Journal ArticleDOI
Mechanism and modeling of nitrogen chemistry in combustion
James A. Miller,Craig T. Bowman +1 more
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TLDR
In this article, the mechanisms and rate parameters for the gas-phase reactions of nitrogen compounds that are applicable to combustion-generated air pollution are discussed and illustrated by comparison of results from detailed kinetics calculations with experimental data.About:
This article is published in Progress in Energy and Combustion Science.The article was published on 1989-01-01. It has received 2843 citations till now. The article focuses on the topics: Combustion.read more
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Journal ArticleDOI
Chemical Kinetics of Methane Pyrolysis in Microwave Plasma at Atmospheric Pressure
TL;DR: In this paper, the results of chemical kinetics modeling in methane subjected to the microwave plasma at atmospheric pressure are presented and the reaction mechanism is based on the methane oxidation model without reactions involving nitrogen and oxygen.
Journal ArticleDOI
NOx emission from high-temperature air/methane counterflow diffusion flame
TL;DR: In this paper, the authors measured NO x emission of counterflow diffusion flame, compared the findings with numerical results, and demonstrated efficacious effect of high-temperature air with low concentration of oxygen on NO x emissions.
Journal ArticleDOI
Absolute CH radical concentrations in rich low-pressure methane-oxygen-argon flames via cavity ringdown spectroscopy of the A transition
John W. Thoman,Andrew McIlroy +1 more
TL;DR: In this article, the authors measured absolute methylidyne (CH) radical concentrations in a series of rich 31.0 Torr (4.13 kPa) methane-oxygen-argon flames using cavity ringdown spectroscopy.
Journal ArticleDOI
Reaction of methylidyne radical with CH4 and H2S: overall rate constant and absolute atomic hydrogen production
TL;DR: In this article, the CH+CH4 and H2S reactions were studied, at room temperature, in a low-pressure fast-flow reactor, and the overall rate constants were found at 330 K to be (0.76±0.20)×10−10 and (2.8± 0.8)× 10 −10 cm 3 molecule −1 s −1, respectively.
Journal ArticleDOI
New double many-body expansion potential energy surface for ground-state HCN from a multiproperty fit to accurate ab initio energies and rovibrational calculations.
TL;DR: An accurate single-sheeted double many-body expansion potential energy surface has been obtained for the ground electronic state of the hydrogen cyanide molecule via a multiproperty fit to ab initio energies and rovibrational data.
References
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Journal ArticleDOI
Chemical Kinetic Data Base for Combustion Chemistry. Part I. Methane and Related Compounds
W. Tsang,R. F. Hampson +1 more
TL;DR: In this paper, the authors evaluated data on the kinetics and thermodynamic properties of species that are of importance in methanepyrolysis and combustion, including H, H2, O, O2, OH, HO2, CH2O, CH4, C2H6, HCHO, CO2, CO, HCO, CH3, CH5, CH6, CH7, CH8, CH9, CH10, CH11, CH12, CH13, CH14, CH15, CH16, CH17, CH
Book
The Mathematical Theory of Combustion and Explosions
TL;DR: In this paper, various topics in the area of combustion and explosives are discussed, including basic physical concepts of the science of combustion, the time-independent theory of thermal explosions, time-dependent statement of the problem of the initiation of chemical reaction waves in fuel mixtures, laminar flames, complex and chain reactions in flames, the gas dynamics of combustion dynamics, and diffusional combustion of gases.
ReportDOI
The Chemkin Thermodynamic Data Base
TL;DR: The Chemkin general-purpose chemical kinetics package uses a data base that contains polynomial fits to specific heats, standard state enthalpies, and standard state entropy as mentioned in this paper.
Book ChapterDOI
Rate Coefficients in the C/H/O System
TL;DR: In this article, a critical survey of reaction rate coefficient data important in describing high-temperature combustion of H2, CO, and small hydrocarbons up to C4 is presented.