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Journal ArticleDOI

Mechanism and modeling of nitrogen chemistry in combustion

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TLDR
In this article, the mechanisms and rate parameters for the gas-phase reactions of nitrogen compounds that are applicable to combustion-generated air pollution are discussed and illustrated by comparison of results from detailed kinetics calculations with experimental data.
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This article is published in Progress in Energy and Combustion Science.The article was published on 1989-01-01. It has received 2843 citations till now. The article focuses on the topics: Combustion.

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Journal ArticleDOI

Properties of Laminar Premixed CO/H/Air Flames at Various Pressures

TL;DR: In this paper, the effects of positive ame stretch on the laminar burning velocities of CO/H2/air mixtures were studied both experimentally and computationally for outwardly propagating spherical ames having concentrations of hydrogen in the fuel mixture of 3 − 50% by volume, fuel-equivalence ratios of 0.6 − 5.0, and pressures at 0.5 − 4.0 atm.
Journal ArticleDOI

On the Performance and Operability of GE’s Dry Low NOx Combustors utilizing Exhaust Gas Recirculation for PostCombustion Carbon Capture

TL;DR: In this paper, an experimental work performed at General Electric Global Research Center in order to better understand the risks of utilizing exhaust gas recirculation in combination with dry low NOx (DLN) combustors is presented.
Journal ArticleDOI

The role of unsteadiness in direct initiation of gaseous detonations

TL;DR: In this paper, an analytical model for the direct initiation of gaseous detonations by a blast wave is presented for stable or weakly unstable mixtures, and local analysis of the one-dimensional unsteady reaction zone structure identifies a competition between heat release, wave front curvature and unsteadiness.
Journal ArticleDOI

Understanding NOx formation in nonpremixed flames: Experiments and modeling

TL;DR: Experimental studies and models of NOx formation in simple non-premixed flames at atmospheric pressure are reviewed in this paper, where the failure of a simple leading-order scaling is investigated and interpreted in terms of the various interrelated parameters affecting NO formation: the relative importance of various NO-forming chemical pathways, departures of O-atom concentrations and temperatures from their equilibrium values, flame strain, and flame radiation.
Journal ArticleDOI

Detailed Kinetic Modelling of Chemistry and Temperature Effects on Ammonia Oxidation

TL;DR: In this paper, an extensive set offlat laminar premixed NH3/H2/O2,NH3,/NO/H 2/O 2 and NH3O2 flames have been investigated by detailed chemical kinetic modelling to facilitate the construction of a reaction mechanism capable of satisfactory predictions for a wide range of flames.
References
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Journal ArticleDOI

Chemical Kinetic Data Base for Combustion Chemistry. Part I. Methane and Related Compounds

TL;DR: In this paper, the authors evaluated data on the kinetics and thermodynamic properties of species that are of importance in methanepyrolysis and combustion, including H, H2, O, O2, OH, HO2, CH2O, CH4, C2H6, HCHO, CO2, CO, HCO, CH3, CH5, CH6, CH7, CH8, CH9, CH10, CH11, CH12, CH13, CH14, CH15, CH16, CH17, CH
Book

The Mathematical Theory of Combustion and Explosions

TL;DR: In this paper, various topics in the area of combustion and explosives are discussed, including basic physical concepts of the science of combustion, the time-independent theory of thermal explosions, time-dependent statement of the problem of the initiation of chemical reaction waves in fuel mixtures, laminar flames, complex and chain reactions in flames, the gas dynamics of combustion dynamics, and diffusional combustion of gases.
ReportDOI

The Chemkin Thermodynamic Data Base

TL;DR: The Chemkin general-purpose chemical kinetics package uses a data base that contains polynomial fits to specific heats, standard state enthalpies, and standard state entropy as mentioned in this paper.
Book ChapterDOI

Rate Coefficients in the C/H/O System

J. Warnatz
TL;DR: In this article, a critical survey of reaction rate coefficient data important in describing high-temperature combustion of H2, CO, and small hydrocarbons up to C4 is presented.
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