Journal ArticleDOI
Supercritical Fluids in Heterogeneous Catalysis
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This article is published in Chemical Reviews.The article was published on 1999-02-10. It has received 689 citations till now. The article focuses on the topics: Supercritical fluid & Heterogeneous catalysis.read more
Citations
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Journal ArticleDOI
Kinetics of liquid-phase hydrogenation reactions over supported metal catalysts — a review
Utpal K. Singh,M. Albert Vannice +1 more
TL;DR: In this article, the authors reviewed the kinetics of liquid-phase hydrogenation reactions with a special emphasis on α, β-unsaturated aldehydes as reactants and showed that surface coverage is independent of the liquid phase H2 concentration.
Journal ArticleDOI
More sustainable approaches for the synthesis of N-based heterocycles.
TL;DR: This research presents a novel and scalable approach to nanosciences called “Smart Nanotechnology” that combines “smart chip” technology with traditional “nanofiltration” techniques.
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Subcritical Water as Reaction Environment: Fundamentals of Hydrothermal Biomass Transformation
TL;DR: This review summarizes the current state of knowledge of hydrothermal biomass conversion in subcritical water and major emphasis is put on the nature of the carbohydrate monomers, since the conversion of the respective polymers is analogous with the additional prior step of hydrolytic depolymerization.
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New developments in hydrogenation catalysis particularly in synthesis of fine and intermediate chemicals
B. Chen,Uwe Dingerdissen,J.G.E. Krauter,H.G.J. Lansink Rotgerink,K. Mobus,D. J. Ostgard,Peter Panster,T.H. Riermeier,Steffen Dr. Seebald,T. Tacke,H. Trauthwein +10 more
TL;DR: An overview of the most relevant hydrogenations that have been brought on stream over the last 20 years, as well as, the upcoming processes that will set the future trends in chemical industry can be found in this paper.
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A perspective on catalysis in sub- and supercritical water
TL;DR: An overview of the field of catalysis in sub-and supercritical water can be found in this paper, where contributions that are particularly important, either for historical or scientific reasons, are highlighted.
References
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Journal ArticleDOI
Aerogels-Airy Materials: Chemistry, Structure, and Properties.
Nicola Hüsing,Ulrich S. Schubert +1 more
TL;DR: The design of such a filigrane network requires the very careful control of chemical parameters and the reward is an assortment of different property profiles owing to the richness of possible variations.
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Structures of metal sites of oxidized bovine heart cytochrome c oxidase at 2.8 A
Tomitake Tsukihara,Hiroshi Aoyama,Eiki Yamashita,Takashi Tomizaki,Hiroshi Yamaguchi,Kyoko Shinzawa-Itoh,Ryosuke Nakashima,Rieko Yaono,Shinya Yoshikawa +8 more
TL;DR: The high resolution three-dimensional x-ray structure of the metal sites of bovine heart cytochrome c oxidase is reported, suggesting a dinuclear copper center with an unexpected structure similar to a [2Fe-2S]-type iron-sulfur center.
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Homogeneous Hydrogenation of Carbon Dioxide
TL;DR: In this article, the simplest and most studied reactions of CO{sub 2} are the catalytic reactions with H{sub 1} in the presence or absence of other reactive species.
Journal ArticleDOI
Reactions at supercritical conditions: Applications and fundamentals
TL;DR: A review of chemical reactions in and with supercritical fluids can be found in this paper, where the authors discuss both fundamental studies and applications of reactions at supercritical conditions, with focus on work published after 1985.