Journal ArticleDOI
Helical microtubules of graphitic carbon
TLDR
Iijima et al. as mentioned in this paper reported the preparation of a new type of finite carbon structure consisting of needle-like tubes, which were produced using an arc-discharge evaporation method similar to that used for fullerene synthesis.Abstract:
THE synthesis of molecular carbon structures in the form of C60 and other fullerenes1 has stimulated intense interest in the structures accessible to graphitic carbon sheets. Here I report the preparation of a new type of finite carbon structure consisting of needle-like tubes. Produced using an arc-discharge evaporation method similar to that used for fullerene synthesis, the needles grow at the negative end of the electrode used for the arc discharge. Electron microscopy reveals that each needle comprises coaxial tubes of graphitic sheets, ranging in number from 2 up to about 50. On each tube the carbon-atom hexagons are arranged in a helical fashion about the needle axis. The helical pitch varies from needle to needle and from tube to tube within a single needle. It appears that this helical structure may aid the growth process. The formation of these needles, ranging from a few to a few tens of nanometres in diameter, suggests that engineering of carbon structures should be possible on scales considerably greater than those relevant to the fullerenes. On 7 November 1991, Sumio Iijima announced in Nature the preparation of nanometre-size, needle-like tubes of carbon — now familiar as 'nanotubes'. Used in microelectronic circuitry and microscopy, and as a tool to test quantum mechanics and model biological systems, nanotubes seem to have unlimited potential.read more
Citations
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Carbon Nanotube Field-Effect-Transistor-Based Biosensors
TL;DR: In this article, a review of the application of carbon nanotube field effect transistors (NTFETs) for biological sensors is presented, with a focus on carbon-nanotube fields.
Journal ArticleDOI
Advances and challenges for flexible energy storage and conversion devices and systems
TL;DR: In this article, an overview of the remarkable contributions made by the leading scientists in this important and promising research area is given, and some perspectives for the future and impacts of flexible energy storage and conversion systems are also proposed.
Journal ArticleDOI
Theory of Electronic States and Transport in Carbon Nanotubes
TL;DR: In this paper, a brief review is given of electronic and transport properties of carbon nanotubes obtained mainly in a k · p scheme, including a giant Aharonov-Bohm effect on the band gap and a Landau-level formation in magnetic fields.
Journal ArticleDOI
Adsorption of polycyclic aromatic hydrocarbons by carbon nanomaterials.
TL;DR: Quantitative relationships between these sorbent properties and the estimated parameters of PMM were obtained, which may represent a first fundamental step toward establishing empirical equations for quantitative prediction of PAH adsorption by carbon nanomaterials and possibly other forms of carbonaceous (geo-) sorbents, and for evaluating their environmental impact.
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Covalent and noncovalent phthalocyanine-carbon nanostructure systems: synthesis, photoinduced electron transfer, and application to molecular photovoltaics.
TL;DR: The aim of reproducing some of the fundamental steps occurring in natural photosynthesis, one of the most important being the photoinduced charge separation (CS), are reproduced.
References
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Journal ArticleDOI
C 60 : Buckminsterfullerene
Harold W. Kroto,Harold W. Kroto,James R. Heath,Sean C. O'Brien,Robert F. Curl,Richard E. Smalley +5 more
TL;DR: In this article, the authors proposed a truncated icosahedron, a polygon with 60 vertices and 32 faces, 12 of which are pentagonal and 20 hexagonal.
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Solid C60: a new form of carbon
TL;DR: In this article, a new form of pure, solid carbon has been synthesized consisting of a somewhat disordered hexagonal close packing of soccer-ball-shaped C60 molecules.
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Filamentous growth of carbon through benzene decomposition
TL;DR: Carbon fibres have been prepared by pyrolysing a mixture of benzene and hydrogen at about 1100°C and have been studied by high resolution electron microscopy.
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Cohesive mechanism and energy bands of solid C60.
Susumu Saito,Atsushi Oshiyama +1 more
TL;DR: In this paper, the authors present microscopic total energy calculations which provide a cohesive property and electronic structures of a new form of solid carbon, the face-centered-cubic crystal (fcc ${\mathrm{C}}_{60}$).
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Growth, Structure, and Properties of Graphite Whiskers
TL;DR: Graphite whiskers have been grown in a dc arc under a pressure of 92 atmospheres of argon and at 3900°K as discussed by the authors, with recoverable lengths up to 3 cm. They are embedded in a solid matrix of graphite which builds up by diffusion of carbon vapor from the positive to the negative electrode.