Journal ArticleDOI
Mechanism and modeling of nitrogen chemistry in combustion
James A. Miller,Craig T. Bowman +1 more
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In this article, the mechanisms and rate parameters for the gas-phase reactions of nitrogen compounds that are applicable to combustion-generated air pollution are discussed and illustrated by comparison of results from detailed kinetics calculations with experimental data.About:
This article is published in Progress in Energy and Combustion Science.The article was published on 1989-01-01. It has received 2843 citations till now. The article focuses on the topics: Combustion.read more
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Temperature Dependence of Rate Coefficients and Branching Ratios for the NH2 + NO Reaction via Microcanonical Variational Transition State Theory
Eric W.-G. Diau,Sean C. Smith +1 more
TL;DR: In this paper, the temperature dependence of the rate coefficient and product branching ratios in the NH + NO reaction have been performed using microcanonical varitational transition state theory (μVTST) in conjunction with Rice-Ramsperger-Kassel-Marcus (RRKM) theory.
Journal ArticleDOI
Catalytic activity and selectivities of metal oxides and Pt/Al2O3 for NH3 combustion
Satoshi Hinokuma,Hiroki Shimanoe,Shun Matsuki,Michihisa Kawano,Yusuke Kawabata,Masato Machida +5 more
TL;DR: In this paper, catalytic activity and selectivities of metal oxides and Pt/Al2O3 were evaluated for the combustion of NH3, which is considered a carbon-free energy source.
Journal ArticleDOI
The Oxidation of HCN and Reactions with Nitric Oxide: Experimental and Detailed Kinetic Modeling
TL;DR: A detailed chemical kinetic model for NO-reburning (751 reactions and 102 species) was used to simulate the present experiments and an overall good agreement between the experimental results and the modeling was obtained.
Journal ArticleDOI
Performance, emission and combustion characteristics of a branched higher mass, C3 alcohol (isopropanol) blends fuelled medium duty MPFI SI engine
Harish Sivasubramanian,Yashwanth Kutti Pochareddy,Gopinath Dhamodaran,Ganapathy Sundaram Esakkimuthu +3 more
TL;DR: In this article, the use of isopropanol/gasoline blends as fuel in a 4-cylinder Spark Ignition engine with Multi-Point Fuel Injection System was investigated.
Journal ArticleDOI
Measurements of hydrogen cyanide and its chemical production rate in a laminar methane/air, non-premixed flame using cw cavity ringdown spectroscopy
TL;DR: In this article, a cavity ringdown spectroscopy using an external cavity tunable diode laser is coupled with microprobe sampling to quantitatively determine hydrogen cyanide concentrations in a methane/air non-premixed flame.
References
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Journal ArticleDOI
Chemical Kinetic Data Base for Combustion Chemistry. Part I. Methane and Related Compounds
W. Tsang,R. F. Hampson +1 more
TL;DR: In this paper, the authors evaluated data on the kinetics and thermodynamic properties of species that are of importance in methanepyrolysis and combustion, including H, H2, O, O2, OH, HO2, CH2O, CH4, C2H6, HCHO, CO2, CO, HCO, CH3, CH5, CH6, CH7, CH8, CH9, CH10, CH11, CH12, CH13, CH14, CH15, CH16, CH17, CH
Book
The Mathematical Theory of Combustion and Explosions
TL;DR: In this paper, various topics in the area of combustion and explosives are discussed, including basic physical concepts of the science of combustion, the time-independent theory of thermal explosions, time-dependent statement of the problem of the initiation of chemical reaction waves in fuel mixtures, laminar flames, complex and chain reactions in flames, the gas dynamics of combustion dynamics, and diffusional combustion of gases.
ReportDOI
The Chemkin Thermodynamic Data Base
TL;DR: The Chemkin general-purpose chemical kinetics package uses a data base that contains polynomial fits to specific heats, standard state enthalpies, and standard state entropy as mentioned in this paper.
Book ChapterDOI
Rate Coefficients in the C/H/O System
TL;DR: In this article, a critical survey of reaction rate coefficient data important in describing high-temperature combustion of H2, CO, and small hydrocarbons up to C4 is presented.