Journal ArticleDOI
Helical microtubules of graphitic carbon
TLDR
Iijima et al. as mentioned in this paper reported the preparation of a new type of finite carbon structure consisting of needle-like tubes, which were produced using an arc-discharge evaporation method similar to that used for fullerene synthesis.Abstract:
THE synthesis of molecular carbon structures in the form of C60 and other fullerenes1 has stimulated intense interest in the structures accessible to graphitic carbon sheets. Here I report the preparation of a new type of finite carbon structure consisting of needle-like tubes. Produced using an arc-discharge evaporation method similar to that used for fullerene synthesis, the needles grow at the negative end of the electrode used for the arc discharge. Electron microscopy reveals that each needle comprises coaxial tubes of graphitic sheets, ranging in number from 2 up to about 50. On each tube the carbon-atom hexagons are arranged in a helical fashion about the needle axis. The helical pitch varies from needle to needle and from tube to tube within a single needle. It appears that this helical structure may aid the growth process. The formation of these needles, ranging from a few to a few tens of nanometres in diameter, suggests that engineering of carbon structures should be possible on scales considerably greater than those relevant to the fullerenes. On 7 November 1991, Sumio Iijima announced in Nature the preparation of nanometre-size, needle-like tubes of carbon — now familiar as 'nanotubes'. Used in microelectronic circuitry and microscopy, and as a tool to test quantum mechanics and model biological systems, nanotubes seem to have unlimited potential.read more
Citations
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Journal ArticleDOI
Electronic-structure-dependent bacterial cytotoxicity of single-walled carbon nanotubes.
TL;DR: It is demonstrated for the first time how SWNT electronic structure (i.e., metallic versus semiconducting) is a key factor regulating SWNT antimicrobial activity.
Journal ArticleDOI
Nanoparticles and filled nanocapsules
TL;DR: In this paper, a hollow graphitic cage was used to encapsulate rare-earth and iron-group metals by using an electric arc discharge and showed the excellent protection of outer graphitic cages against oxidation of the inner materials.
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Aggregation kinetics of multiwalled carbon nanotubes in aquatic systems: measurements and environmental implications.
TL;DR: The results suggest that MWNTs are relatively stable at solution pH and electrolyte conditions typical of aquatic environments, suggesting the presence of ionizable functional groups on the MWNT carbon scaffold.
Journal ArticleDOI
Nanostructured Anode Materials for Lithium Ion Batteries: Progress, Challenge and Perspective
TL;DR: In this paper, the authors highlight the characteristics for both anode and cathode for better choice of electrode combinations in the full batteries for high load applications, and the use of several techniques to determine the dynamic variations in nanostructures including both structural and chemical changes of electrode nanostructure during cycling.
Journal ArticleDOI
Plasma Nanoscience: from Nano-Solids in Plasmas to Nano-Plasmas in Solids
TL;DR: In this paper, a unified conceptual framework based on the control of production, transport, and self-organization of precursor species is introduced and a variety of plasma-specific non-equilibrium and kinetics-driven phenomena across the many temporal and spatial scales is explained.
References
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Journal ArticleDOI
C 60 : Buckminsterfullerene
Harold W. Kroto,Harold W. Kroto,James R. Heath,Sean C. O'Brien,Robert F. Curl,Richard E. Smalley +5 more
TL;DR: In this article, the authors proposed a truncated icosahedron, a polygon with 60 vertices and 32 faces, 12 of which are pentagonal and 20 hexagonal.
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Solid C60: a new form of carbon
TL;DR: In this article, a new form of pure, solid carbon has been synthesized consisting of a somewhat disordered hexagonal close packing of soccer-ball-shaped C60 molecules.
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Filamentous growth of carbon through benzene decomposition
TL;DR: Carbon fibres have been prepared by pyrolysing a mixture of benzene and hydrogen at about 1100°C and have been studied by high resolution electron microscopy.
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Cohesive mechanism and energy bands of solid C60.
Susumu Saito,Atsushi Oshiyama +1 more
TL;DR: In this paper, the authors present microscopic total energy calculations which provide a cohesive property and electronic structures of a new form of solid carbon, the face-centered-cubic crystal (fcc ${\mathrm{C}}_{60}$).
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Growth, Structure, and Properties of Graphite Whiskers
TL;DR: Graphite whiskers have been grown in a dc arc under a pressure of 92 atmospheres of argon and at 3900°K as discussed by the authors, with recoverable lengths up to 3 cm. They are embedded in a solid matrix of graphite which builds up by diffusion of carbon vapor from the positive to the negative electrode.