Journal ArticleDOI
Supercritical Fluids in Heterogeneous Catalysis
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This article is published in Chemical Reviews.The article was published on 1999-02-10. It has received 689 citations till now. The article focuses on the topics: Supercritical fluid & Heterogeneous catalysis.read more
Citations
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How does magnetic field affect polymerization in supercritical fluids? Study of radical polymerization in supercritical CO2
Jun Liu,Rui Zhang,Hongping Li,Buxing Han,Zhimin Liu,Tao Jiang,Jun He,Xiaogang Zhang,Guanying Yang +8 more
TL;DR: In this article, the effect of magnetic field on the polymerization of methyl methacrylate and styrene initiated with benzoyl peroxide in supercritical (SC) CO2 was studied.
Journal ArticleDOI
The Synthesis of Ce1 – xZr x O2 Oxides in Supercritical Alcohols and Catalysts for Carbon Dioxide Reforming of Methane on Their Basis
M. Yu. Smirnova,M. Yu. Smirnova,Svetlana N. Pavlova,Tamara Krieger,Tamara Krieger,Yu. N. Bespalko,V. I. Anikeev,Yu. A. Chesalov,V. V. Kaichev,N. V. Mezentseva,Vladislav A. Sadykov,Vladislav A. Sadykov +11 more
TL;DR: In this paper, the effect of starting zirconium compounds on the solvothermal synthesis of mixed Ce-Zr oxides in a flow reactor using ethanol and isopropanol as a supercritical medium was studied.
Journal ArticleDOI
Direct synthesis of dimethyl carbonate and propylene glycol using potassium bicarbonate as catalyst in supercritical CO2
TL;DR: In this paper, the improved one-pot synthesis of dimethyl carbonate and propylene glycol from propylene oxide, supercritical carbon dioxide, and methanol with potassium bicarbonate as the catalyst has been reported.
Journal ArticleDOI
Photocatalytic oxidation of n-octanol in aerated supercritical CO2 on hydrophobic TiO2
TL;DR: In this paper, supercritical CO2 has been used as a reaction medium for the photocatalytic oxidative degradation of n-octanol on a partially desilanized hydrophobic suspension of TiO2 as photocatalyst.
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Palladium-catalysed dehydrogenation of 1-phenylethanol in dense carbon dioxide
TL;DR: The feasibility of the heterogeneous catalytic dehydrogenation of alcohols in dense (sub- and supercritical) carbon dioxide is shown by the transformation of 1-phenylethanol in a continuous flow fixed-bed reactor.
References
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Journal ArticleDOI
Aerogels-Airy Materials: Chemistry, Structure, and Properties.
Nicola Hüsing,Ulrich S. Schubert +1 more
TL;DR: The design of such a filigrane network requires the very careful control of chemical parameters and the reward is an assortment of different property profiles owing to the richness of possible variations.
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Structures of metal sites of oxidized bovine heart cytochrome c oxidase at 2.8 A
Tomitake Tsukihara,Hiroshi Aoyama,Eiki Yamashita,Takashi Tomizaki,Hiroshi Yamaguchi,Kyoko Shinzawa-Itoh,Ryosuke Nakashima,Rieko Yaono,Shinya Yoshikawa +8 more
TL;DR: The high resolution three-dimensional x-ray structure of the metal sites of bovine heart cytochrome c oxidase is reported, suggesting a dinuclear copper center with an unexpected structure similar to a [2Fe-2S]-type iron-sulfur center.
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Homogeneous Hydrogenation of Carbon Dioxide
TL;DR: In this article, the simplest and most studied reactions of CO{sub 2} are the catalytic reactions with H{sub 1} in the presence or absence of other reactive species.
Journal ArticleDOI
Reactions at supercritical conditions: Applications and fundamentals
TL;DR: A review of chemical reactions in and with supercritical fluids can be found in this paper, where the authors discuss both fundamental studies and applications of reactions at supercritical conditions, with focus on work published after 1985.