such as the hydrogen borrowing methodology.
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A review on versatile applications of transition metal complexes incorporating Schiff bases
TL;DR: This review compiles examples of the most promising applied Schiff bases and their complexes in different areas and explains how to understand the properties of both ligands and metal can lead to the synthesis of highly active compounds.
References
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Asymmetric trimethylsilylcyanation of benzaldehyde catalyzed by novel Ti(IV)-chiral Schiff base complexes
Zi Guo-Fu,Yin Cheng-Lie +1 more
TL;DR: In this paper, a trimethylsilylcyanated benzaldehyde has been used with a catalyst prepared in situ from titanium tetraisopropoxide and chiral Schiff bases.
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Cu(I)-Binaphthyldiimine Catalyzed Asymmetric Cyclopropanation of Olefin with Diazoacetate
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Synthesis, structure and catalytic activity of new chiral nitrogen-containing ligands
TL;DR: The use of nitrogen-containing ligands for asymmetric catalysis has received growing interest in the last years as discussed by the authors, and the synthesis of three new ligands (5c, 5d and 6) and the X-ray structure analysis of 5c and of the copper-II complex 6-Cu(II)OTf.
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Enantioselective catalysis. Part 148: Carbohydrate-derived oxime ethers stable towards hydrolysis—syntheses of ligands and complexes and a study of their catalytic properties ☆
TL;DR: In this paper, the synthesis of new hydrolytically stable oxime ether ligands by condensation of various aldehydes with O-β- d -glucopyranosylhydroxylamine 1 or O-α-d -galactopyrano-nyl-hydroxyl groups was described.
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Studies on CoSalen immobilized onto N-(4-pyridylmethylidene)–chitosan
TL;DR: In this article, a chitosan (CS) derivative, N-(4-pyridylmethylidene)−CS (PMC), was synthesized and a cobalt(II) complex of bis(salicylideneethylene diamine) (CoSalen) was immobilized on it.