Journal ArticleDOI
Mechanism and modeling of nitrogen chemistry in combustion
James A. Miller,Craig T. Bowman +1 more
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TLDR
In this article, the mechanisms and rate parameters for the gas-phase reactions of nitrogen compounds that are applicable to combustion-generated air pollution are discussed and illustrated by comparison of results from detailed kinetics calculations with experimental data.About:
This article is published in Progress in Energy and Combustion Science.The article was published on 1989-01-01. It has received 2843 citations till now. The article focuses on the topics: Combustion.read more
Citations
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Journal ArticleDOI
NOx and CO emissions from a pulse combustor operating in a lean premixed mode
TL;DR: In this paper, it was shown that controlling the flame temperature, chemical kinetics, and residence time at high temperature was best accomplished by controlling the equivalence ratio and the degree of macroscopic mixing rather than controlling the microscopic mixing over the dynamic range obtainable by the techniques used in this study.
Journal ArticleDOI
Absolute Rate Coefficients of the Reactions of C2H with NO and H2 between 295 and 440 K
TL;DR: In this article, the rate coefficients of the title reactions were measured at 295 < T < 440 K and at He pressures in the 2−20 Torr range by a laser photodissociation/chemiluminescence technique (LPD/CL).
Journal ArticleDOI
Rate coefficients for fuel + NO2: Predictive kinetics for HONO and HNO2 formation
TL;DR: In this article, high-accuracy electronic structure calculations and transition state theory are used to predict the rate coefficients for the H-abstraction reactions H2+−NO2 and CH4+
Journal ArticleDOI
Numerical Simulation and Scaling of NOx Emissions from Turbulent Hydrogen Jet Flames with Various Amounts of Helium Dilution
TL;DR: In this paper, five reduced reaction mechanisms and a detailed mechanism have been incorporated into Monte Carlo simulation of NO formation in turbulent hydrogen jet flames with various amounts of helium dilution, and compared with the predicted NO emission indexes with recent experimental data show significant improvement in the predictions by using better reduced chemistry especially for high helium dilutions cases.
Journal ArticleDOI
Modeling and simulation of SiC CVD in the horizontal hot-wall reactor concept
TL;DR: In this article, a combination of heat and mass transfer modeling, process simulation and experimental studies allows the identification and quantification of the growth and doping histories of silicon carbide epitaxial layers grown in a horizontal hot-wall chemical vapor deposition reactor.
References
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Journal ArticleDOI
Chemical Kinetic Data Base for Combustion Chemistry. Part I. Methane and Related Compounds
W. Tsang,R. F. Hampson +1 more
TL;DR: In this paper, the authors evaluated data on the kinetics and thermodynamic properties of species that are of importance in methanepyrolysis and combustion, including H, H2, O, O2, OH, HO2, CH2O, CH4, C2H6, HCHO, CO2, CO, HCO, CH3, CH5, CH6, CH7, CH8, CH9, CH10, CH11, CH12, CH13, CH14, CH15, CH16, CH17, CH
Book
The Mathematical Theory of Combustion and Explosions
TL;DR: In this paper, various topics in the area of combustion and explosives are discussed, including basic physical concepts of the science of combustion, the time-independent theory of thermal explosions, time-dependent statement of the problem of the initiation of chemical reaction waves in fuel mixtures, laminar flames, complex and chain reactions in flames, the gas dynamics of combustion dynamics, and diffusional combustion of gases.
ReportDOI
The Chemkin Thermodynamic Data Base
TL;DR: The Chemkin general-purpose chemical kinetics package uses a data base that contains polynomial fits to specific heats, standard state enthalpies, and standard state entropy as mentioned in this paper.
Book ChapterDOI
Rate Coefficients in the C/H/O System
TL;DR: In this article, a critical survey of reaction rate coefficient data important in describing high-temperature combustion of H2, CO, and small hydrocarbons up to C4 is presented.