Journal ArticleDOI
Supercritical Fluids in Heterogeneous Catalysis
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This article is published in Chemical Reviews.The article was published on 1999-02-10. It has received 689 citations till now. The article focuses on the topics: Supercritical fluid & Heterogeneous catalysis.read more
Citations
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Production of renewable fuels by blending bio-oil with alcohols and upgrading under supercritical conditions
TL;DR: In this article, the authors studied a non-catalytic upgrading of fast pyrolysis bio-oil by blending under supercritical conditions using methanol, ethanol and isopropanol as solvent and hydrogen donor.
Journal ArticleDOI
Critical Temperatures and Pressures of Several Binary and Ternary Mixtures Concerning the Alkylation of 2-Methylpropane with 1-Butene in the Presence of Methane or Carbon Dioxide
TL;DR: The critical temperatures and pressures of four binary mixtures (2-methylpropane + 1-butene, 2,2,4-trimethylpentane + 2-methyl-propane, 2-ethylpropane+ methane, and 2-mixture + carbon dioxid...
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Chemoselective Hydrogenation of Halonitroaromatics over Platinum on Carbon as Catalyst in Supercritical Carbon Dioxide
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Alkylation of Toluene with Propylene in Supercritical Carbon Dioxide over Chemical Liquid Deposition HZSM-5 Pellets
Te-Wen Kuo and,Chung-Sung Tan +1 more
TL;DR: In this paper, the shape-screening character of toluene with propylene in supercritical carbon dioxide over the parent and modified HZSM-5 pellets was carried out in a packed bed.
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Enhancing Reaction Rate of Transesterification of Glycerol Monostearate and Methanol by CO2
TL;DR: It is shown that addition of CO2 can enhance the miscibility of the reactant and reduce the viscosity of the reaction mixture, and increase the diffusion coefficients of the reactsants.
References
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Journal ArticleDOI
Aerogels-Airy Materials: Chemistry, Structure, and Properties.
Nicola Hüsing,Ulrich S. Schubert +1 more
TL;DR: The design of such a filigrane network requires the very careful control of chemical parameters and the reward is an assortment of different property profiles owing to the richness of possible variations.
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Structures of metal sites of oxidized bovine heart cytochrome c oxidase at 2.8 A
Tomitake Tsukihara,Hiroshi Aoyama,Eiki Yamashita,Takashi Tomizaki,Hiroshi Yamaguchi,Kyoko Shinzawa-Itoh,Ryosuke Nakashima,Rieko Yaono,Shinya Yoshikawa +8 more
TL;DR: The high resolution three-dimensional x-ray structure of the metal sites of bovine heart cytochrome c oxidase is reported, suggesting a dinuclear copper center with an unexpected structure similar to a [2Fe-2S]-type iron-sulfur center.
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Homogeneous Hydrogenation of Carbon Dioxide
TL;DR: In this article, the simplest and most studied reactions of CO{sub 2} are the catalytic reactions with H{sub 1} in the presence or absence of other reactive species.
Journal ArticleDOI
Reactions at supercritical conditions: Applications and fundamentals
TL;DR: A review of chemical reactions in and with supercritical fluids can be found in this paper, where the authors discuss both fundamental studies and applications of reactions at supercritical conditions, with focus on work published after 1985.