Journal ArticleDOI
Catalytic activities of Schiff base transition metal complexes
K.C. Gupta,Alekha Kumar Sutar +1 more
TLDR
A review of the catalytic activity of metal complexes of binaphthyl compounds and their combinations with salen Schiff base is presented in this paper, where the pyridyl bis (imide) and pyridine bis(imine) complexes of cobalt(II), iron(II) ions have been used as catalysts in the polymerization of ethylene and propylene.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2008-07-01. It has received 1237 citations till now. The article focuses on the topics: Schiff base & Imine.read more
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Crystal structure of {N-(2-hydroxyethylamino) ethylsalicylaldiminato]-palladium(II) chloride}: Synthesis, X-ray structure, electrochemistry, DFT and TDDFT studies
Ali Hasnaoui,Ismail Hdoufane,Rachid Idouhli,Bruno Therrien,Mustapha Ait Ali,Larbi El Firdoussi +5 more
TL;DR: In this article, a new complex N-(2-hydroxyethylamino)ethylsalicylaldiminato]-palladium(II) chloride [Pd(L)Cl] was synthesized by the reaction in ethanol of the Schiff base 2-(2-(2]-ethylaminino)ethylimino)methyl phenol (LH) and Li2PdCl4.
Journal ArticleDOI
Synthesis, crystal structures, optical properties, DFT and TD-DFT studies of Ni (II) complexes with imine-based ligands
Abdelmadjid Kherrouba,Rafik Bensegueni,Mounia Guergouri,Ahlem-Linda Boulkedid,Mehdi Boutebdja,Mustapha Bencharif +5 more
TL;DR: In this article, two new square-planar nickel (II) complexes were synthesized from (2-((E)-(9-ethyl-9H-carbazol-7-ylimino)methyl)phenol) and (1-((S)-(S-ethyl 9H- carbazol 7-Ylimino)-naphthalen-2-ol) ligands, for complex I and complex II, respectively.
Journal ArticleDOI
A bi-nuclear Cu(II)-complex for selective epoxidation of alkenes: Crystal structure, thermal, photoluminescence and cyclic voltammetry
TL;DR: In this article, a 3D supramolecular structure of a binuclear Cu(II)-complex has been reported, which is stable up to 230°C in a chiral monoclinic P21/n space group.
Journal ArticleDOI
One-pot synthesis of bimetal MOFs as highly efficient catalysts for selective oxidation of styrene
TL;DR: A series of novel bimetallic organic framework materials (Cux-Coy-MOF) have been successfully prepared by a simple one-pot synthetic method, and their characters were evaluated via means of various techniques as discussed by the authors.
Journal ArticleDOI
An unusual Cu(II) complex of a Schiff-base ligand of 3-aminoquinoline with a hydronated pyridine unit: Synthesis, characterizations, and computational studies
Sanjit Nayak,Sanjit Nayak,Andrej Pevec,Colin C. Seaton,Patrick Gamez,Patrick Gamez,Jan Reedijk,Jan Reedijk +7 more
TL;DR: A very unusual Cu(II) compound of formula [Cu(mqmp)2(ClO4)2] was synthesized in situ from a one-pot reaction between copper(II)-perchlorate and a Schiff base ligand, abbreviated mqmp. The resulting compound, bearing positively charged side groups was characterized using single-crystal X-ray diffraction, elemental analysis, electrospray-ionization mass spectrometry (ESI-MS), infrared spectroscopy (IR), ligand-field (LF) spectrosc
References
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Journal ArticleDOI
The heck reaction as a sharpening stone of palladium catalysis.
TL;DR: s, or keywords if they used Heck-type chemistry in their syntheses, because it became one of basic tools of organic preparations, a natural way to make organic preparations.
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The Development of L2X2RuCHR Olefin Metathesis Catalysts: An Organometallic Success Story
Tina M. Trnka,Robert H. Grubbs +1 more
TL;DR: The discussion includes an analysis of trends in catalyst activity, a description of catalysts coordinated with N-heterocyclic carbene ligands, and an overview of ongoing work to improve the activity, stability, and selectivity of this family of L2X2Ru=CHR complexes.
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Catalytic Asymmetric Synthesis
TL;DR: Asymmetric Hydrogenation (T. Ohkuma, et al. as discussed by the authors ), asymmetric carbon-Carbon Bond-Forming Reactions (K. Nozaki & I. Negishi). Asymmetric Addition and Insertion Reactions of Catalytically-Generated Metal Carbenes (M. O'Donnell), and asymptotic phase-transfer Reactions.