Journal ArticleDOI
Catalytic activities of Schiff base transition metal complexes
K.C. Gupta,Alekha Kumar Sutar +1 more
TLDR
A review of the catalytic activity of metal complexes of binaphthyl compounds and their combinations with salen Schiff base is presented in this paper, where the pyridyl bis (imide) and pyridine bis(imine) complexes of cobalt(II), iron(II) ions have been used as catalysts in the polymerization of ethylene and propylene.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2008-07-01. It has received 1237 citations till now. The article focuses on the topics: Schiff base & Imine.read more
Citations
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Homoleptic Cobalt(II) Phenoxyimine Complexes for Hydrosilylation of Aldehydes and Ketones without Base Activation of Cobalt(II)
TL;DR: In this article, homoleptic cobalt(II) complexes bearing pendant-modified phenoxyimine ligands were synthesized and determined, and the complexes exhibited high catalytic performance for re...
Journal ArticleDOI
Selective Oxidation of Thiols and Alcohols by Physically Encapsulated Nickel Schiff-Base Complex Prepared Via Sol-Gel Method as Nano-Catalyst
TL;DR: In this article, a heterogeneous catalyst was prepared by direct physical encapsulation of nickel Schiff-base complex into the silicon dioxide matrix via sol-gel method, which was characterized by FT-IR, SEM, TEM, XRD, CHNS, and AAS.
Journal ArticleDOI
Synthesis, Spectral Characterization and Thermal Behavior of Newly Derived La(III), Co(III) and Mn(II) Complexes with Schiff Base Derived from Methionine and Salicylaldehyde
TL;DR: In this article, three new metal complexes with the Schiff base (L) derived from salicylaldehyde and amino acid (methionine) were synthesized and investigated by using various physico-chemical techniques such as elemental analysis, FTIR, UV-visible spectroscopy, magnetic measurement, thermo gravimetric analysis (TGA) and X-ray powder diffraction (XRD) method.
Journal ArticleDOI
Bis(2-hydroxyiminomethyl-6-methoxyphenolato-κ2O1,N)cobalt(II)
TL;DR: In this paper, the CoII atom lies on a center of inversion and is coordinated in a slightly distorted square-planar geometry by two N and two O atoms from the 2-hydroxy-imino-methyl-6-methoxyphenolate ligands.
References
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The heck reaction as a sharpening stone of palladium catalysis.
TL;DR: s, or keywords if they used Heck-type chemistry in their syntheses, because it became one of basic tools of organic preparations, a natural way to make organic preparations.
Journal ArticleDOI
The Development of L2X2RuCHR Olefin Metathesis Catalysts: An Organometallic Success Story
Tina M. Trnka,Robert H. Grubbs +1 more
TL;DR: The discussion includes an analysis of trends in catalyst activity, a description of catalysts coordinated with N-heterocyclic carbene ligands, and an overview of ongoing work to improve the activity, stability, and selectivity of this family of L2X2Ru=CHR complexes.
Journal ArticleDOI
Late-metal catalysts for ethylene homo- and copolymerization.
Book
Catalytic Asymmetric Synthesis
TL;DR: Asymmetric Hydrogenation (T. Ohkuma, et al. as discussed by the authors ), asymmetric carbon-Carbon Bond-Forming Reactions (K. Nozaki & I. Negishi). Asymmetric Addition and Insertion Reactions of Catalytically-Generated Metal Carbenes (M. O'Donnell), and asymptotic phase-transfer Reactions.