Journal ArticleDOI
Supercritical Fluids in Heterogeneous Catalysis
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This article is published in Chemical Reviews.The article was published on 1999-02-10. It has received 689 citations till now. The article focuses on the topics: Supercritical fluid & Heterogeneous catalysis.read more
Citations
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Journal ArticleDOI
Neue Prozessoptionen für die Nutzung von Zeolithen in überkritischen Fluiden und ionischen Flüssigkeiten
TL;DR: In this paper, Beispiele f Anwendungen von Zeolithen in uberkritischen Fluiden and ionischen Flussigkeiten aus der aktuellen Literatur besprochen.
Book ChapterDOI
Phase Equilibrium and Process Development
Esteban A. Brignole,Selva Pereda +1 more
TL;DR: In this article, the philosophy of phase equilibrium thermodynamic modeling is discussed in the context of process development and chemical plant operation, and typical phase scenarios that are encountered in separation, materials and chemical process are presented as well as the problem of phase design and the PEE tools.
Book ChapterDOI
Phase Equilibrium Engineering in Conceptual Process Design
Esteban A. Brignole,Selva Pereda +1 more
TL;DR: The application of phase equilibrium engineering to the development of two innovative technologies for the production of bio-fuels is discussed in this article, where the authors use a group contribution approach (GC-EOS) to extrapolate the scarce experimental information available not only in pressure, temperature, and composition but also in molecular structure.
In situ raman spectroscopy of solid catalyzed reactions in supercritical co2 within a si/glass microreactor
TL;DR: In this article, the in situ monitoring of a solid catalyzed reaction by Raman spectroscopy in a packed bed Si/glass microreactor up to pressures of 10 MPa is reported.
Journal ArticleDOI
PdCl 2 -catalyzed heterocyclotrimerization in MeOH/scCO 2 : A versatile approach to dimethyl pyridine-3,5-dicarboxylate from methyl acrylate and urea
Bo Zou,HuanFeng Jiang +1 more
TL;DR: In this article, a green method for the synthesis of dimethyl pyridine-3,5-dicarboxylate has been developed, which is PdCl2-catalyzed heterocyclotrimerization of methyl acrylate with urea in methanol/supercritical carbon dioxide.
References
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Journal ArticleDOI
Aerogels-Airy Materials: Chemistry, Structure, and Properties.
Nicola Hüsing,Ulrich S. Schubert +1 more
TL;DR: The design of such a filigrane network requires the very careful control of chemical parameters and the reward is an assortment of different property profiles owing to the richness of possible variations.
Journal ArticleDOI
Structures of metal sites of oxidized bovine heart cytochrome c oxidase at 2.8 A
Tomitake Tsukihara,Hiroshi Aoyama,Eiki Yamashita,Takashi Tomizaki,Hiroshi Yamaguchi,Kyoko Shinzawa-Itoh,Ryosuke Nakashima,Rieko Yaono,Shinya Yoshikawa +8 more
TL;DR: The high resolution three-dimensional x-ray structure of the metal sites of bovine heart cytochrome c oxidase is reported, suggesting a dinuclear copper center with an unexpected structure similar to a [2Fe-2S]-type iron-sulfur center.
Journal ArticleDOI
Homogeneous Hydrogenation of Carbon Dioxide
TL;DR: In this article, the simplest and most studied reactions of CO{sub 2} are the catalytic reactions with H{sub 1} in the presence or absence of other reactive species.
Journal ArticleDOI
Reactions at supercritical conditions: Applications and fundamentals
TL;DR: A review of chemical reactions in and with supercritical fluids can be found in this paper, where the authors discuss both fundamental studies and applications of reactions at supercritical conditions, with focus on work published after 1985.