Journal ArticleDOI
Mechanism and modeling of nitrogen chemistry in combustion
James A. Miller,Craig T. Bowman +1 more
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TLDR
In this article, the mechanisms and rate parameters for the gas-phase reactions of nitrogen compounds that are applicable to combustion-generated air pollution are discussed and illustrated by comparison of results from detailed kinetics calculations with experimental data.About:
This article is published in Progress in Energy and Combustion Science.The article was published on 1989-01-01. It has received 2843 citations till now. The article focuses on the topics: Combustion.read more
Citations
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Thermal decomposition of NCN(3) as a high-temperature NCN radical source: singlet-triplet relaxation and absorption cross section of NCN((3)Σ).
J. Dammeier,Gernot Friedrichs +1 more
TL;DR: Stable NCN concentration plateaus have been observed, showing that NCN3 is an ideal precursor for NCN kinetic experiments behind shock waves, and temperature-dependent collision-induced intersystem crossing (CIISC) rate constants are best represented.
Journal ArticleDOI
Temperature dependence of laser-induced fluorescence of nitric oxide in laminar premixed atmospheric-pressure flames.
TL;DR: The temperature dependence of laser-induced NO A (2?(+)-X (2)?
Journal ArticleDOI
Temperature and oxygen partial pressure dependencies of the coal-bound nitrogen to NOx conversion in O2/CO2 environments
TL;DR: In this paper, an experimental and numerical study aiming to assess the emissions of nitrogen oxides (NOx) from combustion of bituminous and lignite coals in O2/CO2 environments, simulating one-pass dry oxy-combustion conditions, and investigate the influences of temperature and oxygen partial pressure on such emissions.
Journal ArticleDOI
Nitrosyl isocyanate (ONNCO): gas-phase generation and a HeI photoelectron spectroscopy study.
TL;DR: The observed decomposition products indicate the formation of ONNCO and further confirm the previously reported decomposition pathway.
Journal ArticleDOI
Industrial combustion control using UV emission tomography
TL;DR: In this article, a new strategy for industrial combustion monitoring and control is presented which is based on UV emission spectroscopy measurements in combination with tomographic evaluation procedures, in contrast to usual closed-loop control for low pollutant combustion on the basis of flue gas composition measurements, this new strategy prevents the production of combustion NO x by an early detection of NO x generating flame radicals in a two-dimensional plane of the combustion system.
References
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Journal ArticleDOI
Chemical Kinetic Data Base for Combustion Chemistry. Part I. Methane and Related Compounds
W. Tsang,R. F. Hampson +1 more
TL;DR: In this paper, the authors evaluated data on the kinetics and thermodynamic properties of species that are of importance in methanepyrolysis and combustion, including H, H2, O, O2, OH, HO2, CH2O, CH4, C2H6, HCHO, CO2, CO, HCO, CH3, CH5, CH6, CH7, CH8, CH9, CH10, CH11, CH12, CH13, CH14, CH15, CH16, CH17, CH
Book
The Mathematical Theory of Combustion and Explosions
TL;DR: In this paper, various topics in the area of combustion and explosives are discussed, including basic physical concepts of the science of combustion, the time-independent theory of thermal explosions, time-dependent statement of the problem of the initiation of chemical reaction waves in fuel mixtures, laminar flames, complex and chain reactions in flames, the gas dynamics of combustion dynamics, and diffusional combustion of gases.
ReportDOI
The Chemkin Thermodynamic Data Base
TL;DR: The Chemkin general-purpose chemical kinetics package uses a data base that contains polynomial fits to specific heats, standard state enthalpies, and standard state entropy as mentioned in this paper.
Book ChapterDOI
Rate Coefficients in the C/H/O System
TL;DR: In this article, a critical survey of reaction rate coefficient data important in describing high-temperature combustion of H2, CO, and small hydrocarbons up to C4 is presented.