Journal ArticleDOI
Supercritical Fluids in Heterogeneous Catalysis
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This article is published in Chemical Reviews.The article was published on 1999-02-10. It has received 689 citations till now. The article focuses on the topics: Supercritical fluid & Heterogeneous catalysis.read more
Citations
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Transition metal nanoparticle catalysis in green solvents
Ning Yan,Chaoxian Xiao,Yuan Kou +2 more
TL;DR: A review of the current status of NP catalysis in solvents and the main drawbacks hindering the particles from industrial practice can be found in this paper, where a state-of-the-art approach to satisfy ideal ESSR criteria is to produce cohesion over the individual contributions of metal center, stabilizer and solvent.
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Toxicity of Ionic Liquids: Eco(cyto)activity as Complicated, but Unavoidable Parameter for Task-Specific Optimization
TL;DR: It is shown that biological activity and cytotoxicity of ionic liquids dramatically depend on the nature of a biological system, and a careful selection of biological activity data is a must for the correct assessment of chemical technologies involving ionic liquid.
Journal ArticleDOI
Combining enabling techniques in organic synthesis: continuous flow processes with heterogenized catalysts.
TL;DR: The concepts article describes enabling techniques (solid-phase assisted synthesis, new reactor design, microwave irradiation and new solvents) in organic chemistry and emphasizes the combination of several of them for creating new synthetic technology platforms.
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Direct synthesis of hydrogen peroxide from H2 and O2 using Pd and Au catalysts
Philip Landon,Paul J. Collier,Albert Frederick Carley,David Chadwick,Adam J. Papworth,Andrew Burrows,Christopher J. Kiely,Graham J. Hutchings +7 more
TL;DR: In this paper, a detailed study of the factors influencing the formation and decomposition of hydrogen peroxide is presented for a Pd/sulfonated carbon catalyst in a methanol/water solvent.
References
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Journal ArticleDOI
Aerogels-Airy Materials: Chemistry, Structure, and Properties.
Nicola Hüsing,Ulrich S. Schubert +1 more
TL;DR: The design of such a filigrane network requires the very careful control of chemical parameters and the reward is an assortment of different property profiles owing to the richness of possible variations.
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Structures of metal sites of oxidized bovine heart cytochrome c oxidase at 2.8 A
Tomitake Tsukihara,Hiroshi Aoyama,Eiki Yamashita,Takashi Tomizaki,Hiroshi Yamaguchi,Kyoko Shinzawa-Itoh,Ryosuke Nakashima,Rieko Yaono,Shinya Yoshikawa +8 more
TL;DR: The high resolution three-dimensional x-ray structure of the metal sites of bovine heart cytochrome c oxidase is reported, suggesting a dinuclear copper center with an unexpected structure similar to a [2Fe-2S]-type iron-sulfur center.
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Homogeneous Hydrogenation of Carbon Dioxide
TL;DR: In this article, the simplest and most studied reactions of CO{sub 2} are the catalytic reactions with H{sub 1} in the presence or absence of other reactive species.
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Reactions at supercritical conditions: Applications and fundamentals
TL;DR: A review of chemical reactions in and with supercritical fluids can be found in this paper, where the authors discuss both fundamental studies and applications of reactions at supercritical conditions, with focus on work published after 1985.