Journal ArticleDOI
Mechanism and modeling of nitrogen chemistry in combustion
James A. Miller,Craig T. Bowman +1 more
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TLDR
In this article, the mechanisms and rate parameters for the gas-phase reactions of nitrogen compounds that are applicable to combustion-generated air pollution are discussed and illustrated by comparison of results from detailed kinetics calculations with experimental data.About:
This article is published in Progress in Energy and Combustion Science.The article was published on 1989-01-01. It has received 2843 citations till now. The article focuses on the topics: Combustion.read more
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Optimization and analysis of large chemical kinetic mechanisms using the solution mapping method—combustion of methane
TL;DR: In this article, a solution mapping technique is applied to a large-scale dynamic model to determine an optimum set of parameters for a methane combustion mechanism, which is then used in a joint multiparameter multi-data-set optimization.
Journal ArticleDOI
Master equation methods in gas phase chemical kinetics.
TL;DR: The application of master equation methods to problems in gas phase chemical kinetics, focusing on reactions that take place over multiple, interconnected potential wells and on the dissociation of weakly bound free radicals, is discussed.
Journal ArticleDOI
Chemical Effects of a High CO2 Concentration in Oxy-Fuel Combustion of Methane
TL;DR: In this article, a detailed chemical kinetic mechanism for hydrocarbon oxidation in an atmospheric-pressure flow reactor has been studied experimentally under highly diluted conditions in N2 and CO2, respectively.
Laser Techniques for the Quantitative Detection of Reactive Intermediates
TL;DR: An overview of recent developments in laser diagnostic methods for the quantitative measurement of trace species concentrations and, in conjunction, of temperature in combustion systems is given in this article, where typical applications and discusses advantages and limitations of laser techniques including laser absorption, linear, saturated, predissociative and multi-photon-excited laser-induced fluorescence (LIF), resonanceenhanced multiphoton ionization (REMPI), electronically resonant coherent anti-Stokes Raman scattering (resonance CARS), degenerate four-wave mixing (DFWM) and amplified spontaneous
References
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Journal ArticleDOI
Chemical Kinetic Data Base for Combustion Chemistry. Part I. Methane and Related Compounds
W. Tsang,R. F. Hampson +1 more
TL;DR: In this paper, the authors evaluated data on the kinetics and thermodynamic properties of species that are of importance in methanepyrolysis and combustion, including H, H2, O, O2, OH, HO2, CH2O, CH4, C2H6, HCHO, CO2, CO, HCO, CH3, CH5, CH6, CH7, CH8, CH9, CH10, CH11, CH12, CH13, CH14, CH15, CH16, CH17, CH
Book
The Mathematical Theory of Combustion and Explosions
TL;DR: In this paper, various topics in the area of combustion and explosives are discussed, including basic physical concepts of the science of combustion, the time-independent theory of thermal explosions, time-dependent statement of the problem of the initiation of chemical reaction waves in fuel mixtures, laminar flames, complex and chain reactions in flames, the gas dynamics of combustion dynamics, and diffusional combustion of gases.
ReportDOI
The Chemkin Thermodynamic Data Base
TL;DR: The Chemkin general-purpose chemical kinetics package uses a data base that contains polynomial fits to specific heats, standard state enthalpies, and standard state entropy as mentioned in this paper.
Book ChapterDOI
Rate Coefficients in the C/H/O System
TL;DR: In this article, a critical survey of reaction rate coefficient data important in describing high-temperature combustion of H2, CO, and small hydrocarbons up to C4 is presented.