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Open AccessJournal ArticleDOI

Kinetically Stable Single Crystals of Perovskite-Phase CsPbI3

Daniel B. Straus, +2 more
- 08 Jul 2019 - 
- Vol. 141, Iss: 29, pp 11435-11439
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TLDR
In this article, a solid-state method was used to synthesize single crystals of perovskite-phase cesium lead iodide (γ-CsPbI3) that are kinetically stable at room temperature.
Abstract
We use a solid-state method to synthesize single crystals of perovskite-phase cesium lead iodide (γ-CsPbI3) that are kinetically stable at room temperature. Single crystal X-ray diffraction charact...

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Citations
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Journal ArticleDOI

The Role of Dimethylammonium Iodide in CsPbI 3 Perovskite Fabrication: Additive or Dopant?

TL;DR: This work demonstrated that the DMAI is an effective volatile additive to manipulate the crystallization process of CsPbI 3 inorganic perovskite films with different crystal phases and morphologies and confirmed the time-of-flight secondary ion mass spectrometry and nuclear magnetic resonance results confirmed the D MAI additive would not alloy into CsDMAI 3 perovksite 's crystal lattice.
Journal ArticleDOI

Printable CsPbI3 Perovskite Solar Cells with PCE of 19% via an Additive Strategy

TL;DR: In this article, high-quality CsPbI3 films are grown via introducing a low concentration of the multifunctional molecular additive Zn(C6 F5 )2, which reconciles the conflict between air-flow-assisted fast drying and low-quality film including energy misalignment and trap formation.
Journal ArticleDOI

Chemically Stable Black Phase CsPbI 3 Inorganic Perovskites for High-Efficiency Photovoltaics

TL;DR: The latest experimental and theoretical studies on the fundamental physical properties of photoactive phase CsPbI3 have deepened the understanding of inorganic perovskites and will further advance inorganicperovskite for highly stable and efficient photovoltaics.
Journal ArticleDOI

A “Tips and Tricks” Practical Guide to the Synthesis of Metal Halide Perovskite Nanocrystals

TL;DR: The metal halide perovskite nanocrystals offer a range of interesting properties and are being studied extensively for applications in solar cells, photodetectors and light-emitting devices as discussed by the authors.
Journal ArticleDOI

Understanding the Instability of the Halide Perovskite CsPbI3 through Temperature-Dependent Structural Analysis.

TL;DR: In this paper, single-crystal X-ray diffraction and Xray pair distribution function (PDF) measurements characterize bulk perovskite CsPbI3 from 100 to 295 K to elucidate its thermodynamic instability.
References
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Journal ArticleDOI

Crystal structure refinement with SHELXL

TL;DR: New features added to the refinement program SHELXL since 2008 are described and explained.
Journal ArticleDOI

OLEX2: a complete structure solution, refinement and analysis program

TL;DR: OLEX2 seamlessly links all aspects of the structure solution, refinement and publication process and presents them in a single workflow-driven package, with the ultimate goal of producing an application which will be useful to both chemists and crystallographers.
Journal ArticleDOI

SHELXT - Integrated space-group and crystal- structure determination

TL;DR: This work automates routine small-molecule structure determination starting from single-crystal reflection data, the Laue group and a reasonable guess as to which elements might be present.
Journal ArticleDOI

Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells

TL;DR: Two organolead halide perovskite nanocrystals were found to efficiently sensitize TiO(2) for visible-light conversion in photoelectrochemical cells, which exhibit strong band-gap absorptions as semiconductors.
Journal ArticleDOI

VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data

TL;DR: VESTA has been upgraded to the latest version, VESTA 3, implementing new features including drawing the external mor­phology of crystals, and an extended bond-search algorithm to enable more sophisticated searches in complex molecules and cage-like structures.
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