Journal ArticleDOI
Tuning the Light Emission Properties by Band Gap Engineering in Hybrid Lead Halide Perovskite
Valerio D’Innocenzo,Valerio D’Innocenzo,Ajay Ram Srimath Kandada,Michele De Bastiani,Michele De Bastiani,Marina Gandini,Annamaria Petrozza +6 more
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TLDR
It is demonstrated that larger crystallites present smaller band gap and longer lifetime, which correlates to a smaller radiative bimolecular recombination coefficient, and also shows that they present a higher optical gain, becoming preferred candidates for the realization of CW lasing devices.Abstract:
We report about the relationship between the morphology and luminescence properties of methylammonium lead trihalide perovskite thin films. By tuning the average crystallite dimension in the film from tens of nanometers to a few micrometers, we are able to tune the optical band gap of the material along with its photoluminescence lifetime. We demonstrate that larger crystallites present smaller band gap and longer lifetime, which correlates to a smaller radiative bimolecular recombination coefficient. We also show that they present a higher optical gain, becoming preferred candidates for the realization of CW lasing devices.read more
Citations
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Journal ArticleDOI
Brightly Luminescent and Color-Tunable Colloidal CH3NH3PbX3 (X = Br, I, Cl) Quantum Dots: Potential Alternatives for Display Technology.
Feng Zhang,Haizheng Zhong,Cheng Chen,Xian-gang Wu,Xiangmin Hu,Huang Hailong,Junbo Han,Bingsuo Zou,Yuping Dong +8 more
TL;DR: A ligand-assisted reprecipitation strategy is developed to fabricate brightly luminescent and color-tunable colloidal CH3NH3PbX3 quantum dots with absolute quantum yield up to 70% at room temperature and low excitation fluencies, expected to exhibit interesting nanoscale excitonic properties.
Journal ArticleDOI
Perovskite energy funnels for efficient light-emitting diodes
Mingjian Yuan,Li Na Quan,Li Na Quan,Riccardo Comin,Grant Walters,Randy P. Sabatini,Oleksandr Voznyy,Sjoerd Hoogland,Yongbiao Zhao,Eric M. Beauregard,Pongsakorn Kanjanaboos,Zheng-Hong Lu,Dong Ha Kim,Edward H. Sargent +13 more
TL;DR: A perovskite mixed material comprising a series of differently quantum-size-tuned grains that funnels photoexcitations to the lowest-bandgap light-emitter in the mixture functions as charge carrier concentrators, ensuring that radiative recombination successfully outcompetes trapping and hence non-radiatives recombination.
Journal ArticleDOI
Tuning the Optical Properties of Cesium Lead Halide Perovskite Nanocrystals by Anion Exchange Reactions
Quinten A. Akkerman,Valerio D’Innocenzo,Sara Accornero,Alice Scarpellini,Annamaria Petrozza,Mirko Prato,Liberato Manna +6 more
TL;DR: It is demonstrated that, via controlled anion exchange reactions using a range of different halide precursors, this approach gives access to perovskite semiconductor NCs with both structural and optical qualities comparable to those of directly synthesized NCs.
Journal ArticleDOI
High-quality bulk hybrid perovskite single crystals within minutes by inverse temperature crystallization
Makhsud I. Saidaminov,Ahmed L. Abdelhady,Ahmed L. Abdelhady,Banavoth Murali,Erkki Alarousu,Victor M. Burlakov,Wei-Wei Peng,Ibrahim Dursun,Lingfei Wang,Yao-xin He,Giacomo Maculan,Alain Goriely,Tao Wu,Omar F. Mohammed,Osman M. Bakr +14 more
TL;DR: A rapid crystal growth process to obtain MAPbX3 single crystals, an order of magnitude faster than previous reports, and the grown crystals exhibit transport properties and trap densities comparable to the highest quality MAPb X3 reported to date.
Journal ArticleDOI
Perovskite photonic sources
TL;DR: In this article, the authors discuss the properties of perovskites that benefit light emission, review recent progress in perov-skite electroluminescent diodes and optically pumped lasers, and examine the remaining challenges in achieving continuous-wave and electrically driven lasing.
References
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Journal ArticleDOI
Sequential deposition as a route to high-performance perovskite-sensitized solar cells
Julian Burschka,Norman Pellet,Norman Pellet,Soo-Jin Moon,Robin Humphry-Baker,Peng Gao,Mohammad Khaja Nazeeruddin,Michael Grätzel +7 more
TL;DR: A sequential deposition method for the formation of the perovskite pigment within the porous metal oxide film that greatly increases the reproducibility of their performance and allows the fabrication of solid-state mesoscopic solar cells with unprecedented power conversion efficiencies and high stability.
Journal ArticleDOI
Electron-hole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber.
Samuel D. Stranks,Giles E. Eperon,Giulia Grancini,Christopher Menelaou,Marcelo J. P. Alcocer,Tomas Leijtens,Laura M. Herz,Annamaria Petrozza,Henry J. Snaith +8 more
TL;DR: In this article, transient absorption and photoluminescence-quenching measurements were performed to determine the electron-hole diffusion lengths, diffusion constants, and lifetimes in mixed halide and triiodide perovskite absorbers.
Journal Article
Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber
Samuel D. Stranks,Giles E. Eperon,Giulia Grancini,Christopher Menelaou,Marcelo J. P. Alcocer,Tomas Leijtens,Laura M. Herz,Annamaria Petrozza,Henry J. Snaith +8 more
TL;DR: In this paper, transient absorption and photoluminescence-quenching measurements were performed to determine the electron-hole diffusion lengths, diffusion constants, and lifetimes in mixed halide and triiodide perovskite absorbers.
Journal ArticleDOI
Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH3NH3PbI3
Guichuan Xing,Nripan Mathews,Shuangyong Sun,Swee Sien Lim,Yeng Ming Lam,Michael Grätzel,Michael Grätzel,Subodh Mhaisalkar,Tze Chien Sum +8 more
TL;DR: Two studies show, using a variety of time-resolved absorption and emission spectroscopic techniques, that perovskite materials manifest relatively long diffusion paths for charge carriers energized by light absorption, highlighting effective carrier diffusion as a fruitful parameter for further optimization.
Journal ArticleDOI
Temperature dependence of the energy gap in semiconductors
TL;DR: In this article, a relation for the variation of the energy gap (E g ) with temperature (T ) in semiconductors is proposed. And the equation satisfactorily represents the experimental data for diamond, Si, Ge, 6H-SiC, GaAs, InP and InAs.