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Journal ArticleDOI

Dispersion and alignment of carbon nanotubes in polymer matrix: A review

TLDR
In this article, the authors review recent progress and advances that have been made on: (a) dispersion of CNTs in a polymer matrix, including optimum blending, in situ polymerization and chemical functionalization; and (b) alignment of CNNs in the matrix enhanced by ex situ techniques, force and magnetic fields, electrospinning and liquid crystalline phase-induced methods.
Abstract
Polymer/carbon nanotube (CNT) composites are expected to have good processability characteristics of the polymer and excellent functional properties of the CNTs. The critical challenge, however, is how to enhance dispersion and alignment of CNTs in the matrix. Here, we review recent progress and advances that have been made on: (a) dispersion of CNTs in a polymer matrix, including optimum blending, in situ polymerization and chemical functionalization; and (b) alignment of CNTs in the matrix enhanced by ex situ techniques, force and magnetic fields, electrospinning and liquid crystalline phase-induced methods. In addition, discussions on mechanical, thermal, electrical, electrochemical, optical and super-hydrophobic properties; and applications of polymer/CNT composites are included. Enhanced dispersion and alignment of CNTs in the polymer matrix will promote and extend the applications and developments of polymer/CNT nanocomposites.

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Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites: a review

TL;DR: In this paper, a review of the current understanding of carbon nanotubes and CNT/polymer nanocomposites with two particular topics: (i) the principles and techniques for CNT dispersion and functionalization and (ii) the effects of CNT-based functionalization on the properties of polymers.
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Graphene-based polymer nanocomposites

TL;DR: A survey of the literature on polymer nanocomposites with graphene-based fillers including recent work using graphite nanoplatelet fillers is presented in this article, along with methods for dispersing these materials in various polymer matrices.
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Effects of particle size, particle/matrix interface adhesion and particle loading on mechanical properties of particulate–polymer composites

TL;DR: In this article, the effects of particle size, particle/matrix interface adhesion and particle loading on the stiffness, strength and toughness of such particulate polymer composites are reviewed.
Journal ArticleDOI

Thermal conductivity of carbon nanotubes and their polymer nanocomposites: A review

TL;DR: In this article, the status of worldwide research in the thermal conductivity of carbon nanotubes and their polymer nanocomposites is reviewed, as well as the relationship between thermal conductivities and the micro- and nano-structure of the composites.
Journal ArticleDOI

Polymer nanocomposites based on functionalized carbon nanotubes

TL;DR: There are several methods for the dispersion of CNTs in the polymer matrix such as solution mixing, melt mixing, electrospinning, in-situ polymerization and chemical functionalization of the carbon nanotubes as discussed by the authors.
References
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Journal ArticleDOI

Plasma Activation of Carbon Nanotubes for Chemical Modification

TL;DR: In this article, a novel approach for chemical modification of carbon nanotubes was developed, which involved radio frequency glow-discharge plasma activation, followed by chemical reactions characteristic of the plasma generated functional groups.
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Thermo-physical and impact properties of epoxy nanocomposites reinforced by single-wall carbon nanotubes

TL;DR: In this article, a sonication technique was used to disperse fluorinated single-wall carbon nanotubes (FSWCNT) in the glassy epoxy network resulting in nanocomposites having large improvement in modulus with extremely small amount of FSWCNT.
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In-plane-aligned membranes of carbon nanotubes

TL;DR: In this paper, the first macroscopic objects comprised of highly aligned single-wall carbon nanotubes (SWNTs) were produced by producing a suspension of SWNT segments, introducing the suspension to a strong magnetic field to align the segments, and filtering the suspension in the magnetic field.
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A Microscopic and Spectroscopic Study of Interactions between Carbon Nanotubes and a Conjugated Polymer

TL;DR: In this article, a conjugated, semiconducting polymer was examined by a range of microscopic and spectroscopic techniques, to gain a greater understanding of the binding between polymer and nanotubes.
Journal ArticleDOI

A Generic Organometallic Approach toward Ultra-Strong Carbon Nanotube Polymer Composites

TL;DR: Multiwalled carbon nanotubes have been functionalized using n-butyllithium and then covalently bonded to a chlorinated polypropylene polymer matrix, potentially leading to new ultra-strong polymer composite materials.
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