Journal ArticleDOI
Mechanism and modeling of nitrogen chemistry in combustion
James A. Miller,Craig T. Bowman +1 more
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TLDR
In this article, the mechanisms and rate parameters for the gas-phase reactions of nitrogen compounds that are applicable to combustion-generated air pollution are discussed and illustrated by comparison of results from detailed kinetics calculations with experimental data.About:
This article is published in Progress in Energy and Combustion Science.The article was published on 1989-01-01. It has received 2843 citations till now. The article focuses on the topics: Combustion.read more
Citations
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Journal ArticleDOI
Pollutant emissions reduction and performance optimization of an industrial radiant tube burner
TL;DR: In this article, the results of an experimental investigation performed upon a single-ended self-recuperative radiant tube burner fuelled by natural gas in the non-premixed mode, which is used in the steel industry for surface treatment, were presented.
Journal ArticleDOI
Hydrogen Abstraction from Hydrocarbons by NH2
Kamal Siddique,Mohammednoor Altarawneh,Jeff Gore,Phillip R. Westmoreland,Bogdan Z. Dlugogorski +4 more
TL;DR: The thermokinetic parameters of bimolecular gas-phase reactions involving the amine (NH2) radical and a large number of saturated and unsaturated hydrocarbons are investigated and six sets of the generalized Arrhenius rate parameters for H abstractions from different C-H bond types are developed.
Journal ArticleDOI
Experimental characterization of the influence of CO on the high-temperature reduction of NO by NH3
Johannes Suhlmann,Gerd Rotzoll +1 more
TL;DR: In this paper, the dependence of fractional conversions of NO, NH3 and CO was measured as a function of residence time, temperature, initial NH 3 NO molar ratio and concentrations of CO and O2.
Journal ArticleDOI
Effects of diesel engine speed and water content on emission characteristics of three-phase emulsions.
Cherng-Yuan Lin,Kuo-Hua Wang +1 more
TL;DR: It is suggested that the emulsions with water content larger than 20% are not suitable for use as alternative fuel for diesel engines because they may cause diesel engines to shut down earlier than those running on O/W/O emulsion with the same water content.
Journal ArticleDOI
Evaluation of chemical effects of added CO2 according flame location
TL;DR: In this paper, a numerical study has been conducted to clearly grasp the impact of chemical effects caused by added CO 2 and of flame location on flame structure and NO emission behavior, and it is shown that the reduction of maximum flame temperature due to chemical effects for fuel-side dilution is mainly caused by the competition of the principal chain branching reaction with the reaction, CH 4 + H → CH 3 + H 2.
References
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Journal ArticleDOI
Chemical Kinetic Data Base for Combustion Chemistry. Part I. Methane and Related Compounds
W. Tsang,R. F. Hampson +1 more
TL;DR: In this paper, the authors evaluated data on the kinetics and thermodynamic properties of species that are of importance in methanepyrolysis and combustion, including H, H2, O, O2, OH, HO2, CH2O, CH4, C2H6, HCHO, CO2, CO, HCO, CH3, CH5, CH6, CH7, CH8, CH9, CH10, CH11, CH12, CH13, CH14, CH15, CH16, CH17, CH
Book
The Mathematical Theory of Combustion and Explosions
TL;DR: In this paper, various topics in the area of combustion and explosives are discussed, including basic physical concepts of the science of combustion, the time-independent theory of thermal explosions, time-dependent statement of the problem of the initiation of chemical reaction waves in fuel mixtures, laminar flames, complex and chain reactions in flames, the gas dynamics of combustion dynamics, and diffusional combustion of gases.
ReportDOI
The Chemkin Thermodynamic Data Base
TL;DR: The Chemkin general-purpose chemical kinetics package uses a data base that contains polynomial fits to specific heats, standard state enthalpies, and standard state entropy as mentioned in this paper.
Book ChapterDOI
Rate Coefficients in the C/H/O System
TL;DR: In this article, a critical survey of reaction rate coefficient data important in describing high-temperature combustion of H2, CO, and small hydrocarbons up to C4 is presented.