Journal ArticleDOI
Catalytic activities of Schiff base transition metal complexes
K.C. Gupta,Alekha Kumar Sutar +1 more
TLDR
A review of the catalytic activity of metal complexes of binaphthyl compounds and their combinations with salen Schiff base is presented in this paper, where the pyridyl bis (imide) and pyridine bis(imine) complexes of cobalt(II), iron(II) ions have been used as catalysts in the polymerization of ethylene and propylene.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2008-07-01. It has received 1237 citations till now. The article focuses on the topics: Schiff base & Imine.read more
Citations
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Journal ArticleDOI
Study of the structure–bioactivity relationship of three new pyridine Schiff bases: synthesis, spectral characterization, DFT calculations and biological assays
Alexander Carreño,César Zúñiga,Dayán Páez-Hernández,Manuel Gacitúa,Rubén Polanco,Carolina Otero,Ramiro Arratia-Pérez,Juan A. Fuentes +7 more
TL;DR: In this article, three new pyridine Schiff bases were synthesized and characterized to explore their structure-bioactivity relationship as antifungal agents and provided data supporting a correlation between the structure and bioactivity in this kind of Schiff base.
Journal ArticleDOI
Organic–inorganic hybrid tinphosphonate material with mesoscopic void spaces: an excellent catalyst for the radical polymerization of styrene
TL;DR: In this article, a new porous tinphosphonate HSnP-1 has been synthesized through the reaction of butylene-1,4-diphosphonic acid and SnCl4·5H2O under hydrothermal conditions at 453 K for 3 days in the absence of any structure directing agent.
Journal ArticleDOI
Introducing Metallosalens into Biological Studies: The Renaissance of Traditional Coordination Complexes
TL;DR: In this paper, a microreview of recent advances in metallosalens in biological applications is presented, divided into four categories: DNA binding, fluorescent imaging, magnetic resonance imaging, and potential drugs.
Journal ArticleDOI
Pronounced Catalytic Activity of Manganese(III)–Schiff Base Complexes in the Oxidation of Alcohols by Tetrabutylammonium Peroxomonosulfate
TL;DR: In this article, a novel and practical catalytic method for efficient and highly selective oxidation of a wide range of benzylic, allylic, aliphatic, primary, and secondary alcohols to the corresponding aldehydes and ketones using tetrabutylammonium peroxomonosulfate catalyzed by tetradentate Schiff base-MnIII complexes has been developed.
Journal ArticleDOI
When is an imine not an imine? Unusual reactivity of a series of Cu(II) imine-pyridine complexes and their exploitation for the Henry reaction
Christine J. Cooper,Matthew D. Jones,Simon K. Brayshaw,Benjamin Sonnex,Mark L. Russell,Mary F. Mahon,David R. Allan +6 more
TL;DR: The synthesis and solid-state structures for a series of pyridine based Cu(II) complexes and preliminary data for the asymmetric Henry reaction indicate the incorporation of an alcohol into one of the imine groups of the ligand, forming a rare α-amino ether group.
References
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Journal ArticleDOI
The heck reaction as a sharpening stone of palladium catalysis.
TL;DR: s, or keywords if they used Heck-type chemistry in their syntheses, because it became one of basic tools of organic preparations, a natural way to make organic preparations.
Journal ArticleDOI
The Development of L2X2RuCHR Olefin Metathesis Catalysts: An Organometallic Success Story
Tina M. Trnka,Robert H. Grubbs +1 more
TL;DR: The discussion includes an analysis of trends in catalyst activity, a description of catalysts coordinated with N-heterocyclic carbene ligands, and an overview of ongoing work to improve the activity, stability, and selectivity of this family of L2X2Ru=CHR complexes.
Journal ArticleDOI
Late-metal catalysts for ethylene homo- and copolymerization.
Book
Catalytic Asymmetric Synthesis
TL;DR: Asymmetric Hydrogenation (T. Ohkuma, et al. as discussed by the authors ), asymmetric carbon-Carbon Bond-Forming Reactions (K. Nozaki & I. Negishi). Asymmetric Addition and Insertion Reactions of Catalytically-Generated Metal Carbenes (M. O'Donnell), and asymptotic phase-transfer Reactions.