Journal ArticleDOI
Supercritical Fluids in Heterogeneous Catalysis
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This article is published in Chemical Reviews.The article was published on 1999-02-10. It has received 689 citations till now. The article focuses on the topics: Supercritical fluid & Heterogeneous catalysis.read more
Citations
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Phase behavior of systems containing Genapol X080®+technical 1-dodecene+water compared with the phase behavior of pure C12E8+pure 1-dodecene+water
TL;DR: In this article, the phase behavior of technical grade, nonionic surfactant Genapol X080+technical 1-dodecene+water was studied and compared to the phase behaviour of the pure compound.
Journal ArticleDOI
Application of Supercritical CO2 Treatment Enhances Enzymatic Hydrolysis of Sugarcane Bagasse
TL;DR: In this article, the effects of supercritical CO2 treatment on the enzymatic hydrolysis of sugarcane bagasse (2% w−v−1) and on the kinetic parameters were assessed in a central composite design (CCD).
Journal ArticleDOI
Critical Control by Temperature and Pressure of Enantiodifferentiating Anti-Markovnikov Photoaddition of Methanol to Diphenylpropene in Near Critical and Supercritical Carbon Dioxide
TL;DR: The enantiomeric excess of photoadduct obtained in the title reaction was critically manipulated not only by pressure (P) but also by temperature (T), exhibiting substantially different P-dependenc...
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Control of Stereoselectivity in 4-tert-Butylphenol Hydrogenation over a Carbon-supported Rhodium Catalyst by Carbon Dioxide Solvent
TL;DR: In this article, a high cis ratio (cis/(cis + trans) = 0.9) was obtained for 4-tert-butylphenol over a carbon-supported rhodium catalyst along with hydrochloric acid.
References
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Journal ArticleDOI
Aerogels-Airy Materials: Chemistry, Structure, and Properties.
Nicola Hüsing,Ulrich S. Schubert +1 more
TL;DR: The design of such a filigrane network requires the very careful control of chemical parameters and the reward is an assortment of different property profiles owing to the richness of possible variations.
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Structures of metal sites of oxidized bovine heart cytochrome c oxidase at 2.8 A
Tomitake Tsukihara,Hiroshi Aoyama,Eiki Yamashita,Takashi Tomizaki,Hiroshi Yamaguchi,Kyoko Shinzawa-Itoh,Ryosuke Nakashima,Rieko Yaono,Shinya Yoshikawa +8 more
TL;DR: The high resolution three-dimensional x-ray structure of the metal sites of bovine heart cytochrome c oxidase is reported, suggesting a dinuclear copper center with an unexpected structure similar to a [2Fe-2S]-type iron-sulfur center.
Journal ArticleDOI
Homogeneous Hydrogenation of Carbon Dioxide
TL;DR: In this article, the simplest and most studied reactions of CO{sub 2} are the catalytic reactions with H{sub 1} in the presence or absence of other reactive species.
Journal ArticleDOI
Reactions at supercritical conditions: Applications and fundamentals
TL;DR: A review of chemical reactions in and with supercritical fluids can be found in this paper, where the authors discuss both fundamental studies and applications of reactions at supercritical conditions, with focus on work published after 1985.