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Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures

Mark V. Khenkin, +67 more
- 01 Jan 2020 - 
- Vol. 5, Iss: 1, pp 35-49
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TLDR
A consensus between researchers in the field is reported on procedures for testing perovskite solar cell stability, which are based on the International Summit on Organic Photovoltaic Stability (ISOS) protocols, and additional procedures to account for properties specific to PSCs are proposed.
Abstract
Improving the long-term stability of perovskite solar cells is critical to the deployment of this technology. Despite the great emphasis laid on stability-related investigations, publications lack consistency in experimental procedures and parameters reported. It is therefore challenging to reproduce and compare results and thereby develop a deep understanding of degradation mechanisms. Here, we report a consensus between researchers in the field on procedures for testing perovskite solar cell stability, which are based on the International Summit on Organic Photovoltaic Stability (ISOS) protocols. We propose additional procedures to account for properties specific to PSCs such as ion redistribution under electric fields, reversible degradation and to distinguish ambient-induced degradation from other stress factors. These protocols are not intended as a replacement of the existing qualification standards, but rather they aim to unify the stability assessment and to understand failure modes. Finally, we identify key procedural information which we suggest reporting in publications to improve reproducibility and enable large data set analysis. Reliability of stability data for perovskite solar cells is undermined by a lack of consistency in the test conditions and reporting. This Consensus Statement outlines practices for testing and reporting stability tailoring ISOS protocols for perovskite devices.

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Citations
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Perovskite solar cells with atomically coherent interlayers on SnO2 electrodes.

TL;DR: In this paper, a coherent interlayer between a SnO2 electron-transporting layer and a halide perovskite light-absorbing layer, achieved by coupling Cl-bonded SnO 2 with a Cl-containing perovsite precursor, was proposed.
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Semiconductor quantum dots: Technological progress and future challenges

TL;DR: In quantum-confined semiconductor nanostructures, electrons exhibit distinctive behavior compared with that in bulk solids as mentioned in this paper, which enables the design of materials with tunable chemical, physical, electrical, and optical properties.
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The 2D Halide Perovskite Rulebook: How the Spacer Influences Everything from the Structure to Optoelectronic Device Efficiency.

TL;DR: In this paper, the authors provide guidelines on successfully choosing spacers and incorporating them into crystalline materials and optoelectronic devices and provide a summary of various synthetic methods to act as a tutorial for groups interested in pursuing synthesis of novel 2D halide perovskites.
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Towards commercialization: the operational stability of perovskite solar cells

TL;DR: The main target of this review is gaining insight into the operational stability of PSCs, as well as providing useful guidance to further improve their operational lifetime by rational materials processing and device fabrication, which would finally promote the commercialization of perovskite solar cells.
References
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Journal ArticleDOI

Chemical Management for Colorful, Efficient, and Stable Inorganic–Organic Hybrid Nanostructured Solar Cells

TL;DR: This paper demonstrates highly efficient solar cells exhibiting 12.3% in a power conversion efficiency of under standard AM 1.5, for the most efficient device, as a result of tunable composition for the light harvester in conjunction with a mesoporous TiO2 film and a hole conducting polymer.
Journal ArticleDOI

Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency

TL;DR: In this paper, the triple cation perovskite photovoltaics with inorganic cesium were shown to be thermally more stable, contain less phase impurities and are less sensitive to processing conditions.
Journal ArticleDOI

A hole-conductor-free, fully printable mesoscopic perovskite solar cell with high stability

TL;DR: A perovskite solar cell that uses a double layer of mesoporous TiO2 and ZrO2 as a scaffold infiltrated with perovSkite and does not require a hole-conducting layer is fabricated and achieves a certified power conversion efficiency of 12.8%.
Journal ArticleDOI

High-efficiency two-dimensional Ruddlesden–Popper perovskite solar cells

TL;DR: Thin films of near-single-crystalline quality are produced, in which the crystallographic planes of the inorganic perovskite component have a strongly preferential out-of-plane alignment with respect to the contacts in planar solar cells to facilitate efficient charge transport.
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