Journal ArticleDOI
Supercritical Fluids in Heterogeneous Catalysis
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This article is published in Chemical Reviews.The article was published on 1999-02-10. It has received 689 citations till now. The article focuses on the topics: Supercritical fluid & Heterogeneous catalysis.read more
Citations
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Supercritical and near-critical CO2 in green chemical synthesis and processing
TL;DR: A review of the use of CO 2 to create greener processes and products, with a focus on research and commercialization efforts performed since 1995, is presented in this article, which reveals that careful application of CO2 technology can result in products (and processes) that are cleaner, less expensive and of higher quality.
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Lewis Acids: From Conventional Homogeneous to Green Homogeneous and Heterogeneous Catalysis
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Polymer synthesis and processing using supercritical carbon dioxide
TL;DR: Carbon dioxide is a clean and versatile solvent for the synthesis and processing of a range of materials as discussed by the authors, with particular attention being given to the formation of polymers with well defined morphologies.
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Metal-mediated reductive hydrodehalogenation of organic halides.
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Homogeneous Catalysis in Supercritical Fluids.
TL;DR: Homogeneous molecular catalysts, which have far greater control over selectivity than heterogeneous solid catalysts are now being tested in SCFs, and early results show that high rates, improved selectivity, and elimination of masstransfer problems can be achieved.
References
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Journal ArticleDOI
Aerogels-Airy Materials: Chemistry, Structure, and Properties.
Nicola Hüsing,Ulrich S. Schubert +1 more
TL;DR: The design of such a filigrane network requires the very careful control of chemical parameters and the reward is an assortment of different property profiles owing to the richness of possible variations.
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Structures of metal sites of oxidized bovine heart cytochrome c oxidase at 2.8 A
Tomitake Tsukihara,Hiroshi Aoyama,Eiki Yamashita,Takashi Tomizaki,Hiroshi Yamaguchi,Kyoko Shinzawa-Itoh,Ryosuke Nakashima,Rieko Yaono,Shinya Yoshikawa +8 more
TL;DR: The high resolution three-dimensional x-ray structure of the metal sites of bovine heart cytochrome c oxidase is reported, suggesting a dinuclear copper center with an unexpected structure similar to a [2Fe-2S]-type iron-sulfur center.
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Homogeneous Hydrogenation of Carbon Dioxide
TL;DR: In this article, the simplest and most studied reactions of CO{sub 2} are the catalytic reactions with H{sub 1} in the presence or absence of other reactive species.
Journal ArticleDOI
Reactions at supercritical conditions: Applications and fundamentals
TL;DR: A review of chemical reactions in and with supercritical fluids can be found in this paper, where the authors discuss both fundamental studies and applications of reactions at supercritical conditions, with focus on work published after 1985.