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Valorization of greenhouse carbon dioxide emissions into value-added products by catalytic processes

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TLDR
In this article, a review of the catalytic processes of the chemistries involved in the conversion of CO 2 into value-added products is presented, and an overview regarding the challenges and opportunities for future research in CO 2 valorization is provided.
Abstract
Complete oxidation or combustion of any carbon-based organic matter produces CO 2 , which is known to cause global warming and climate changes To mitigate the concentration of CO 2 in the atmosphere various strategies have been implemented such as separation, storage, and valorization of CO 2 The focus of this review was on the catalytic processes of the chemistries involved in the conversion of CO 2 into value-added products The various valorization technologies which include conversion of CO 2 into fuel, valorization of CO 2 as a feedstock for chemicals were discussed Also, an overview regarding the challenges and opportunities for future research in CO 2 valorization was provided

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Journal ArticleDOI

Sustainable Conversion of Carbon Dioxide: An Integrated Review of Catalysis and Life Cycle Assessment

TL;DR: The motivation to develop CO2-based chemistry does not depend primarily on the absolute amount of CO2 emissions that can be remediated by a single technology and is stimulated by the significance of the relative improvement in carbon balance and other critical factors defining the environmental impact of chemical production in all relevant sectors in accord with the principles of green chemistry.
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Postsynthetic ionization of an imidazole-containing metal–organic framework for the cycloaddition of carbon dioxide and epoxides

TL;DR: In this article, a bifunctional imidazolium functionalized zirconium metal-organic framework (Zr-MOF), (I−)Meim-UiO-66 (2), was successfully prepared from the iminazole-containing Zr-MoF Im UiO+66 (1) by a post-synthetic modification (PSM) method.
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One-Step Reforming of CO2 and CH4 into High-Value Liquid Chemicals and Fuels at Room Temperature by Plasma-Driven Catalysis.

TL;DR: The combination of plasma and catalyst in this process shows great potential for manipulating the distribution of liquid chemical products in a given process.
Journal ArticleDOI

Sustainion Imidazolium-Functionalized Polymers for Carbon Dioxide Electrolysis

TL;DR: The synthesis and testing of a series of new anion-conductive membranes that incorporate the functional character of imidazolium-based ionic liquids as co-catalysts in CO2 reduction into a solid membrane with a styrene backbone are reported.
Journal ArticleDOI

Cr(salophen) Complex Catalyzed Cyclic Carbonate Synthesis at Ambient Temperature And Pressure

TL;DR: In this article, the combination of a chromium(III) salophen bromide complex and tetrabutylammonium bromides was shown to catalyze the reaction between terminal epoxides and carbon dioxide at ambient temperature and 1 bar carbon dioxide pressure and between internal epoxide and CO 2 at 80 °C and 10 bar CO 2 pressure to form cyclic carbonates.
References
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Book

Modern Aspects of Electrochemistry

TL;DR: In this paper, the authors focus on topics at the forefront of electrochemical research, such as splitting water by electrolysis, splitting water with visible light, and the recent development of lithium batteries.
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Microalgal triacylglycerols as feedstocks for biofuel production: perspectives and advances

TL;DR: A brief summary of the current knowledge on oleaginous algae and their fatty acid and TAG biosynthesis, algal model systems and genomic approaches to a better understanding of TAG production, and a historical perspective and path forward for microalgae-based biofuel research and commercialization are provided.
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Transformation of carbon dioxide.

TL;DR: Reaction Mechanism, Synthesis of Urea and Urethane Derivatives, and Alcohol Homologation 2382 10.1.
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Recent advances in catalytic hydrogenation of carbon dioxide

TL;DR: A critical review of recent developments in hydrogenation reaction, with emphases on catalytic reactivity, reactor innovation, and reaction mechanism, provides an overview regarding the challenges and opportunities for future research in the field.
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