Journal ArticleDOI
Electrocatalytic Oxygen Evolution Reaction (OER) on Ru, Ir, and Pt Catalysts: A Comparative Study of Nanoparticles and Bulk Materials
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In this article, the intrinsic catalytic activity and durability of carbon supported Ru, Ir, and Pt nanoparticles and corresponding bulk materials for the electrocatalytic oxygen evolution reaction (OER) were examined by surface-sensitive cyclic voltammetry.Abstract:
A comparative investigation was performed to examine the intrinsic catalytic activity and durability of carbon supported Ru, Ir, and Pt nanoparticles and corresponding bulk materials for the electrocatalytic oxygen evolution reaction (OER). The electrochemical surface characteristics of nanoparticles and bulk materials were studied by surface-sensitive cyclic voltammetry. Although basically similar voltammetric features were observed for nanoparticles and bulk materials of each metal, some differences were uncovered highlighting the changes in oxidation chemistry. On the basis of the electrochemical results, we demonstrated that Ru nanoparticles show lower passivation potentials compared to bulk Ru material. Ir nanoparticles completely lost their voltammetric metallic features during the voltage cycling, in contrast to the corresponding bulk material. Finally, Pt nanoparticles show an increased oxophilic nature compared to bulk Pt. With regard to the OER performance, the most pronounced effects of nanosca...read more
Citations
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Electrocatalysis for the oxygen evolution reaction: recent development and future perspectives
TL;DR: This review acquaints some materials for performing OER activity, in which the metal oxide materials build the basis of OER mechanism while non-oxide materials exhibit greatly promising performance toward overall water-splitting.
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Recent Trends and Perspectives in Electrochemical Water Splitting with an Emphasis on Sulfide, Selenide, and Phosphide Catalysts of Fe, Co, and Ni: A Review
Sengeni Anantharaj,Sivasankara Rao Ede,Kuppan Sakthikumar,Kannimuthu Karthick,Soumyaranjan Mishra,Subrata Kundu,Subrata Kundu +6 more
TL;DR: In this article, the hydrogen (H2) and oxygen (O2) fuel cell is the one with zero carbon emission and water as the only byproduct, which is essential to ensure higher life cycle and less decay in cell efficiency.
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Oxygen electrochemistry as a cornerstone for sustainable energy conversion
TL;DR: A promising strategy to develop such an understanding is the investigation of the impact of material properties on reaction activity/selectivity and on catalyst stability under the conditions of operation, as well as the application of complementary in situ techniques for the Investigation of catalyst structure and composition.
Journal ArticleDOI
Electrocatalytic oxygen evolution reaction for energy conversion and storage: A comprehensive review
Muhammad Tahir,Muhammad Tahir,Lun Pan,Lun Pan,Faryal Idrees,Xiangwen Zhang,Li Wang,Ji-Jun Zou,Zhong Lin Wang,Zhong Lin Wang +9 more
TL;DR: In this paper, a review article summarizes the very recent efforts in the field of OER electrocatalysis along with the faced challenges and solutions to these challenges also outline with appropriate examples of scientific literatures.
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Electrically Rechargeable Zinc–Air Batteries: Progress, Challenges, and Perspectives
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References
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Adsorption of bisulfate on the Ru(0001) single crystal electrode surface
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Particle Size Dependence of the Electrocatalytic Activity of Nanocrystalline RuO2 Electrodes
TL;DR: In this article, the effect of nanocrystal size/shape on the electrocatalytic behavior of polygonal prismatic oxide electrodes was demonstrated on electrodes based on sol-gel-prepared RuO 2 materials.
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Electron Transfer Through Thin Anodic Oxide Films during the Oxygen Evolution Reactions at Pt Electrodes: I . Acid Solutions
TL;DR: In this paper, the authors present a method for the synthesis of a new type of graphite called graphite-based graphite, which they call graphite graphite (Graphite Graphite), and present in the Journal of the Electrochemical Society (JES).
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Iridium Anodic Oxidation to Ir(III) and Ir(IV) Hydrous Oxides
TL;DR: In this article, the authors used cyclic voltammetry and chronopotentiometry to find out the reasons of super-Nernstian pH-sensitivity of iridium oxide films.