Journal ArticleDOI
Helical microtubules of graphitic carbon
TLDR
Iijima et al. as mentioned in this paper reported the preparation of a new type of finite carbon structure consisting of needle-like tubes, which were produced using an arc-discharge evaporation method similar to that used for fullerene synthesis.Abstract:
THE synthesis of molecular carbon structures in the form of C60 and other fullerenes1 has stimulated intense interest in the structures accessible to graphitic carbon sheets. Here I report the preparation of a new type of finite carbon structure consisting of needle-like tubes. Produced using an arc-discharge evaporation method similar to that used for fullerene synthesis, the needles grow at the negative end of the electrode used for the arc discharge. Electron microscopy reveals that each needle comprises coaxial tubes of graphitic sheets, ranging in number from 2 up to about 50. On each tube the carbon-atom hexagons are arranged in a helical fashion about the needle axis. The helical pitch varies from needle to needle and from tube to tube within a single needle. It appears that this helical structure may aid the growth process. The formation of these needles, ranging from a few to a few tens of nanometres in diameter, suggests that engineering of carbon structures should be possible on scales considerably greater than those relevant to the fullerenes. On 7 November 1991, Sumio Iijima announced in Nature the preparation of nanometre-size, needle-like tubes of carbon — now familiar as 'nanotubes'. Used in microelectronic circuitry and microscopy, and as a tool to test quantum mechanics and model biological systems, nanotubes seem to have unlimited potential.read more
Citations
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Organizing Single-Walled Carbon Nanotubes on Gold Using a Wet Chemical Self-Assembling Technique
TL;DR: In this article, a wet chemical approach for organizing randomly tangled single-walled carbon nanotubes (SWCNTs) on gold surfaces was proposed, where the as-grown SWCNT was first chemically cut into short pipes and thiol-derivatized at the open ends.
Journal ArticleDOI
Carbon nanotube based biosensors
TL;DR: Carbon nanotube (CNT) based biosensors are recognized to be a next generation building block for ultra-sensitive and ultra-fast biosensing systems as mentioned in this paper.
Journal ArticleDOI
Raman studies of carbon nanotubes
TL;DR: In this article, the first and second-order Raman spectra of closed-carbon nanostructures (nanotubes and nanoparticles) have been measured and compared to those of glassy carbon and highly oriented pyrolitic graphite.
Journal ArticleDOI
Adsorption of fluoride from water by amorphous alumina supported on carbon nanotubes
Yanhui Li,Shuguang Wang,Anyuan Cao,Dan Zhao,Dan Zhao,Xianfeng Zhang,Cailu Xu,Zhaokun Luan,Dianbo Ruan,Ji Liang,Dehai Wu,Bingqing Wei +11 more
TL;DR: A new candidate for fluoride adsorption from water, amorphous Al2O3 supported on carbon nanotubes (Al 2O3/CNTs) is reported in this article.
Journal ArticleDOI
Solid phase extraction of heavy metal ions in environmental samples on multiwalled carbon nanotubes.
TL;DR: The presented method has been applied to the determination of analytes in food and environmental samples with satisfactory results.
References
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Journal ArticleDOI
C 60 : Buckminsterfullerene
Harold W. Kroto,Harold W. Kroto,James R. Heath,Sean C. O'Brien,Robert F. Curl,Richard E. Smalley +5 more
TL;DR: In this article, the authors proposed a truncated icosahedron, a polygon with 60 vertices and 32 faces, 12 of which are pentagonal and 20 hexagonal.
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Solid C60: a new form of carbon
TL;DR: In this article, a new form of pure, solid carbon has been synthesized consisting of a somewhat disordered hexagonal close packing of soccer-ball-shaped C60 molecules.
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Filamentous growth of carbon through benzene decomposition
TL;DR: Carbon fibres have been prepared by pyrolysing a mixture of benzene and hydrogen at about 1100°C and have been studied by high resolution electron microscopy.
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Cohesive mechanism and energy bands of solid C60.
Susumu Saito,Atsushi Oshiyama +1 more
TL;DR: In this paper, the authors present microscopic total energy calculations which provide a cohesive property and electronic structures of a new form of solid carbon, the face-centered-cubic crystal (fcc ${\mathrm{C}}_{60}$).
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Growth, Structure, and Properties of Graphite Whiskers
TL;DR: Graphite whiskers have been grown in a dc arc under a pressure of 92 atmospheres of argon and at 3900°K as discussed by the authors, with recoverable lengths up to 3 cm. They are embedded in a solid matrix of graphite which builds up by diffusion of carbon vapor from the positive to the negative electrode.