Journal ArticleDOI
Mechanism and modeling of nitrogen chemistry in combustion
James A. Miller,Craig T. Bowman +1 more
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TLDR
In this article, the mechanisms and rate parameters for the gas-phase reactions of nitrogen compounds that are applicable to combustion-generated air pollution are discussed and illustrated by comparison of results from detailed kinetics calculations with experimental data.About:
This article is published in Progress in Energy and Combustion Science.The article was published on 1989-01-01. It has received 2843 citations till now. The article focuses on the topics: Combustion.read more
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Journal ArticleDOI
Stability limits and NO emissions of premixed swirl ammonia-air flames enriched with hydrogen or methane at elevated pressures
Abdulrahman A. Khateeb,Thibault F. Guiberti,Guoqing Wang,Wesley R. Boyette,Mourad Younes,Aqil Jamal,William L. Roberts +6 more
TL;DR: In this paper, the authors report measurements of stability limits and exhaust NO mole fractions of theoretically-premixed swirl ammonia-air flames enriched with either methane or hydrogen, at different pressures from atmospheric to 5 bar, representative of commercial micro gas turbines.
Journal ArticleDOI
Ab Initio Quantum Chemical and Kinetic Modeling Study of the Pyrolysis Kinetics of Pyrrole
TL;DR: Mackie et al. as discussed by the authors investigated the kinetics of pyrolysis of pyrrole by ab initio quantum chemical techniques and by detailed chemical kinetic modeling of previously reported experimental results, and the overall kinetics can be successfully modeled by a 117 step kinetic model that gives good agreement with temperature profiles of major products and also provides an acceptable fit for minor products.
Journal ArticleDOI
Ethane ignition and oxidation behind reflected shock waves
Jaap de Vries,Joel M. Hall,Stefanie L. Simmons,Matthew J. A. Rickard,Danielle M. Kalitan,Eric L. Petersen +5 more
TL;DR: In this article, several diluted C{sub 2}H{sub 6}/O{ sub 2}/Ar mixtures of varying concentrations and equivalence ratios (0.5<{phi}<2.0) were studied at temperatures between 1218 and 1860 K and at pressures between 0.57 and 3.0 atm using a shock tube.
Journal ArticleDOI
Formation of HNCO from the rapid pyrolysis of coals
TL;DR: In this paper, the authors reported the first observation of the formation of isocyanic acid, HNCO, from the pyrolysis of coals and discuss the possible implications of this observation for the release and subsequent fate of volatile N species during coal pyrotelysis and combustion.
Journal ArticleDOI
An experimental investigation of NO2 emission characteristics of a heavy-duty H2-diesel dual fuel engine
TL;DR: In this paper, the authors investigated the nitrogen dioxide (NO 2 ) emissions of a heavy-duty diesel engine operated in hydrogen (H 2 )-diesel dual fuel combustion mode with H 2 supplemented into the intake air.
References
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Journal ArticleDOI
Chemical Kinetic Data Base for Combustion Chemistry. Part I. Methane and Related Compounds
W. Tsang,R. F. Hampson +1 more
TL;DR: In this paper, the authors evaluated data on the kinetics and thermodynamic properties of species that are of importance in methanepyrolysis and combustion, including H, H2, O, O2, OH, HO2, CH2O, CH4, C2H6, HCHO, CO2, CO, HCO, CH3, CH5, CH6, CH7, CH8, CH9, CH10, CH11, CH12, CH13, CH14, CH15, CH16, CH17, CH
Book
The Mathematical Theory of Combustion and Explosions
TL;DR: In this paper, various topics in the area of combustion and explosives are discussed, including basic physical concepts of the science of combustion, the time-independent theory of thermal explosions, time-dependent statement of the problem of the initiation of chemical reaction waves in fuel mixtures, laminar flames, complex and chain reactions in flames, the gas dynamics of combustion dynamics, and diffusional combustion of gases.
ReportDOI
The Chemkin Thermodynamic Data Base
TL;DR: The Chemkin general-purpose chemical kinetics package uses a data base that contains polynomial fits to specific heats, standard state enthalpies, and standard state entropy as mentioned in this paper.
Book ChapterDOI
Rate Coefficients in the C/H/O System
TL;DR: In this article, a critical survey of reaction rate coefficient data important in describing high-temperature combustion of H2, CO, and small hydrocarbons up to C4 is presented.