Journal ArticleDOI
Supercritical Fluids in Heterogeneous Catalysis
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This article is published in Chemical Reviews.The article was published on 1999-02-10. It has received 689 citations till now. The article focuses on the topics: Supercritical fluid & Heterogeneous catalysis.read more
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Book ChapterDOI
Catalytic Thermochemical Processes for Biomass Conversion to Biofuels and Chemicals
TL;DR: In this paper, the effect of reaction conditions, reactors, solvents and catalysts on the yield and distribution of the products are reviewed for the thermal process of biomass for biofuels and chemicals.
Journal ArticleDOI
Transport, Geometrical and Topological Properties of Stealthy Disordered Hyperuniform Two-Phase Systems
TL;DR: In this paper, the authors focus on the disordered regime in which there is no long-range order, and control the degree of short-range ordering, and map these stealthy disordered hyperuniform point configurations to two-phase media by circumscribing each point with a possibly overlapping sphere.
Journal ArticleDOI
Kinetics of the N-alkylation by supercritical methanol
Dmitry S. Bulgarevich,Katsuto Otake,Takeshi Sako,Tsutomu Sugeta,Yoshihiro Takebayashi,Chiyoshi Kamizawa,Daisuke Shintani,Akira Negishi,Chikao Tsurumi +8 more
TL;DR: In situ ultraviolet absorption spectroscopy was applied to study the kinetics of Nalkylation of N-methyl-o-toluidine (NMOT) by supercritical methanol without any added catalysts as discussed by the authors.
Journal ArticleDOI
Pyrite in contact with supercritical water: the desolation of steam.
TL;DR: It is come to the conclusion that hot-pressurized water on pyrite leads to an interface where a dry pyrites surface is in contact with the nearby SC water without significant chemical interactions.
Journal ArticleDOI
Catalyst preparation using supercritical carbon dioxide: preparation of Rh/FSM-16 catalysts and their catalytic performances in butane hydrogenolysis reaction
TL;DR: In this article, supported Rh catalysts on FSM-16 were prepared by treating FSM16, impregnated with [Rh(OAc)2]2 in supercritical carbon dioxide at 398 K and 30.3 MPa.
References
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Journal ArticleDOI
Aerogels-Airy Materials: Chemistry, Structure, and Properties.
Nicola Hüsing,Ulrich S. Schubert +1 more
TL;DR: The design of such a filigrane network requires the very careful control of chemical parameters and the reward is an assortment of different property profiles owing to the richness of possible variations.
Journal ArticleDOI
Structures of metal sites of oxidized bovine heart cytochrome c oxidase at 2.8 A
Tomitake Tsukihara,Hiroshi Aoyama,Eiki Yamashita,Takashi Tomizaki,Hiroshi Yamaguchi,Kyoko Shinzawa-Itoh,Ryosuke Nakashima,Rieko Yaono,Shinya Yoshikawa +8 more
TL;DR: The high resolution three-dimensional x-ray structure of the metal sites of bovine heart cytochrome c oxidase is reported, suggesting a dinuclear copper center with an unexpected structure similar to a [2Fe-2S]-type iron-sulfur center.
Journal ArticleDOI
Homogeneous Hydrogenation of Carbon Dioxide
TL;DR: In this article, the simplest and most studied reactions of CO{sub 2} are the catalytic reactions with H{sub 1} in the presence or absence of other reactive species.
Journal ArticleDOI
Reactions at supercritical conditions: Applications and fundamentals
TL;DR: A review of chemical reactions in and with supercritical fluids can be found in this paper, where the authors discuss both fundamental studies and applications of reactions at supercritical conditions, with focus on work published after 1985.