Showing papers by "British Geological Survey published in 2014"

Marine litter distribution and density in European seas, from the shelves to deep basins.

Abstract: Anthropogenic litter is present in all marine habitats, from beaches to the most remote points in the oceans. On the seafloor, marine litter, particularly plastic, can accumulate in high densities with deleterious consequences for its inhabitants. Yet, because of the high cost involved with sampling the seafloor, no large-scale assessment of distribution patterns was available to date. Here, we present data on litter distribution and density collected during 588 video and trawl surveys across 32 sites in European waters. We found litter to be present in the deepest areas and at locations as remote from land as the Charlie-Gibbs Fracture Zone across the Mid-Atlantic Ridge. The highest litter density occurs in submarine canyons, whilst the lowest density can be found on continental shelves and on ocean ridges. Plastic was the most prevalent litter item found on the seafloor. Litter from fishing activities (derelict fishing lines and nets) was particularly common on seamounts, banks, mounds and ocean ridges. Our results highlight the extent of the problem and the need for action to prevent increasing accumulation of litter in marine environments.

Dietary mineral supplies in Africa

Abstract: Dietary micronutrient deficiencies (MNDs) are widespread, yet their prevalence can be difficult to assess. Here, we estimate MND risks due to inadequate intakes for seven minerals in Africa using food supply and composition data, and consider the potential of food-based and agricultural interventions. Food Balance Sheets (FBSs) for 46 countries were integrated with food composition data to estimate per capita supply of calcium (Ca), copper (Cu), iron (Fe), iodine (I), magnesium (Mg), selenium (Se) and zinc (Zn), and also phytate. Deficiency risks were quantified using an estimated average requirement (EAR) ‘cut-point’ approach. Deficiency risks are highest for Ca (54% of the population), followed by Zn (40%), Se (28%) and I (19%, after accounting for iodized salt consumption). The risk of Cu (1%) and Mg (<1%) deficiency are low. Deficiency risks are generally lower in the north and west of Africa. Multiple MND risks are high in many countries. The population-weighted mean phytate supply is 2770 mg capita−1 day−1. Deficiency risks for Fe are lower than expected (5%). However, ‘cut-point’ approaches for Fe are sensitive to assumptions regarding requirements; e.g. estimates of Fe deficiency risks are 43% under very low bioavailability scenarios consistent with high-phytate, low-animal protein diets. Fertilization and breeding strategies could greatly reduce certain MNDs. For example, meeting HarvestPlus breeding targets for Zn would reduce dietary Zn deficiency risk by 90% based on supply data. Dietary diversification or direct fortification is likely to be needed to address Ca deficiency risks.

A stratigraphical basis for the Anthropocene

Abstract: Recognition of intimate feedback mechanisms linking changes across the atmosphere, biosphere, geosphere and hydrosphere demonstrates the pervasive nature of humankind's influence, perhaps to the point that we have fashioned a new geological epoch, the Anthropocene. To what extent will these changes be evident as long-lasting signatures in the geological record? To establish the Anthropocene as a formal chronostratigraphical unit it is necessary to consider a spectrum of indicators of anthropogenically induced environmental change, and to determine how these show as stratigraphic signals that can be used to characterize an Anthropocene unit and to recognize its base. It is important to consider these signals against a context of Holocene and earlier stratigraphic patterns. Here we review the parameters used by stratigraphers to identify chronostratigraphical units and how these could apply to the definition of the Anthropocene. The onset of the range of signatures is diachronous, although many show maximum signatures which post-date1945, leading to the suggestion that this date may be a suitable age for the start of the Anthropocene.

Mapping seabed sediments: Comparison of manual, geostatistical, object-based image analysis and machine learning approaches

Abstract: Marine spatial planning and conservation need underpinning with sufficiently detailed and accurate seabed substrate and habitat maps. Although multibeam echosounders enable us to map the seabed with high resolution and spatial accuracy, there is still a lack of fit-for-purpose seabed maps. This is due to the high costs involved in carrying out systematic seabed mapping programmes and the fact that the development of validated, repeatable, quantitative and objective methods of swath acoustic data interpretation is still in its infancy. We compared a wide spectrum of approaches including manual interpretation, geostatistics, object-based image analysis and machine-learning to gain further insights into the accuracy and comparability of acoustic data interpretation approaches based on multibeam echosounder data (bathymetry, backscatter and derivatives) and seabed samples with the aim to derive seabed substrate maps. Sample data were split into a training and validation data set to allow us to carry out an accuracy assessment. Overall thematic classification accuracy ranged from 67% to 76% and Cohen׳s kappa varied between 0.34 and 0.52. However, these differences were not statistically significant at the 5% level. Misclassifications were mainly associated with uncommon classes, which were rarely sampled. Map outputs were between 68% and 87% identical. To improve classification accuracy in seabed mapping, we suggest that more studies on the effects of factors affecting the classification performance as well as comparative studies testing the performance of different approaches need to be carried out with a view to developing guidelines for selecting an appropriate method for a given dataset. In the meantime, classification accuracy might be improved by combining different techniques to hybrid approaches and multi-method ensembles.

Detection and impacts of leakage from sub-seafloor deep geological carbon dioxide storage

Abstract: Fossil fuel power generation and other industrial emissions of carbon dioxide are a threat to global climate1, yet many economies will remain reliant on these technologies for several decades2. Carbon dioxide capture and storage (CCS) in deep geological formations provides an effective option to remove these emissions from the climate system3. In many regions storage reservoirs are located offshore4, 5, over a kilometre or more below societally important shelf seas6. Therefore, concerns about the possibility of leakage7, 8 and potential environmental impacts, along with economics, have contributed to delaying development of operational CCS. Here we investigate the detectability and environmental impact of leakage from a controlled sub-seabed release of CO2. We show that the biological impact and footprint of this small leak analogue (<1 tonne CO2 d−1) is confined to a few tens of metres. Migration of CO2 through the shallow seabed is influenced by near-surface sediment structure, and by dissolution and re-precipitation of calcium carbonate naturally present in sediments. Results reported here advance the understanding of environmental sensitivity to leakage and identify appropriate monitoring strategies for full-scale carbon storage operations.

Atomic spectrometry update – a review of advances in environmental analysis

Abstract: This is the 30th annual review of the application of atomic spectrometry to the chemical analysis of environmental samples. This Update refers to papers published approximately between August 2013 and July 2014 and continues the series of Atomic Spectrometry Updates (ASUs) in environmental analysis that should be read in conjunction with other related ASUs in the series, namely: clinical and biological materials, foods and beverages, advances in atomic spectrometry and related techniques, elemental speciation,X-ray fluorescence spectrometry, and the analysis of metals, chemicals and functional materials. In the field of air analysis, highlights within this review period included: the use of 3D printing technology for the rapid prototyping of new air sampler components; single particle ICP-MS studies; use of a new triple-quadrupole ICP-MS for the analysis of radioactive species and the use of FEG-SEM and IBA for the analysis of gun-shot residues. In the field of water analysis, methods continue to be developed: for the extraction and preconcentration of elements; speciation of As, Cr, Hg and Sb forms and determination of elemental constituents in colloidal and NP fractions. Instrumental developments reported include the use of MC-ICP-MS for isotopic tracer studies and a review of XRF techniques and associated preconcentration procedures for trace element analysis. Many articles featuring the analysis of plants and soils appeared but, as usual, most focused on environmental applications rather than the advancement of atomic spectrometry. There have, however, been interesting developments, such as the almost bewildering increase in types of micro-extraction for analyte preconcentration and the resurgence of CS-AAS. Clearly LIBS is maturing rapidly, with soil analysis becoming more routine in nature. Also notable was the way the accident at the Fukishima-Daiichi nuclear power plant triggered development of analytical methods for the assessment of contamination in the surrounding area. Recent research indicates that geological applications still drives many of the instrumental and methodological advances in LA-ICP-MS. Fundamental studies continue to shed light on the processes involved and hence ways of improving the analysis of laser-produced aerosols. The preparation of NP powders for the production of matrix-matched RMs for microanalytical techniques such as LA-ICP-MS and SIMS showed great promise for addressing one of the major issues when analysing geological materials by these techniques. Steady advances in MC-ICP-MS methodology is feeding through to applications in isotope geochemistry, while new SIMS instrumentation is being directed towards probing fine growth structures in biogenic carbonates and inferring past climate conditions from their geochemistry. Feedback on this review is most welcome and the review coordinator can be contacted using the email address provided.

Chapter 1 An overview of the eruption of Soufrière Hills Volcano, Montserrat from 2000 to 2010

Abstract: The 1995–present eruption of Soufriere Hills Volcano on Montserrat has produced over a cubic kilometre of andesitic magma, creating a series of lava domes that were successively destroyed, with much of their mass deposited in the sea. There have been five phases of lava extrusion to form these lava domes: November 1995–March 1998; November 1999–July 2003; August 2005–April 2007; July 2008–January 2009; and October 2009–February 2010. It has been one of the most intensively studied volcanoes in the world during this time, and there are long instrumental and observational datasets. From these have sprung major new insights concerning: the cyclicity of magma transport; low-frequency earthquakes associated with conduit magma flow; the dynamics of lateral blasts and Vulcanian explosions; the role that basalt–andesite magma mingling in the mid-crust has in powering the eruption; identification using seismic tomography of the uppermost magma reservoir at a depth of 5.5 > 7.5 km; and many others. Parallel to the research effort, there has been a consistent programme of quantitative risk assessment since 1997 that has both pioneered new methods and provided a solid evidential source for the civil authority to use in mitigating the risks to the people of Montserrat.

4D electrical resistivity tomography monitoring of soil moisture dynamics in an operational railway embankment

Abstract: The internal moisture dynamics of an aged (> 100 years old) railway earthwork embankment, which is still in use, are investigated using 2D and 3D resistivity monitoring. A methodology was employed that included automated 3D ERT data capture and telemetric transfer with on-site power generation, the correction of resistivity models for seasonal temperature changes and the translation of subsurface resistivity distributions into moisture content based on petrophysical relationships developed for the embankment material. Visualization of the data as 2D sections, 3D tomograms and time series plots for different zones of the embankment enabled the development of seasonal wetting fronts within the embankment to be monitored at a high-spatial resolution and the respective distributions of moisture in the flanks, crest and toes of the embankment to be assessed. Although the embankment considered here is at no immediate risk of failure, the approach developed for this study is equally applicable to other more high-risk earthworks and natural slopes.

Integrating 40Ar/39Ar, U-Pb, and astronomical clocks in the Cretaceous Niobrara Formation, Western Interior Basin, USA

Abstract: This study revises and improves the chronostratigraphic framework for late Turonian through early Campanian time based on work in the Western Interior U.S. and introduces new methods to better quantify uncertainties associated with the development of such time scales. Building on the unique attributes of the Western Interior Basin, which contains abundant volcanic ash beds and rhythmic strata interpreted to record orbital cycles, we integrate new radioisotopic data of improved accuracy with a recently published astrochronologic framework for the Niobrara Formation. New 40Ar/39Ar laser fusion ages corresponding to eight different ammonite biozones are determined by analysis of legacy samples, as well as newly collected material. These results are complemented by new U-Pb (zircon) chemical abrasion–isotope dilution–thermal ionization mass spectrometry ages from four biozones in the study interval. When combined with published radioisotopic data from the Cenomanian-Turonian boundary, paired 206Pb/238U and 40Ar/39Ar ages spanning Cenomanian to Campanian time support an astronomically calibrated Fish Canyon sanidine standard age of 28.201 Ma. Stage boundary ages are estimated via integration of new radioisotopic data with the floating astrochronology for the Niobrara Formation. The ages are determined by anchoring the long eccentricity bandpass from spectral analysis of the Niobrara Formation to radioisotopic ages with the lowest uncertainty proximal to the boundary, and adding or subtracting time by parsing the 405 k.y. cycles. The new stage boundary age determinations are: 89.75 ± 0.38 Ma for the Turonian-Coniacian, 86.49 ± 0.44 Ma for the Coniacian-Santonian, and 84.19 ± 0.38 Ma for the Santonian-Campanian boundary. The 2σ uncertainties for these estimates include systematic contributions from the radioisotopic measurements, astrochronologic methods, and geologic uncertainties (related to stratigraphic correlation and the presence of hiatuses). The latter geologic uncertainties have not been directly addressed in prior time scale studies and their determination was made possible by critical biostratigraphic observations. Each methodological approach employed in this study—new radioisotopic analysis, stratigraphic correlation, astrochronology, and ammonite and inoceramid biostratigraphy—was critical for achieving the final result.

The technofossil record of humans

Abstract: As humans have colonised and modified the Earth’s surface, they have developed progressively more sophisticated tools and technologies. These underpin a new kind of stratigraphy, that we term technostratigraphy, marked by the geologically accelerated evolution and diversification of technofossils – the preservable material remains of the technosphere (Haff, 2013), driven by human purpose and transmitted cultural memory, and with the dynamics of an emergent system. The technosphere, present in some form for most of the Quaternary, shows several thresholds. Its expansion and transcontinental synchronisation in the mid 20th century has produced a global technostratigraphy that combines very high time-resolution, great geometrical complexity and wide (including transplanetary) extent. Technostratigraphy can help characterise the deposits of a potential Anthropocene Epoch and its emergence marks a step change in planetary mode.

Laboratory simulations of fluid/gas induced micro-earthquakes: application to volcano seismology

Abstract: Understanding different seismic signals recorded in active volcanic regions allows geoscientists to derive insight into the processes that generate them. A key type is known as Low Frequency or Long Period (LP) event, generally understood to be generated by different fluid types resonating in cracks and faults. The physical mechanisms of these signals have been linked to either resonance/turbulence within fluids, or as a result of fluids ‘sloshing’ due to a mixture of gas and fluid being present in the system. Less well understood, however, is the effect of the fluid type (phase) on the measured signal. To explore this, we designed an experiment in which we generated a precisely controlled liquid to gas transition in a closed system by inducing rapid decompression of fluid-filled fault zones in a sample of basalt from Mt. Etna Volcano, Italy. We find that fluid phase transition is accompanied by a marked frequency shift in the accompanying microseismic dataset that can be compared to volcano seismic data. Moreover, our induced seismic activity occurs at pressure conditions equivalent to hydrostatic depths of 200 to 750 meters. This is consistent with recently measured dominant frequencies of LP events and with numerous models.

Proterozoic onset of crustal reworking and collisional tectonics: Reappraisal of the zircon oxygen isotope record

Abstract: A global U-Pb and δ18O zircon database shows temporal changes in the magmatic record related to changes in the degree of crustal reworking. The δ18O composition of bulk sediment remains relatively constant through geologic time, with a mean value of 14.9‰. In contrast, the δ18O values in magmatic zircons vary from relatively low values averaging ∼6‰ in the Archean to increasingly higher and scattered values defining a series of peaks and troughs in post-Archean data. The degree of crustal reworking increases at times of supercontinent assembly. Therefore we attribute the pattern of post-Archean δ18O values recorded by magmatic zircons to a significant increase in the incorporation of high δ18O sediment in response to enhanced crustal thickening and reworking associated with the onset of collisional tectonics, especially during formation of supercontinents.

High-frequency monitoring of nitrogen and phosphorus response in three rural catchments to the end of the 2011–2012 drought in England

Abstract: This paper uses high-frequency bankside measurements from three catchments selected as part of the UK government-funded Demonstration Test Catchments (DTC) project. We compare the hydrological and hydrochemical patterns during the water year 2011–2012 from the Wylye tributary of the River Avon with mixed land use, the Blackwater tributary of the River Wensum with arable land use and the Newby Beck tributary of the River Eden with grassland land use. The beginning of the hydrological year was unusually dry and all three catchments were in states of drought. A sudden change to a wet summer occurred in April 2012 when a heavy rainfall event affected all three catchments. The year-long time series and the individual storm responses captured by in situ nutrient measurements of nitrate and phosphorus (total phosphorus and total reactive phosphorus) concentrations at each site reveal different pollutant sources and pathways operating in each catchment. Large storm-induced nutrient transfers of nitrogen and or phosphorus to each stream were recorded at all three sites during the late April rainfall event. Hysteresis loops suggested transport-limited delivery of nitrate in the Blackwater and of total phosphorus in the Wylye and Newby Beck, which was thought to be exacerbated by the dry antecedent conditions prior to the storm. The high rate of nutrient transport in each system highlights the scale of the challenges faced by environmental managers when designing mitigation measures to reduce the flux of nutrients to rivers from diffuse agricultural sources. It also highlights the scale of the challenge in adapting to future extreme weather events under a changing climate.

Characterisation of the Quaternary eruption record: analysis of the Large Magnitude Explosive Volcanic Eruptions (LaMEVE) database

Abstract: The Large Magnitude Explosive Volcanic Eruptions (LaMEVE) database contains data on 1,883 Quaternary eruption records of magnitude (M) 4 and above and is publically accessible online via the British Geological Survey. Spatial and temporal analysis of the data indicates that the record is incomplete and is thus biased. The recorded distribution of volcanoes is variable on a global scale, with three-quarters of all volcanoes with M≥4 Quaternary activity located in the northern hemisphere and a quarter within Japan alone. The distribution of recorded eruptions does not strictly follow the spatial distribution of volcanoes and has distinct intra-regional variability, with about 40% of all recorded eruptions having occurred in Japan, reflecting in part the country’s efforts devoted to comprehensive volcanic studies. The number of eruptions in LaMEVE decreases with increasing age, exemplified by the recording of 50% of all known Quaternary eruptions during the last 20,000 years. Historical dating is prevalent from 1450 AD to the present day, substantially improving record completeness. The completeness of the record also improves as magnitude increases. This is demonstrated by the calculation of the median time, T50, for eruptions within given magnitude intervals, where 50% of eruptions are older than T50: T50 ranges from 5,070 years for M4-4.9 eruptions to 935,000 years for M≥8 eruptions. T50 follows a power law fit, suggesting a quantifiable relationship between eruption size and preservation potential of eruptive products. Several geographic regions have T50 ages of <250 years for the smallest (~M4) eruptions reflecting substantial levels of under-recording. There is evidence for latitudinal variation in eruptive activity, possibly due to the effects of glaciation. A peak in recorded activity is identified at 11 to 9 ka in high-latitude glaciated regions. This is absent in non-glaciated regions, supporting the hypothesis of increased volcanism due to ice unloading around this time. Record completeness and consequent interpretation of record limitations are important in understanding volcanism on global to local scales and must be considered during rigorous volcanic hazard and risk assessments. The study also indicates that there need to be improvements in the quality of data, including assessment of uncertainties in volume estimates.

Tectonic interleaving along the Main Central Thrust, Sikkim Himalaya

Abstract: Geochemical and geochronological analyses provide quantitative evidence about the origin, development and motion along ductile faults, where kinematic structures have been overprinted. The Main Central Thrust is a key structure in the Himalaya that accommodated substantial amounts of the India–Asia convergence. This structure juxtaposes two isotopically distinct rock packages across a zone of ductile deformation. Structural analysis, whole-rock Nd isotopes, and U–Pb zircon geochronology reveal that the hanging wall is characterized by detrital zircon peaks at c . 800–1000 Ma, 1500–1700 Ma and 2300–2500 Ma and an ϵ Nd(0) signature of −18.3 to −12.1, and is intruded by c . 800 Ma and c . 500–600 Ma granites. In contrast, the footwall has a prominent detrital zircon peak at c . 1800–1900 Ma, with older populations spanning 1900–3600 Ma, and an ϵ Nd(0) signature of −27.7 to −23.4, intruded by c . 1830 Ma granites. The data reveal a c . 5 km thick zone of tectonic imbrication, where isotopically out-of-sequence packages are interleaved. The rocks became imbricated as the once proximal and distal rocks of the Indian margin were juxtaposed by Cenozoic movement along the Main Central Thrust. Geochronological and isotopic characterization allows for correlation along the Himalayan orogen and could be applied to other cryptic ductile shear zones. Supplementary material: Zircon U–Pb geochronological data, whole-rock Sm–Nd isotopic data, sample locations, photomicrographs of sample thin sections, zircon CL images, and detailed analytical conditions are available at www.geolsoc.org.uk/SUP18704.

The permeability and elastic moduli of tuff from Campi Flegrei, Italy: implications for ground deformation modelling

Abstract: The accuracy of ground deformation modelling at active volcanoes is a principal requirement in volcanic hazard mitigation. However, the reliability of such models relies on the accuracy of the rock physical property (permeability and elastic moduli) input parameters. Unfortunately, laboratory-derived values on representative rocks are usually rare. To this end we have performed a systematic laboratory study on the influence of pressure and temperature on the permeability and elastic moduli of samples from the two most widespread lithified pyroclastic deposits at the Campi Flegrei volcanic district, Italy. Our data show that the water permeability of Neapolitan Yellow Tuff and a tuff from the Campanian Ignimbrite differ by about 1.5 orders of magnitude. As pressure (depth) increases beyond the critical point for inelastic pore collapse (at an effective pressure of 10–15 MPa, or a depth of about 750 m), permeability and porosity decrease significantly, and ultrasonic wave velocities and dynamic elastic moduli increase significantly. Increasing the thermal stressing temperature increases the permeability and decreases the ultrasonic wave velocities and dynamic elastic moduli of the Neapolitan Yellow Tuff; whereas the tuff from the Campanian Ignimbrite remains unaffected. This difference is due to the presence of thermally unstable zeolites within the Neapolitan Yellow Tuff. For both rocks we also find, under the same pressure conditions, that the dynamic (calculated from ultrasonic wave velocities) and static (calculated from triaxial stress-strain data) elastic moduli differ significantly. The choice of elastic moduli in ground deformation modelling is therefore an important consideration. While we urge that these new laboratory data should be considered in routine ground deformation modelling, we highlight the challenges for ground deformation modelling based on the heterogeneous nature (vertically and laterally) of the rocks that comprise the caldera at Campi Flegrei.