Journal ArticleDOI
Mechanism and modeling of nitrogen chemistry in combustion
James A. Miller,Craig T. Bowman +1 more
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TLDR
In this article, the mechanisms and rate parameters for the gas-phase reactions of nitrogen compounds that are applicable to combustion-generated air pollution are discussed and illustrated by comparison of results from detailed kinetics calculations with experimental data.About:
This article is published in Progress in Energy and Combustion Science.The article was published on 1989-01-01. It has received 2843 citations till now. The article focuses on the topics: Combustion.read more
Citations
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Journal ArticleDOI
Decomposition of nitrous oxide at medium temperatures
TL;DR: In this paper, the authors studied the thermal decomposition of N{sub 2}O at atmospheric pressure and in a temperature range of 600-1,000 C. The experimental results were discussed using a detailed chemistry model.
Journal ArticleDOI
Formation of NO from N2/O2 Mixtures in a Flow Reactor: Toward an Accurate Prediction of Thermal NO
TL;DR: In this paper, a detailed chemical model was used to determine the rate constant for the reaction N2 + O ⇌ NO + N (R1), with an error limit of ± 30%.
Journal ArticleDOI
Application of ultra-low NOx emission control for CFB boilers based on theoretical analysis and industrial practices
TL;DR: In this article, a low NOx emission (de-NOx) technology applied to CFB boilers was proposed to reduce the NOx emissions by decreasing the average size of bed materials, limestone included, and increasing the solid circulating rate.
Journal ArticleDOI
Laser-based flame species profile measurements: A comparison with flame model predictions
Jeffrey S. Bernstein,Asa Fein,Jung B. Choi,Terrill A. Cool,Rosario C. Sausa,Stephen L. Howard,Randy J. Locke,Andrzej W. Miziolek +7 more
TL;DR: In this article, two laser-based diagnostic methods, resonanceenhanced multiphoton ionization (REMPI) and laser-induced fluorescence (LIF), were used for relative concentration measurements of seven species, O, H, OH, CH, CO, HCO, and CH 3, in low pressure stoichiometric methane oxygen, ethylene oxygen, and ethane oxygen premixed hydrocarbon flames.
Journal ArticleDOI
Carbon dioxide diluted methane/oxygen combustion in a rapidly mixed tubular flame burner
Baolu Shi,Jie Hu,Satoru Ishizuka +2 more
TL;DR: In this article, the Damkohler number was examined to discuss the criterion for the establishment of stable tubular flame, and it was found that stable flame can be obtained for D a D a ǫ ≥ 1 due to formation of diffusion flames near the fuel slits.
References
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Journal ArticleDOI
Chemical Kinetic Data Base for Combustion Chemistry. Part I. Methane and Related Compounds
W. Tsang,R. F. Hampson +1 more
TL;DR: In this paper, the authors evaluated data on the kinetics and thermodynamic properties of species that are of importance in methanepyrolysis and combustion, including H, H2, O, O2, OH, HO2, CH2O, CH4, C2H6, HCHO, CO2, CO, HCO, CH3, CH5, CH6, CH7, CH8, CH9, CH10, CH11, CH12, CH13, CH14, CH15, CH16, CH17, CH
Book
The Mathematical Theory of Combustion and Explosions
TL;DR: In this paper, various topics in the area of combustion and explosives are discussed, including basic physical concepts of the science of combustion, the time-independent theory of thermal explosions, time-dependent statement of the problem of the initiation of chemical reaction waves in fuel mixtures, laminar flames, complex and chain reactions in flames, the gas dynamics of combustion dynamics, and diffusional combustion of gases.
ReportDOI
The Chemkin Thermodynamic Data Base
TL;DR: The Chemkin general-purpose chemical kinetics package uses a data base that contains polynomial fits to specific heats, standard state enthalpies, and standard state entropy as mentioned in this paper.
Book ChapterDOI
Rate Coefficients in the C/H/O System
TL;DR: In this article, a critical survey of reaction rate coefficient data important in describing high-temperature combustion of H2, CO, and small hydrocarbons up to C4 is presented.