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MXene Electrochemical Microsupercapacitor Integrated with Triboelectric Nanogenerator as a Wearable Self-charging Power Unit

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TLDR
In this paper, a highly compact self-charging power unit is proposed by integrating triboelectric nanogenerator with MXene-based microsupercapacitors in a wearable and flexible harvester-storage module.
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This article is published in Nano Energy.The article was published on 2018-03-01 and is currently open access. It has received 298 citations till now. The article focuses on the topics: Power module & Energy storage.

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Triboelectric Nanogenerator: A Foundation of the Energy for the New Era

TL;DR: In this paper, the fundamental theory, experiments, and applications of TENGs are reviewed as a foundation of the energy for the new era with four major application fields: micro/nano power sources, self-powered sensors, large-scale blue energy, and direct high-voltage power sources.
Journal ArticleDOI

Control of MXenes' electronic properties through termination and intercalation.

TL;DR: Two-dimensional transition metal carbides and nitrides (MXenes) have emerged as highly conductive and stable materials, of promise for electronic applications, and in situ electric biasing and transmission electron microscopy are used to investigate the effect of surface termination and intercalation on electronic properties.
Journal ArticleDOI

Review of MXenes as new nanomaterials for energy storage/delivery and selected environmental applications

TL;DR: A comprehensive review of recent studies on energy and environmental applications of MXene and MXene-based nanomaterials, including energy conversion and storage, adsorption, membrane, photocatalysis, and antimicrobial, can be found in this paper.
Journal ArticleDOI

Two-dimensional materials for miniaturized energy storage devices: from individual devices to smart integrated systems

TL;DR: This study reviews the recent advancements in microbatteries and microsupercapacitors based on electrochemically active 2D materials and smart functions and integrated systems are discussed in detail in light of the emergence of intelligent and interactive modes.
References
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Journal ArticleDOI

Laser Scribing of High-Performance and Flexible Graphene-Based Electrochemical Capacitors

TL;DR: It is shown that graphite oxide sheets can be converted by infrared laser irradiation into porous graphene sheets that are flexible, robust, and highly conductive, and hold promise for high-power, flexible electronics.
Journal ArticleDOI

Guidelines for Synthesis and Processing of Two-Dimensional Titanium Carbide (Ti3C2Tx MXene)

TL;DR: Two-dimensional transition metal carbides, carbonitrides, and nitrides (MXenes) were discovered in 2011 and more than 20 different compositions have been synthesized by the selective etching of MAX phase and other precursors and many more theoretically predicted as mentioned in this paper.
Journal ArticleDOI

Ultrahigh-power micrometre-sized supercapacitors based on onion-like carbon

TL;DR: This work demonstrates microsupercapacitors with powers per volume that are comparable to electrolytic capacitors, capacitances that are four orders of magnitude higher, and energies per volume higher than conventional supercapacitor.
Journal ArticleDOI

Laser-induced porous graphene films from commercial polymers

TL;DR: A one-step, scalable approach for producing and patterning porous graphene films with 3-dimensional networks from commercial polymer films using a CO2 infrared laser to provide a rapid route to polymer-written electronic and energy storage devices.
Related Papers (5)
Frequently Asked Questions (20)
Q1. What contributions have the authors mentioned in the paper "Mxene electrochemical microsupercapacitor integrated with triboelectric nanogenerator as a wearable self-charging power unit" ?

In this paper, the authors proposed a simple technique to fabricate a TENG device with a rubber-based self-charging power unit for wearable sensors. 

Their strategy shows that MXene microsupercapacitors are versatile and can be integrated with energy harvesting devices, which opens new possibilities in wearable/implantable sensor networks. 

The chemically cross-linked hydrogel shows excellent elasticity and high ionic conductivity due to alarger water content absorbed in the polymer matrix that helps in fine-tuning ionic conductivity. 

Thin-film or micro-batteries can be used as small-scale energy storage units, but they often suffer from low power density and limited cycle life. 

In addition, their device can have a long lifetime for continuous energy harvesting and storage, which can be useful for powering electronics without additional power sources. 

Carbon based materials such as activated carbon [10], onion like carbon [11], carbonnanotubes (CNTs) [12] and carbide-derived carbon [13] have been explored as electrodes for MSCs. 

Given its 2D layered morphology, MXene is also convenient for flexible energy storage with good mechanical property and straintunability, which gives it more versatility to be integrated with other components. 

Under the short-circuit condition, the maximum charge transferred per cycle reached about 4.2 nC/cm 2 , and the peak current was about 0.13 µA/cm 2 at the working frequency of 1.3 Hz. 

The chemically cross-linked polyvinyl alcohol PVA/H3PO4 hydrogel not only serves as the solid-state electrolyte, but also guarantees the structural integrity and mechanical strength of the assembled device [31]. 

A single-electrode-mode TENG based on carbon-fiber-embedded silicone was designedfor integration with the silicone-encapsulated MXene-based MSC. 

under 10 Hz, the MSC can be charged to 0.11 V within 200 seconds, which demonstrates the fast response even at high frequencies. 

Since the device was fabricated on flexible substrates, it can be repeatedly bent at various angles and frequencies (Fig. 1(h)) without compromising performance. 

MXene-based MSCs fabricated by employing a Meyer coating and spray-coating methods followed by a direct laser cutting process were reported [28,29]. 

As a result, their microsupercapacitor delivers a capacitance of 23 mF/cm 2 with 95% capacitance retention after 10,000 charge-discharge cycles, while the triboelectric nanogenerator exhibits a maximum output power of 7.8 µW/cm 2. 

Fig. 4(c) illustrates the self-charging capability of the power band (Total capacitance ofthe series connected capacitor is 4 mF) under hand clapping (the clapping frequency is estimated to be 5 Hz) when no external load was connected. 

The output power of the TENG connected withvarious external load resistance was measured and plotted, with the maximum output power of 7.8 µW/cm 2 at a load resistance of 400 MΩ. 

The authors investigated the self-discharge behavior of their device via measuring the open circuit potential of the device after thoroughly charging it, and a slow self-discharge rate of 0.1 V/h is observed for the device, which is shown in Fig. 1(g). 

As shown in Fig. S1(a), The Raman spectrum ofTi3C2Tx exhibits strong peaks at 200 and 722 cm -1 , which can be assigned to the A1g modes of Ti3C2O2; the additional peaks at 286, and 630 cm -1 can be assigned to the following vibrational modes: Eg of Ti3C2(OH)2, and Eg of Ti3C2F2, respectively. [30] 

This solid-state MSC exhibits good cycling stability with a capacitance retention up to 76% and coulombic efficiency of 95% over 10k cycles as shown in Fig 1(f). 

One the other hand, the liquid electrolyte in conventional supercapacitors will evaporate if exposed to air, thus proper encapsulation of the supercapacitor is required, which makes the TENG-supercapacitor device bulky.