Journal ArticleDOI
Supercritical Fluids in Heterogeneous Catalysis
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This article is published in Chemical Reviews.The article was published on 1999-02-10. It has received 689 citations till now. The article focuses on the topics: Supercritical fluid & Heterogeneous catalysis.read more
Citations
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Journal ArticleDOI
Characterization and comparison of hydrophilic and hydrophobic room temperature ionic liquids incorporating the imidazolium cation
Jonathan G. Huddleston,Ann E. Visser,W. Matthew Reichert,Heather D. Willauer,Grant A. Broker,Robin D. Rogers +5 more
TL;DR: A series of hydrophilic and hydrophobic 1-alkyl-3-methylimidazolium room temperature ionic liquids (RTILs) have been prepared and characterized to determine how water content, density, viscosity, surface tension, melting point, and thermal stability are affected by changes in alkyl chain length and anion.
Journal ArticleDOI
Hydrogen Peroxide Synthesis: An Outlook beyond the Anthraquinone Process
TL;DR: The direct synthesis of H 2O2 from O2 and H2 using a variety of catalysts, and the factors influencing the formation and decomposition of H2O2 are examined in detail in this Review.
Journal ArticleDOI
Catalytic conversion of lignocellulosic biomass to fine chemicals and fuels
TL;DR: This critical review provides insights into the state-of-the-art accomplishments in the chemocatalytic technologies to generate fuels and value-added chemicals from lignocellulosic biomass, with an emphasis on its major component, cellulose.
Journal ArticleDOI
Nano-magnetite (Fe3O4) as a support for recyclable catalysts in the development of sustainable methodologies
TL;DR: The functionalized magnetically retrievable catalysts or nanocatalysts that are increasingly being used in catalysis, green chemistry and pharmaceutically significant reactions are summarized in this review.
Journal ArticleDOI
Green and Sustainable Solvents in Chemical Processes
TL;DR: This Review considers several aspects of the most prominent sustainable organicsolvents in use today, ionic liquids, deep eutectic solvents, supercritical fluids, switchable solVents, liquid polymers, and renewable solvent, giving a more complete picture of the current status of sustainable solvent research and development.
References
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Journal ArticleDOI
Continous‐mixture kinetics of coke formation from olefinic oligomers
TL;DR: In this article, a model for interpreting the molecular-weight distributions is presented for the olefinic oligomers and aromatic coke compounds that are experimentally observed in a catalyzed hexene isomerization process (the primary reaction). Reaction rate expressions for the secondary generation of hexene dimers, trimers and tetramers by irreversible reaction are represented in mass balances for a stirred tank reactor.
Journal ArticleDOI
Simultaneous pyrolysis of ethane-propane mixture in pulsed microreactor system
TL;DR: In this article, the pyrolyse entre 759 and 925°C de melanges ethane/propane, with a temps de sejour de 0.038 a 1.1 sec.
Book ChapterDOI
Hardening of fats and oils in supercritical CO2
TL;DR: In this article, DELOXAN ® supported precious metal fixed-bed catalysts were used for selective and complete hardening reactions of fats and oils, free fatty acids and fatty acid esters with hydrogen.
Journal ArticleDOI
Reaction phase effect on tertiary butyl alcohol synthesis by air oxidation of isobutane
TL;DR: In this article, a direct introduction of air to supercritical phase isobutane exhibited high activity for selective synthesis of tertiary butyl alcohol, especially on SiO2 TiO2 and Pd/carbon catalysts.